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Volumn , Issue 14, 2013, Pages 2538-2548

Synthesis of differently substituted tacn-based ligands: Towards the control of solubility and electronic and steric properties of uranium coordination complexes

Author keywords

Electronic effects; N,O ligands; Steric hindrance; Uranium

Indexed keywords

CHELATION; CRYSTAL STRUCTURE; LIGANDS; PHENOLS; SINGLE CRYSTALS; SOLUBILITY; SYNTHESIS (CHEMICAL); URANIUM COMPOUNDS;

EID: 84877253877     PISSN: 14341948     EISSN: 10990682     Source Type: Journal    
DOI: 10.1002/ejic.201201549     Document Type: Article
Times cited : (15)

References (59)
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    • A racemate is simply a 1:1 mechanical mixture or a conglomerate of crystals of the two enantiomers, each crystal being made up of homochiral molecules. When crystallization of a racemate leads to the formation of a conglomerate (5-10 % of all racemates) then, by definition, the substance is said to be spontaneously resolved., E. L. Eliel, S. H. Wilen, M. P. Doyle (Eds.), Basic Organic Stereochemistry, Wiley Interscience, New York, 2001, pp. 106, 198.
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