Dispersion polymerization in non-polar solvent: Evolution toward emerging applications

Progress in Polymer Science

Volumn 38, Issue 6, 2013, Pages 897-931

  Richez, Alexandre P ^a   Yow, Huai Nyin ^a   Biggs, Simon ^a   Cayre, Olivier J ^a  

^a UNIVERSITY OF LEEDS   (United Kingdom)

Author keywords

Colloid; Dispersion; Non polar; Particle; Polymerization; Stability

Indexed keywords

COLLOIDS; CONVERGENCE OF NUMERICAL METHODS; DISPERSION (WAVES); EFFLUENT TREATMENT; ELECTROPHORETIC DISPLAYS; LATEXES; MONOMERS; PARTICLES (PARTICULATE MATTER); SOLVENTS; SUPERCRITICAL FLUIDS;

ACADEMIC LITERATURE; DISPERSION POLYMERIZATION; EMERGING APPLICATIONS; LOW DIELECTRIC CONSTANTS; NON-POLAR; NON-POLAR SOLVENTS; PARTICLE CHARACTERISTICS; PARTICLE SYSTEMS;

POLYMERIZATION;

EID: 84877584787     PISSN: 00796700     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.progpolymsci.2012.12.001     Document Type: Review

References (142)

1. T.H. Lowry, and K.S. Schueller-Richardson Mechanism and theory in organic chemistry 3rd ed. 1987 Harper International Edition New York 1090 pp.
2. P.A. Lovell, and M.S. El-Aasser Emulsion polymerization and emulsion polymers 1997 John Wiley & Sons Chichester 826
3. K.E.J. Barrett Dispersion polymerization in organic media 1975 John Wiley & Sons New York 322 pp.
4. Osmond DWJ. Dispersion polymerisation. Imperial Chemical Industries. GB Patent: 893,429; 1962.
5. Osmond DWJ. Polymer dispersion. Imperial Chemical Industries. GB Patent: 941,305; 1963.
6. Osmond DWJ. Copolymer dispersions. Imperial Chemical Industries. GB Patent: 958,023; 1964.
7. Carter RJ, Cousens RH, Osmond DWJ. Modified organosols. Imperial Chemical Industries. GB Patent: 971,885; 1964.
8. Anonymous. Polymer dispersions in organic liquid media and methods of preparation. Rohm & Haas Company. GB Patent: 934,038; 1963.
9. Anonymous. Preparation of particulate polymers. Rohm & Haas Company. GB Patent: 956,453; 1964.
10. D.J. Walbridge, and J.A. Waters Rheology of sterically stabilized dispersions of poly(methylmethacrylate) in aliphatic hydrocarbons Discussions of the Faraday Society 42 1966 294 300
11. D.H. Napper Flocculation studies of non-aqueous sterically stabilized dispersions of polymers Transactions of the Faraday Society 64 1968 1701 1711
12. R.J.R. Cairns, R.H. Ottewill, D.W.J. Osmond, and I. Wagstaff Studies on the preparation and properties of latices in nonpolar media Journal of Colloid and Interface Science 1 1976 45 51
13. M.D. Croucher, and T.H. Milkie Temperature dependence of the shear viscosity of sterically stabilised polymer colloids Faraday Discussions of the Chemical Society 76 1983 261 276
14. T.A. Strivens The viscoelastic properties of concentrated suspensions Colloid and Polymer Science 261 1983 74 81
15. D.W.J. Osmond, and D.J. Walbridge Steric stabilization of polymer suspensions in hydrocarbon media by adsorbed layers of graft copolymers Journal of Polymer Science Part C: Polymer Letters 30 1970 1 391
16. B. Vincent, J. Clarke, and K.G. Barnett The flocculation of non-aqueous sterically-stabilised latex dispersions in the presence of free polymer Colloids Surface 17 1986 51 65
17. D.F. Evans, and H. Wennerström The colloidal domain: where physics, chemistry and biology meet 1999 John Wiley & Sons New York 672 pp.
18. B. Vincent The effect of adsorbed polymers on dispersion stability Advances in Colloid and Interface Science 4 1974 193 297
19. D.H. Napper Polymeric stabilization of colloid dispersions 1984 Academic Press London 428 pp.
20. T. Tadros Polymeric surfactants in disperse systems Advances in Colloid and Interface Science 147-148 2009 281 299
21. T. Cosgrove Colloid science: principles, methods and applications 2010 John Wiley & Sons New York 304 pp.
22. E.W. Fischer Elektronenmikroskopische untersuchungen zur stabilität von suspensionen in makromolekularen lösungen Kolloid Z 160 1958 120 141
23. M.J. Rosen Surfactants and interfacial phenomena 1978 John Wiley & Sons New York 304 pp.
24. P. Jenkins, and M. Snowden Depletion flocculation in colloidal dispersions Advances in Colloid and Interface Science 68 1996 57 96
25. S.J. Barsted, L.J. Nowakowska, I. Wagstaff, and D.J. Walbridge Measurement of steric stabilizer barrier thickness in dispersions of poly(methyl methacrylate) in aliphatic hydrocarbon Transactions of the Faraday Society 67 1971 3598 3603
26. I. Marković, R.H. Ottewill, S.M. Underwood, and T.F. Tadros Interactions in concentrated polymer lattices Langmuir 2 1986 625 630
27. D.H. Everett, and J.F. Stageman Stability studies on polymer colloids in simple liquids Colloid and Polymer Science 255 1977 293 294
28. J.V. Dawkins, and G. Taylor Flocculation studies of non-aqueous poly(methyl methacrylate) dispersions stabilized by AB block copolymers of polystyrene and poly(dimethyl siloxane) Colloid and Polymer Science 258 1980 79 84
29. R. Pelton, A. Osterroth, and M.A. Brook Silicone stabilized poly(methyl methacrylate) nonaqueous latex 2.Flocculation by degradation of the steric layer Journal of Colloid and Interface Science 147 1991 523 530
30. P.A. Reynolds, and C.A. Reid Effect of nonadsorbing polymers on the rheology of a concentrated nonaqueous dispersion Langmuir 7 1991 89 94
31. P.N. Pusey, and W. van Megen Phase behavior of concentrated suspensions of nearly hard colloidal spheres Nature 320 1986 340 342
32. W. van Megen, S.M. Underwood, R.H. Ottewill, N.St.J. Williams, and P.N. Pusey Particle diffusion in concentrated dispersions Faraday Discussions of the Chemical Society 83 1987 47 57
33. R.H. Ottewill, and N.St.J. Williams Study of particle motion in concentrated dispersions by tracer diffusion Nature 325 1987 232 234
34. P. d'Haene, J. Mewis, and G.G. Fuller Scattering dichroism measurements of flow-induced structure of a shear thickening suspension Journal of Colloid and Interface Science 156 1993 350 358
35. J. Mewis, W.J. Frith, T.A. Strivens, and W.B. Russel The rheology of suspsensions containing polymerically stabilized particles AIChE Journal 35 1989 415 422
36. W.J. Frith, T.A. Strivens, and J. Mewis Dynamic mechanical properties of polymerically stabilized dispersions Journal of Colloid and Interface Science 139 1990 55 62
37. W.J. Frith, P. d'Haene, R. Buscall, and J. Mewis Shear thickening in model suspensions of sterically stabilized particles Journal of Rheology 40 1996 531 548
38. P. d'Haene, and J. Mewis Rheological characterization of bimodal colloidal dispersions Rheologica Acta 33 1994 165 174
39. L. Antl, R.D. Goodwin, R.H. Ottewill, S.M. Owens, S. Papworth, and J.A. Waters The preparation of poly(methyl methacrylate) lattices in non-aqueous media Colloids Surface 17 1986 67 78
40. A.I. Campbell, and P. Bartlett Fluorescent hard-sphere polymer colloids for confocal microscopy Journal of Colloid and Interface Science 256 2002 325 330
41. H. Hu, and R.G. Larson Preparation of fluorescent particles with long excitation and emission wavelength dispersible in organic solvents Langmuir 20 2004 7436 7443
42. G. Bosma, C. Pathmamanoharan, E.H.A. de Hoog, W.K. Kegel, A. van Blaaderen, and H.N.W. Lekkerkerker Preparation of monodisperse, fluorescent PMMA-latex colloids by dispersion polymerization Journal of Colloid and Interface Science 245 2002 292 300
43. R.S. Jardine, and P. Bartlett Synthesis of non-aqueous fluorescent hard-sphere polymer colloid Colloids Surfaces A 211 2002 127 132
44. R.P.A. Dullens, M. Claesson, D. Derks, A. van Blaaderen, and W.K. Kegel Monodisperse core-shell poly(methyl methacrylate) latex colloids Langmuir 19 2003 5963 5966
45. R.P.A. Dullens, E.M. Claesson, and W.K. Kegel Preparation and properties of cross-linked fluorescent poly(methyl methacrylate) latex colloids Langmuir 20 2004 658 664
46. M.T. Elesser, A.D. Hollingsworth, K.V. Edmond, and D.J. Pine Large core-shell poly(methyl methacrylate) colloidal clusters: synthesis, characterization and tracking Langmuir 27 2011 917 927
47. M.E. Leunissen, C.G. Christova, A.P. Hynninen, C.P. Royall, A.I. Campbell, A. Imhof, M. Dijkstra, R. van Roij, and A. van Blaaderen Ionic colloidal crystals of oppositely charged particles Nature 437 2005 235 240
48. T. Vissers, A. Wysocki, M. Rex, H. Löwen, C.P. Royall, A. Imhof, and A. van Blaaderen Lane formation in driven mixtures of oppositely charged colloids Soft Matter 7 2011 2352 2356
49. M.F. Hsu, E.R. Dufresne, and D.A. Weitz Charge stabilization in nonpolar solvents Langmuir 21 2005 4881 4887
50. R. Sanchez, and P. Bartlett Synthesis of charged particles in an ultra-low dielectric solvent Soft Matter 7 2011 887 890
51. 2 nanoparticles Journal of Macromolecular Science 45 2006 53 60
52. M.A. Lee, Y.H. Kim, B.J. Park, and H.J. Choi Synthesis and electrophoretic properties of poly(acrylamide-co-methylmethacrylate) coated organic pigments Molecular Crystals and Liquid Crystals 499 2009 627 632
53. M. Badila, A. Hébraud, C. Brochon, and Hadziioannou G Design of colored multilayered electrophoretic particles for electronic inks ACS ACS Applied Materials & Interfaces 3 2011 3602 3610
54. S. Kawaguchi, and K. Ito Dispersion polymerization Advances in Polymer Science 175 2005 299 328
55. M.T. Elsesser, and A.D. Hollingsworth Revisiting the Synthesis of a well-known comb-graft copolymer stabilizer and its application to the dispersion polymerization of poly(methyl methacrylate) in organic media Langmuir 26 2010 17989 17996
56. K. Kargupta, P. Rai, and A. Kumar Effect of graft chain length of the stabilizer on dispersion polymerization of methyl methacrylate in petrol Journal of Applied Polymer Science 49 1993 1309 1329
57. K.E.J. Barrett, and H.R. Thomas Kinetics of dispersion polymerization of soluble monomers. I. Methyl methacrylate Journal of Polymer Science Part A: Polymer Chemistry 7 1969 2621 2650
58. R.J.R. Cairns, R.H. Ottewill, D.W. Osmond, and I. Wagstaff Studies on the preparation and properties of latices in nonpolar media Journal of Colloid and Interface Science 54 1976 45 51
59. C. Pathmamanoharan, C. Slob, and H.N.W. Lekkerkerker Preparation of polymethacrylate latices in non-polar media Colloid and Polymer Science 267 1989 448 450
60. H. Hu, and G. Larson One-step preparation of highly monodisperse micron-size particles in organic solvents Journal of the American Chemical Society 126 2004 13894 13895
61. M.S. Chattha, and J.C. Cassatta A new preparation of nonaqueous dispersions Industrial & Engineering Chemistry Product Research and Development 25 1986 453 456
62. R.H. Pelton, A. Osterroth, and M.A. Brook Silicone stabilized poly(methyl methacrylate) nonaqueous latexes I. Preparation and characterization Journal of Colloid and Interface Science 137 1990 120 127
63. S.A. Srinivasan, J.L. Hedrick, D.R. McKean, R.D. Miller, and J.G. Hilbom Preparation of thermally labile PMMA particles by combined non-aqueous dispersion polymerization and polymer chain transfer Polymer 39 1998 1497 1501
64. S.M. Klein, V.N. Manoharan, D.J. Pine, and F.F. Lange Preparation of monodisperse PMMA microsphere in nonpolar solvents by dispersion polymerisation with a macromonomeric stabilizer Colloid and Polymer Science 282 2003 7 13
65. J.V. Dawkins, and G. Taylor Nonaqueous poly(methyl methacrylate) dispersions: radical dispersion polymerization in the presence of AB block copolymers of polystyrene and poly(dimethyl siloxane) Polymer 20 1979 599 604
66. D.H. Everett, and J.F. Stageman Preparation and stability of novel polymer colloids in a range of simple liquids Faraday Discussions of the Chemical Society 65 1978 230 241
67. J.C. Saam, and C.H. Tsai Silicone-stabilised nonaqueous emulsion polymerisation Journal of Applied Polymer Science 18 1974 2279 2285
68. S. Kawaguchi, T. Okada, K. Tano, and K. Ito Synthesis of polyethylene macromonomers and their radical copolymerizations with methyl methacrylate in homogeneous and oligoehtylene melts media Designed Monomers and Polymers 3 2000 263 277
69. B. Hirzinger, M. Helmstedt, and J. Stejskal Light scattering studies on core-shell systems: determination of size parameters of sterically stabilized poly(methylmethacrylate) dispersions Polymer 41 2000 2883 2891
70. M. Hölderle, G. Bar, and R. Mülhaupt Synthesis and characterization of oxazoline-functional polymer particles by free radical nonaqueous dispersion polymerization Journal of Polymer Science Part A: Polymer Chemistry 35 1997 2539 2548
71. J. Stejskal, D. Hlavatá, A. Sikora, Č. Koňák, J. Pleštil, and P. Kratochvil Equilibrium and non-equilibrium copolymer micelles: polystyrene-block-poly(ethylene-co-propylene) in decane and in diisopropyether Polymer 33 1992 3675 3685
72. J. Stejskal, P. Kratochvil, P. Koubik, Z. Tuzar, J. Urban, M. Helmstedt, and A.D. Jenkins Light scattering characterization of spherical particles prepared by the dispersion polymerization of methyl methacrylate in a non-aqueous medium Polymer 31 1990 1816 1822
73. M. Helmstedt, and H. Schäfer Determination of sizes of spherical particles, prepared by dispersion polymerization of methyl methacrylate in non-aqueous medium, by analysis of the particle scattering and autocorrelation functions Polymer 35 1994 3377 3383
74. B. Williamson, R. Lukas, M.A. Winnik, and M.D. Croucher The preparation of micron-size polymer particles in nonpolar media Journal of Colloid and Interface Science 119 1987 559 564
75. M.A. Winnik Fluorescence in structured media: a look at polymer colloids Pure and Applied Chemistry 9 1984 1281 1288
76. M.A. Winnik, B. Williamson, and T. Russell Small-angle X-ray scattering studies of polymer colloids: nonaqueous dispersions of poly(isobutylene)- stabilized poly(methyl methacrylate) particles Macromolecules 20 1987 899 901
77. M.A. Winnik, B. Disanayaka, O. Pekcan, and M.D. Croucher Fluorescence quenching studies of core and stabilizer-labeled non-aqueous dispersions: the nature of the core-stabilizer interface Journal of Colloid and Interface Science 139 1990 251 259
78. L. Houillot, C. Bui, M. Save, B. Charleux, C. Farcet, C. Moire, J.A. Raust, and I. Rodriguez Synthesis of well-defined polyacrylate particle dispersion in organic medium using simultaneous RAFT polymerization and self-assembly of block copolymers. A strong influence of the selected thiocarbonylthio chain transfer agent Macromolecules 40 2007 6500 6509
79. L. Houillot, C. Bui, C. Farcet, C. Moire, J.A. Raust, H. Pasch, M. Save, and B. Charleux Dispersion polymerization of methyl acrylate in nonpolar solvent stabilized by block copolymers formed in situ via the RAFT process ACS Applied Materials & Interfaces 2 2010 434 442
80. H.V. Harris, and S.J. Holder Octadecyl acrylate based block and random copolymers prepared by ATRP as comb-like stabilizers for colloidal micro-particle one-step synthesis in organic solvents Polymer 47 2006 5701 5706
81. J.G. Murray, and F.C. Schwab Organic fillers by anionic dispersion polymerisation Industrial & Engineering Chemistry Product Research and Development 21 1982 93 96
82. G.B. Stampa The anionic dispersion of polymerization of α-methylstyrene Journal of Applied Polymer Science 14 1970 1227 1233
83. M. Schneider, and R. Mülhaupt Living dispersion polymerization of styrene in the presence of polystyrene-block-poly(4-trimethylsilylstyrene) Polymer Bulletin 32 1994 545 550
84. M.A. Awan, V.L. Dimonie, and M.S. El-Aasser Anionic dispersion polymerization of styrene. I. Investigation of parameters for preparation of uniform micron-size polystyrene particles with narrow molecular weight distribution Journal of Polymer Science Part A: Polymer Chemistry 34 1996 2633 2649
85. M.A. Awan, V.L. Dimonie, and M.S. El-Aasser Anionic dispersion polymerization of styrene. II. Mechanism of particle formation Journal of Polymer Science Part A: Polymer Chemistry 34 1996 2651 2664
86. J. Kim, S.Y. Jeong, K.U. Kim, Y.H. Ahn, and R.P. Quirk Anionic disperison polymerization. I. Control of particle size Journal of Polymer Science Part A: Polymer Chemistry 34 1996 3277 3288
87. S. Kéki, G. Deák, L. Daróczi, A. Kuki, and M. Zsuga Star-shaped nanomicelles of polyisobutylene-polystyrene diblock copolymers. New stabilizer for living dispersion polymerization of styrene Macromolecular Symposium 157 2000 217 224
88. I. Tausendfreund, F. Bandermann, H.W. Siesler, and M. Kleimann Anionic dispersion copolymerisation of styrene and 1,3-butadiene Polymer 43 2002 7085 7091
89. J.V. Dawkins, and G. Taylor Nonaqueous polystyrene dispersions: Radical dispersion polymerization in the presence of AB block copolymers of polystyrene and poly(dimethyl siloxane) European Polymer Journal 15 1978 453 457
90. K. Tauer, and H. Ahmad Study on the preparation and stabilization of pyrene labeled polymer particles in non-polar media Polymer Reaction Engineering 11 2003 305 318
91. M. Hölderle, M. Baumert, and R. Mülhaupt Comparison of controlled radical styrene polymerizations in bulk and nonaqueous dispersion Macromolecules 30 1997 3420 3422
92. O. Okay, and W. Funke Anionic dispersion polymerisation of 1,4-divinylbenzene Macromolecules 23 1990 2623 2628
93. O. Okay, and W. Funke Steric stabilization of reactive microgels from 1,4-dinvinylbenzene Makromolekulare Chemie-Rapid 11 1990 583 587
94. F.A. Taromi, and P. Rempp "Porcupine" polymers and double-star polymers Makromolekulare Chemie 190 1989 1791 1798
95. O. Okay, and W. Funke Conditions of microgel formation in homogeneous anionic polymerization of 1,4-Divinylbenzene Makromolekulare Chemie 191 1990 1565 1573
96. M.A. Ansarifar, and P.F. Luckham The preparation of monodisperse polyacrylonitrile particles in the presence of AB block copolymers of poly-2-vinylpyridine/poly(tertbutylstyrene) Colloid and Polymer Science 266 1988 1020 1023
97. H.V. Penfold, S.J. Holder, and B.E. McKensie Octadecyl acrylate-methyl methacrylate block and gradient copolymers from ATRP: comb-like stabilizers for the preparation of micro- and nano-particles of poly(methyl methacrylate) and poly(acrylonitrile) by non-aqueous dispersion polymerization Polymer 51 2010 1904 1913
98. D. Horák, M. Kryštůfek, and J. Spěvá ček Effect of reaction parameters on the dispersion polymerization of 1-Vinyl-2-Pyrrolidone Journal of Polymer Science Part A: Polymer Chemistry 38 2000 653 663
99. S. Sosnowski, M. Gadzinowski, S. Slomkowski, and S. Penczek Synthesis of bioerodible poly(ε-caprolactone) latexes and poly(D, L-lactide) microspheres by ring-opening polymerization Journal of Bioactive and Compatible Polymers 9 1994 345 366
100. W. Jajubowski, J.F. Lutz, S. Slomkowski, and K. Matyjaszewski Block and random copolymers as surfactants for dispersion polymerization. I. Synthesis via atom transfer radical polymerization and ring-opening polymerization Journal of Polymer Science Part A: Polymer Chemistry 43 2005 1498 1510
101. M. Muranaka, Y. Kitamura, and H. Yoshizawa Preparation of biodegradable microspheres by anionic dispersion polymerization with PLA copolymeric dispersion stabilizer Colloid and Polymer Science 285 2007 1441 1448
102. M. Muranaka, H. Yoshizawa, and T. Ono Design of polylactide-grafted copolymeric stabilizer for dispersion polymerization of d,l-lactide Colloid and Polymer Science 287 2009 525 532
103. A.T. Chen, and R.T. Wojcik Polyurethane coatings for metal and plastics substrates Metal Finishing 108 2010 108 121
104. L.S. Ramanathan, D. Baskaran, P.G. Shukla, and S. Sivaram Preparation of polyurethane microspheres via dispersion polycondensation using poly(1,4-isoprene)-block-poly(ethylene oxide) as steric stabilizer Macromolecular Chemistry and Physics 203 2002 998 1002
105. L.S. Ramanathan, P.G. Shukla, and S. Sivaram Synthesis and characterization of polyurethane microspheres Pure and Applied Chemistry 70 1998 1295 1299
106. B. Radhakrishnan, E. Cloutet, and H. Cramail Synthesis of uniform polyurethane particles by step growth polymerization in a dispersed medium Colloid and Polymer Science 280 2002 1122 1130
107. P. Chambon, E. Cloutet, and H. Cramail Synthesis of core-shell polyurethane-poly(dimethylsiloxane) particles in supercritical carbon Macromolecules 37 2004 5856 5859
108. P. Chambon, E. Cloutet, and H. Cramail Synthesis of core-shell polyurethane-polydimethylsiloxane particles by polyaddition in organic dispersant media: mechanism of particle formation Macromolecular Symposium 226 2005 227 238
109. L.S. Egan, and M.A. Winnik Synthesis and characterization of fluorescently labelled poly(vinyl acetate) particles Journal of Polymer Science Part A: Polymer Chemistry 24 1986 1895 1913
110. L.S. Egan, and M.A. Winnik Oxygen quenching studies of nonaqueous dispersions of poly(vinyl acetate) labeled with phenanthrene groups Langmuir 4 1988 438 445
111. 2 in green chemical synthesis and processing Journal of Supercritical Fluids 28 2004 121 191
112. C.D. Wood, A.I. Cooper, and J.M. DeSimone Green synthesis of polymers using supercritical carbon dioxide Current Opinion in Solid State & Materials 8 2004 325 331
113. P.B. Zetterlund, Y. Kagawa, and M. Okubo Controlled living radical polymerization in dispersed systems Chemical Reviews 108 2008 3747 3794
114. A.I. Cooper Polymer synthesis and processing using supercritical carbon dioxide Journal of Materials Chemistry 10 2000 207 234
115. J.L. Kendall, D.A. Canelas, J.L. Young, and J.M. DeSimone Polymerizations in supercritical carbon dioxide Chemical Reviews 99 1999 543 563
116. D.A. Canelas, and J.M. DeSimone Polymerizations in liquid and supercritical carbon dioxide Advances in Polymer Science 133 1997 103 140
117. A.M. Gregory, K.J. Thurecht, and S.M. Howdle Controlled dispersion polymerization of methyl methacrylate in supercritical carbon dioxide via RAFT Macromolecules 41 2008 1215 1222
118. 2 Macromolecules 40 2007 2965 2967
119. 2 stabilized by random copolymers of 1H,1H-perfluorooctyl methacrylate and 2-(dimethylaminoethyl methacrylate) Journal of Polymer Science Part A: Polymer Chemistry 46 2008 1365 1375
120. 2 Macromolecules 30 1997 745 756
121. J. Shin, W. Bae, and H. Kim Synthesis of cross-linked poly(methyl methacrylate) via dispersion polymerization in supercritical carbon dioxide Colloid and Polymer Science 288 2010 271 282
122. Y.L. Hsiao, E.E. Maury, J.M. DeSimone, S. Mawson, and K.P. Johnston Dispersion polymerization of methyl methacrylate stabilized with poly(1,1-dihydroperfluorooctyl acrylate) in supercritical carbon-dioxide Macromolecules 28 1995 8159 8166
123. 2 Polymer 41 2000 6715 6721
124. 2: effect of stabilizer,initiator and monomer concentrations Macromolecular Research 16 2008 120 127
125. 2 in the presence of non-fluorous random copolymers European Polymer Journal 44 2008 2253 2261
126. K.A. Shaffer, T.A. Jones, D.A. Canelas, J.M. DeSimone, and S.P. Wilkinson Dispersion polymerisations in carbon dioxide using siloxane-based stabilisers Macromolecules 29 1996 2704 2706
127. M. Okubo, S. Fujii, and H. Minami Production of poly(methyl methacrylate) particles by dispersion polymerization with aminopropyl-terminated poly(dimethylsiloxane) stabilizer in supercritical carbon dioxide Progress in Colloid and Polymer Science 124 2004 121 125
128. S. Fujii, H. Minami, and M. Okubo Production of poly(methyl methacrylate) particles by dispersion polymerization with mercaptopropyl terminated poly(dimethylsiloxane) stabilizer in supercritical carbon dioxide Colloid and Polymer Science 282 2004 569 574
129. M. Okubo, S. Fujii, H. Maenaka, and H. Minami Production of submicron-sized poly(methyl methacrylate) particles by dispersion polymerization with a poly(dimethylsiloxane)-based azoinitiator in supercritical carbon dioxide Colloid and Polymer Science 280 2002 183 187
130. H. Minami, Y. Kagawa, S. Kuwahara, J. Shigematsu, S. Fujii, and M. Okubo Dispersion atom transfer radical polymerization of methyl methacrylate with bromo-terminated poly(dimethylsiloxane) in supercritical carbon dioxide Designed Monomers and Polymers 7 2004 553 562
131. L.-Q. Cao, L.-P. Chen, P.-Y. Cui, and J.-D. Wang Synthesis of PNIPA/PDMS-g-PAA core-shell composites in supercritical carbon dioxide Journal of Applied Polymer Science 108 2008 3843 3850
132. 2 and water Macromolecules 33 2000 1606 1612
133. 2 solubility studies of poly(ether carbonate)s and poly(ether ester)s produced by step growth polymerization Macromolecules 38 2005 1691 1698
134. C. Drohmann, and E.J. Beckman Phase behavior of polymers containing ether groups in carbon dioxide Journal of Supercritical Fluids 22 2002 103 110
135. 2-philes Industrial and Engineering Chemistry Research 39 2000 4678 4683
136. 2 Angewandte Chemie International Edition 48 2009 4993 4995
137. 2-soluble vinyl pivalate hydrocarbon stabilisers via RAFT polymerisation Polymer Chemistry 2 2011 1293 1299
138. I. Blakey, A.G. Yu, S.M. Howdle, A.K. Whittaker, and K.J. Thurecht Controlled polymerisation of lactide using an organo-catalyst in supercritical carbon dioxide Green Chemistry 13 2011 2032 2037
139. J.Y. Lee, C.H. Song, J.I. Kim, and J.H. Kim Preparation of aromatic polycarbonate nanoparticles using supercritical carbon dioxide Journal of Nanoparticle Research 4 2002 53 59
140. B. Grignard, C. Jerome, C. Calberg, R. Jerome, W.X. Wang, S.M. Howdle, and C. Detrembleur Dispersion atom transfer radical polymerization of vinyl monomers in supercritical carbon dioxide Macromolecules 41 2008 8575 8583
141. B. Grignard, T. Phan, D. Bertin, D. Gigmes, C. Jerome, and C. Detrembleur Dispersion nitroxide mediated polymerization of methyl methacrylate in supercritical carbon dioxide using in situ formed stabilizers Polymer Chemistry 1 2010 837 840
142. J. Jennings, M. Beija, A. Richez, S. Cooper, P. Mignot, K. Thurecht, K. Jack, and S. Howdle One-pot synthesis of block copolymers in supercritical carbon dioxide: A simple versatile route to nonastructured microparticles Journal of the American Chemical Society 134 2012 4772 4781