Mechanism of hydrogenolysis of an iridium-methyl bond: Evidence for a methane complex intermediate

Journal of the American Chemical Society

Volumn 135, Issue 4, 2013, Pages 1217-1220

  Campos, Jesús ^a   Kundu, Sabuj ^b   Pahls, Dale R ^c   Brookhart, Maurice ^b   Carmona, Ernesto ^a   Cundari, Thomas R ^c  

^a INSTITUTO DE INVESTIGACIONES QUÍMICAS   (Spain)

^b University of North Carolina at Chapel Hill   (United States)

^c UNIVERSITY OF NORTH TEXAS   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

DENSITY FUNCTIONAL THEORY CALCULATIONS; METHANE LOSS; METHYL GROUP; REVERSIBLE FORMATION; TRANSITION STATE;

DENSITY FUNCTIONAL THEORY; DEUTERIUM; HYDROGEN; HYDROGENOLYSIS; HYDROLYSIS; IRIDIUM COMPOUNDS; METHANE;

IRIDIUM;

2,6 BIS(DI TERTBUTYLPHOSPHINITO)PYRIDINE; DEUTERIUM; HYDROGEN; IRIDIUM; METHANE; PYRIDINE; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL BOND; CHEMICAL REACTION; DENSITY FUNCTIONAL THEORY; HYDROGEN BOND; HYDROGENOLYSIS;

HYDROGEN; HYDROGENATION; IRIDIUM; METHANE; MOLECULAR STRUCTURE; ORGANOMETALLIC COMPOUNDS; QUANTUM THEORY;

EID: 84873836229     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja310982v     Document Type: Article

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