A linear, O-coordinated η1-CO2 bound to uranium

Science

Volumn 305, Issue 5691, 2004, Pages 1757-1759

  Castro Rodriguez, Ingrid ^a   Nakai, Hidetaka ^a   Zakharov, Lev N ^a   Rheingold, Arnold L ^a   Meyer, Karsten ^a  

^a UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CHEMICAL BONDS; COORDINATION REACTIONS; MAGNETIZATION; OXYGEN; REACTION KINETICS; RESONANCE;

BOND LENGTHS; LIGANDS; LINEAR COORDINATIONS; RESONANCE STRUCTURES;

AROMATIC COMPOUNDS;

CARBON DIOXIDE; COORDINATION COMPOUND; LIGAND; METAL COMPLEX; OXYGEN; URANIUM;

CARBON DIOXIDE; CHEMISTRY; URANIUM;

ARTICLE; ATOM; CHEMICAL BOND; CHEMICAL STRUCTURE; COMPLEX FORMATION; CRYSTALLOGRAPHY; ELECTRON; ELECTRON TRANSPORT; LIGAND BINDING; LINEAR SYSTEM; MAGNETISM; MOLECULAR MODEL; OXIDATION; PRIORITY JOURNAL; QUANTUM YIELD; REACTION ANALYSIS; REDUCTION; SEPARATION TECHNIQUE; SPECTROSCOPY; STRUCTURE ANALYSIS; VIBRATION; CHEMISTRY; HYDROPHOBICITY; OXIDATION REDUCTION REACTION; TEMPERATURE; X RAY;

CARBON DIOXIDE; CRYSTALLOGRAPHY; ELECTRONS; HYDROPHOBICITY; LIGANDS; MAGNETICS; MODELS, MOLECULAR; MOLECULAR STRUCTURE; OXIDATION-REDUCTION; OXYGEN; SPECTRUM ANALYSIS; TEMPERATURE; URANIUM; X-RAYS;

EID: 4544303533     PISSN: 00368075     EISSN: None     Source Type: Journal    
DOI: 10.1126/science.1102602     Document Type: Article

References (25)

1. P. Falkowski et al., Science 290, 291 (2000).
2. D. H. Gibson, Chem. Rev. 96, 2063 (1996).
3. M. Aresta, C. F. Nobile, V. G. Albano, E. Forni, M. Manassero, J. Chem. Soc. Chem. Commun. 1975, 636 (1975).
4. M. Aresta, C. F. Nobile, J. Chem. Soc. Dalton Trans. 1977, 708 (1977).
5. T. Herskovitz, J. Am. Chem. Soc. 99, 2391 (1977).
6. H. J. Freund, R. P. Messmer, Surf. Sci. 172, 1 (1986).
7. D. H. Gibson, Coord. Chem. Rev. 185-186, 335 (1999).
8. P. F. Souter, L Andrews, J. Am. Chem. Soc. 119, 7350 (1997).
9. L. Andrews, M. F. Zhou, B. Y. Liang, J. Li, B. E. Bursten, J. Am. Chem. Soc. 122, 11440 (2000).
10. H. Mauser, W. A. King, J. E. Gready, T. J. Andrews, J. Am. Chem. Soc. 123, 10821 (2001).
11. H. J. Lee et al., J. Mol. Biol. 308, 937 (2001).
12. D. L. Clark, A. P. Sattelberger, R. A. Andersen, Inorg. Synth. 31, 307 (1997).
13. P. L. Diaconescu, P. L. Arnold, T.A. Baker, D.J. Mindiola, C. C. Cummins, J. Am. Chem. Soc. 122, 6108 (2000).
14. J. G. Brennan, R. A. Andersen, J. L. Robbins, J. Am. Chem. Soc. 108, 335 (1986).
15. M. del Mar Conejo et al., Chem. Eur. J. 5, 3000 (1999).
16. P. Roussel, P. Scott, J. Am. Chem. Soc. 120, 1070 (1998).
17. A. L. Odom, P. L. Arnold, C. C. Cummins, J. Am. Chem. Soc. 120, 5836 (1998).
18. I. Castro-Rodriguez et al., J. Am. Chem. Soc. 125, 15734 (2003).
19. H. Nakai, X. Hu, L. N. Zakharov, A. L Rheingotd, K. Meyer, Inorg. Chem. 43, 855 (2004).
20. See supporting material on Science Online.
21. 3, Z = 4, R = 0.0529, wR2 = 0.1191.
22. I. Castro-Rodriguez, K. Olsen, P. Gantzel, K. Meyer, J. Am. Chem. Soc. 125, 4565 (2003).
23. I. Castro-Rodriguez, K. Olsen, P. Gantzel, K. Meyer, Chem. Commun. 2002, 2764 (2002).
24. J. J. Katz, L. R. Morss, G. T. Seaborg, The Chemistry of the Actinide Elements (Chapman & Hall, New York, 1980).
25. Supported by the University of California, San Diego, and U.S. Department of Energy grant DE-FG02-04ER15537, We thank W. L. S. Andrews and N. Edelstein for insightful discussions and NIH for a fellowship to I.C.R. (3 T32 DK07233-2651). K.M. is an Alfred P. Sloan fellow. Crystallographic data were deposited in the Cambridge Crystallographic Database Centre (2: CCDC-244303; 3: CCDC-244304).