Electrophilicities of benzaldehyde-derived iminium ions: Quantification of the electrophilic activation of aldehydes by iminium formation

Journal of the American Chemical Society

Volumn 135, Issue 17, 2013, Pages 6579-6587

  Appel, Roland ^a   Chelli, Saloua ^a   Tokuyasu, Takahiro ^a   Troshin, Konstantin ^a   Mayr, Herbert ^a  

^a UNIVERSITY OF MUNICH   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

ELECTROPHILIC ACTIVATION; ELECTROPHILICITIES; ELECTROPHILICITY; ENOL ETHERS; IMINIUM IONS; KETENE ACETALS; ORDERS OF MAGNITUDE; TRANSITION STATE;

ALDEHYDES; AMINES; CHEMICAL COMPOUNDS; RATE CONSTANTS;

IONS;

ACETAL DERIVATIVE; ACETONITRILE DERIVATIVE; BENZALDEHYDE; CATION; ENAMINE; ETHER DERIVATIVE; KETENE DERIVATIVE; WATER;

ARTICLE; CHEMICAL REACTION; CHEMICAL STRUCTURE; CORRELATION ANALYSIS; ELECTROPHILICITY; ELIMINATION REACTION; KINETICS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; PARAMETERS; QUANTITATIVE ASSAY; SUBSTITUTION REACTION; X RAY ANALYSIS;

EID: 84877028148     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja401106x     Document Type: Article

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