Cleavage of DNA by proton-coupled electron transfer to a photoexcited, hydrated Ru(II) 1,10-phenanthroline-5,6-dione complex

Journal of the American Chemical Society

Volumn 135, Issue 7, 2013, Pages 2419-2422

  Poteet, Steven A ^a   Majewski, Marek B ^b   Breitbach, Zachary S ^a   Griffith, Cynthia A ^a   Singh, Shreeyukta ^a   Armstrong, Daniel W ^a   Wolf, Michael O ^b   MacDonnell, Frederick M ^a  

^a UNIVERSITY OF TEXAS AT ARLINGTON   (United States)

^b UNIVERSITY OF BRITISH COLUMBIA   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

1 ,10-PHENANTHROLINE-5 ,6-DIONE; BASIC SITES; CARBONYL FUNCTION; COMPLEX 1; DEPROTONATED FORM; DNA CLEAVAGE; DNA SCISSION; ENERGY GAP LAW; FLUORESCENCE MEASUREMENTS; H-ATOM ABSTRACTION; NMR ANALYSIS; NONRADIATIVE DECAYS; OXYGEN SITE; PHOTOPHYSICAL PROPERTIES; PROTON ACCEPTORS; PROTON-COUPLED ELECTRON TRANSFER; RADICAL ANIONS; RU(PHEN); RUTHENIUM COMPLEXES; SMALL MOLECULES; SUGAR MOIETY; TRANSIENT ABSORPTION SPECTROSCOPIES; VISIBLE-LIGHT IRRADIATION;

ACETONITRILE; BYPRODUCTS; DNA; ELECTRON TRANSITIONS; ENERGY GAP; FREE RADICAL REACTIONS; HYDRATES; HYDRATION; OXYGEN; PROTONS; RUTHENIUM;

RUTHENIUM COMPOUNDS;

ACETONITRILE; OXYGEN; QUINONE DERIVATIVE; RUTHENIUM 1,10 PHENANTHROLINE 5,6 DIONE COMPLEX; RUTHENIUM COMPLEX; UNCLASSIFIED DRUG;

ABSORPTION SPECTROSCOPY; ARTICLE; DECOMPOSITION; DNA CLEAVAGE; ELECTRON TRANSPORT; ENERGY; FLUORESCENCE; HYDRATION; LIGHT EXPOSURE; LUMINESCENCE; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; PHOTOACTIVATION; PHOTOCHEMISTRY; PROTON COUPLED ELECTRON TRANSFER; PROTON TRANSPORT;

COORDINATION COMPLEXES; DNA; ELECTRONS; MOLECULAR STRUCTURE; RUTHENIUM; WATER;

EID: 84874045980     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja3106863     Document Type: Article

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