Covalency in metal-oxygen multiple bonds evaluated using oxygen K-edge spectroscopy and electronic structure theory

Journal of the American Chemical Society

Volumn 135, Issue 5, 2013, Pages 1864-1871

  Minasian, Stefan G ^a,b   Keith, Jason M ^a   Batista, Enrique R ^a   Boland, Kevin S ^a   Bradley, Joseph A ^c   Daly, Scott R ^a   Kozimor, Stosh A ^a   Lukens, Wayne W ^b   Martin, Richard L ^a   Nordlund, Dennis ^d   Seidler, Gerald T ^e   Shuh, David K ^b   Sokaras, Dimosthenis ^d   Tyliszczak, Tolek ^b   Wagner, Gregory L ^a   Weng, Tsu Chein ^d   Yang, Ping ^f  

^a LOS ALAMOS NATIONAL LABORATORY   (United States)

^b LAWRENCE BERKELEY NATIONAL LABORATORY   (United States)

^c LAWRENCE LIVERMORE NATIONAL LABORATORY   (United States)

^d SLAC NATIONAL ACCELERATOR LABORATORY   (United States)

^e UNIVERSITY OF WASHINGTON   (United States)

^f PACIFIC NORTHWEST NATIONAL LABORATORY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

BONDING THEORY; COVALENCIES; D ORBITALS; ELECTRONIC STRUCTURE THEORY; INELASTIC X RAY SCATTERING; MULTIPLE BONDS; NONRESONANT; ORBITAL ENERGY; ORBITAL MIXING; ORBITALS; OXYGEN K-EDGE; TIME DEPENDENT DENSITY FUNCTIONAL THEORY;

CHEMICAL BONDS; DENSITY FUNCTIONAL THEORY; ELECTRONIC STRUCTURE; MANGANESE; MIXING; MOLYBDENUM; OXYGEN; RHENIUM; SPECTROSCOPIC ANALYSIS; TRANSITION METALS; X RAY ABSORPTION SPECTROSCOPY; X RAY MICROSCOPES;

CHROMIUM;

MANGANESE; OXYGEN; RHENIUM; TECHNETIUM;

ARTICLE; CHEMICAL ANALYSIS; CHEMICAL REACTION; CHEMICAL STRUCTURE; COVALENT BOND; ENERGY; FLUORESCENCE MICROSCOPY; METAL BINDING; MICROSCOPE; RADIATION SCATTERING; SCANNING TRANSMISSION ELECTRON MICROSCOPY; TRANSMISSION ELECTRON MICROSCOPY; X RAY ABSORPTION SPECTROSCOPY;

ELECTRONS; METALS, HEAVY; MICROSCOPY, ELECTRON, SCANNING TRANSMISSION; MOLECULAR STRUCTURE; OXYGEN; QUANTUM THEORY; X-RAY ABSORPTION SPECTROSCOPY; X-RAYS;

EID: 84873331284     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja310223b     Document Type: Article

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