Divergent cyclizations of 1-R-ethynyl-9,10-anthraquinones: Use of thiourea as a "s2-" equivalent in an "anchor-relay" addition mediated by formal C-H activation

Journal of Organic Chemistry

Volumn 78, Issue 5, 2013, Pages 2074-2082

  Baranov, Denis S ^a   Gold, Brian ^b   Vasilevsky, Sergei F ^a   Alabugin, Igor V ^b  

^a INSTITUTE OF CHEMICAL KINETICS AND COMBUSTION   (Russian Federation)

^b FLORIDA STATE UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ACTIVATION ANALYSIS; CHEMICAL ACTIVATION; HYDROCARBONS; KETONES; NUCLEOPHILES; QUINONE; SODIUM SULFIDE; THIOPHENE; THIOUREAS; UREA;

DFT COMPUTATIONS; ELECTRON-DEFICIENT; FIVE-MEMBERED HETEROCYCLES; FUSED THIOPHENE; MEDIATED REACTIONS; NUCLEOPHILIC ATTACK; PREFUNCTIONALIZATION; SELECTIVE SYNTHESIS;

CYCLIZATION;

ALKYNE; ANION; ANTHRAQUINONE DERIVATIVE; CARBON; CARBONYL DERIVATIVE; GUANIDINE; HYDRAZINE; HYDROGEN; SODIUM SULFIDE; THIOPHENE; THIOUREA; UREA;

ADDITION REACTION; AROMATIZATION; ARTICLE; COMPUTATIONAL FLUID DYNAMICS; CYCLIZATION; NUCLEOPHILICITY; OXIDATION;

EID: 84874585928     PISSN: 00223263     EISSN: 15206904     Source Type: Journal    
DOI: 10.1021/jo302146r     Document Type: Article

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