Mechanistic studies into amine-mediated electrophilic arene borylation and its application in MIDA boronate synthesis

Journal of the American Chemical Society

Volumn 135, Issue 1, 2013, Pages 474-487

  Bagutski, Viktor ^a,c   Del Grosso, Alessandro ^a   Carrillo, Josue Ayuso ^a   Cade, Ian A ^a   Helm, Matthew D ^a   Lawson, James R ^a   Singleton, Paul J ^a,d   Solomon, Sophia A ^a,e   Marcelli, Tommaso ^b   Ingleson, Michael J ^a  

^a UNIVERSITY OF MANCHESTER   (United Kingdom)

^b POLITECNICO DI MILANO   (Italy)

^c DARMSTADT UNIVERSITY OF TECHNOLOGY   (Germany)

^d Apollo Scientific   (United Kingdom)

^e UNIVERSITY OF CAMBRIDGE   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

ADDUCT FORMATION; BORONATE; BORYLATION; CATION INTERMEDIATES; COMPUTATIONAL STUDIES; ELECTROPHILES; FREE AMINES; FUNCTIONALIZATIONS; HETEROARENES; HIGH TEMPERATURE; MECHANISTIC STUDIES; REACTION PATHWAYS; TERTIARY AMINE; TO EFFECT; TRANSMETALATION;

AROMATIC COMPOUNDS; BORON; DEPROTONATION; TOLUENE;

POSITIVE IONS;

ACETIC ACID DERIVATIVE; ALUMINUM CHLORIDE; BORON; BORONIC ACID DERIVATIVE; CATION; N METHYL IMINODIACETIC ACID; POLYCYCLIC AROMATIC HYDROCARBON; TERTIARY AMINE; UNCLASSIFIED DRUG;

ARTICLE; BORYLATION; CHEMICAL MODIFICATION; DISSOCIATION; ELECTROPHILICITY; HIGH TEMPERATURE; ISOMERIZATION; NUCLEOPHILICITY; REACTION ANALYSIS; SYNTHESIS;

AMINES; BORON COMPOUNDS; HYDROCARBONS, AROMATIC; IMINO ACIDS; MODELS, MOLECULAR; MOLECULAR STRUCTURE;

EID: 84872109056     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja3100963     Document Type: Article

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