Dispersion polymerization of methyl methacrylate in supercritical CO2 in the presence of non-fluorous random copolymers

European Polymer Journal

Volumn 44, Issue 7, 2008, Pages 2253-2261

  Yuvaraj, Haldorai ^a   Hwang, Ha Soo ^a   Kim, Won Soo ^a   Kim, Hyun Gyu ^b   Jeong, Euh Duck ^b   Lim, Kwon Taek ^a  

^a Pukyong National University   (South Korea)

^b Korea Basic Science Institute (KBSI)   (South Korea)

Author keywords

2 dimethylaminoethyl methacrylate; Dispersion polymerization; PMMA; Random copolymer; Supercritical CO2

Indexed keywords

ACRYLIC MONOMERS; CARBON DIOXIDE; CHEMICAL REACTIONS; DISPERSION (WAVES); ESTERS; FREE RADICALS; MONOMERS; POLYMERIZATION; POLYMERS; SUPERCRITICAL FLUID EXTRACTION;

2 DIMETHYLAMINOETHYL METHACRYLATE; CO MONOMERS; DISPERSION POLYMERIZATION; FLUOROUS; PROPYL METHACRYLATE (PMA); RANDOM CO-POLYMER; SUPER-CRITICAL; SUPERCRITICAL CARBON DIOXIDE (SC CO2);

FREE RADICAL POLYMERIZATION;

EID: 47049120644     PISSN: 00143057     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.eurpolymj.2008.04.040     Document Type: Article

References (30)

1. In: Jessop P.G., and Leitner W. (Eds). Chemical synthesis using supercritical fluids (1999), Weinheim, Wiley-VCH
2. Kendall J.L., Canelas D.A., Young J.L., and DeSimone J.M. Polymerizations in supercritical carbon dioxide. Chem Rev 99 (1999) 543-563
3. Desimone J.M., Maury E.E., Menceloglu Y.Z., McClain J.B., Romack T.R., and Combes J.R. Dispersion polymerization in supercritical carbon dioxide. Science 265 (1994) 356-359
4. Canelas D.A., and DeSimone J.M. Dispersion polymerizations of styrene in carbon dioxide stabilized with poly(styrene-b-dimethylsiloxane). Macromolecules 30 (1997) 5673-5682
5. Li G., Yates M.Z., Johnston K.P., and Howdle S.M. In situ investigation on the mechanism of dispersion polymerization in supercritical carbon dioxide. Macromolecules 33 (2000) 4008-4014
6. Hems W.P., Yong T.M., Van Nunen J.L.M., Cooper A.I., Holmes A.B., and Griffin D.A. Dispersion polymerisation of methyl methacrylate in supercritical carbon dioxide-evaluation of well defined fluorinated AB block copolymers as surfactants. J Mater Chem 9 (1999) 1403-1407
7. Woods H.M., Nouvel C., Licence P., Irnive D.J., and Howdle S.M. Dispersion polymerization of methyl methacrylate in supercritical carbon dioxide: an investigation into stabilizer anchor group. Macromolecules 38 (2005) 3271-3282
8. Shiho H., and DeSimone J.M. Dispersion polymerization of glycidyl methacrylate in supercritical carbon dioxide. Macromolecules 34 (2001) 1198-1203
9. Shiho H., and Desimone J.M. Dispersion polymerization of 2-hydroxyethyl methacrylate in supercritical carbon dioxide. J Polym Sci Part A: Polym Chem 38 (2000) 3783-3790
10. Shiho H., and DeSimone J.M. Dispersion polymerization of acrylonitrile in supercritical carbon dioxide. Macromolecules 33 (2000) 1565-1569
11. Berger T., McGhee B., Scherf U., and Steffen W. Polymerization of vinylpyrrolidone in supercritical carbon dioxide with a diblock copolymer stabilizer. Macromolecules 33 (2000) 3505-3507
12. 2. Macromolecules 30 (1997) 745-756
13. Giles M.R., O'Connor S.J., Hay J.N., Winder R.J., and Howdle S.M. Novel graft stabilizers for the free radical polymerization of methyl methacrylate in supercritical carbon dioxide. Macromolecules 33 (2000) 1996-1999
14. 2. Macromolecules 32 (1999) 1018-1026
15. Christian P., Howdle S.M., and Irnive D.J. Dispersion polymerization of methyl methacrylate in supercritical carbon dioxide with a monofunctional pseudo-graft stabilizer. Macromolecules 33 (2000) 237-239
16. Shaffer K.A., Jones T.A., Canelas D.A., and Wilkinson S.P. Desimone JM, dispersion polymerizations in carbon dioxide using siloxane-based stabilizers. Macromolecules 29 (1996) 2704-2706
17. 2. Polymer 41 (2000) 6715-6721
18. Giles M.R., and Howdle S.M. New unsaturated surfactants for the dispersion polymerisation of methyl methacrylate in supercritical carbon dioxide. Eur Polym J 37 (2001) 1347-1351
19. 2 in the presence of copolymers of perfluorooctyl ethylene methacrylate and poly(propylene glycol) methacrylate. Macromolecules 36 (2003) 4779-4785
20. Deniz S., Baran N., Akgun M., Uzun I.N., and Dincer S. Dispersion polymerization of methyl methacrylate in supercritical carbon dioxide using a silicon-containing fluoroacrylate stabilizer. Polym Int 54 (2005) 1660-1668
21. Hwang H.S., Gal Y.S., Johnston K.P., and Lim K.T. Dispersion polymerization of methyl methacrylate in supercritical carbon dioxide in the presence of random copolymers. Macromol Rapid Commun 27 (2006) 121-125
22. 2 stabilized by random copolymers of 1H,1H-perfluoro octyl methacrylate and 2-dimethylaminoethyl methacrylate. J Supercrit Fluids 42 (2007) 359-365
23. 2. Macromol Rapid Commun 27 (2006) 722-726
24. 2 in the presence of non-fluorous random copolymeric stabilizers. J Supercrit Fluids 42 (2007) 351-358
25. 2. Langmuir 20 (2004) 2466-2471
26. 2 with a siloxane-based macromonomer: 1. The particle growth regime. Macromolecules 31 (1998) 2838-2847
27. 2 with a siloxane-based macromonomer: 2. The particle formation regime. Macromolecules 31 (1998) 2848-2856
28. 2 stabilized by random copolymers of 1H,1H-perfluoro octyl methacrylate and 2-(dimethylaminoethyl methacrylate). J Polym Sci Part A: Polym Chem 2007 46 (2008) 1365-1375
29. Shiho H., and DeSimone J.M. Dispersion polymerization of styrene in supercritical carbon dioxide utilizing random copolymers containing a fluorinated acrylate for preparing micron-size polystyrene particles. J Polym Sci Part A: Polym Chem 38 (2000) 1146-1153
30. Wang W., Griffiths R.M.T., Naylor A., Giles M.R., Irvine D.J., and Howdle S.M. Preparation of cross-linked microparticles of poly(glycidyl methacrylate) by dispersion polymerization of glycidyl methacrylate using a PDMS macromonomer as stabilizer in supercritical carbon dioxide. Polymer 43 (2002) 6653-6659