Mechanistic investigation of the ruthenium-N-heterocyclic-carbene-catalyzed amidation of amines with alcohols

Chemistry - A European Journal

Volumn 18, Issue 49, 2012, Pages 15683-15692

  Makarov, Ilya S ^a   Fristrup, Peter ^a   Madsen, Robert ^a  

^a TECHNICAL UNIVERSITY OF DENMARK   (Denmark)

Author keywords

amides; density functional calculations; isotope effect; reaction mechanisms; ruthenium

Indexed keywords

AMIDATION; BENZYLIC; C-H BOND; CATALYTIC CYCLES; CATALYTICALLY ACTIVE SPECIES; COMPUTATIONAL STUDIES; DIHYDRIDES; EXPERIMENTAL TECHNIQUES; HYDRIDE ELIMINATION; ISOTOPE EFFECT; KINETIC ISOTOPE EFFECTS; NUCLEOPHILIC ATTACK; POSITIVE CHARGES; RATE-LIMITING STEPS; REACTION MECHANISM; THEORETICAL INVESTIGATIONS; TRANSITION STATE; TURNOVER FREQUENCY;

AMIDES; AMINES; CARRIER MOBILITY; CATALYSIS; DENSITY FUNCTIONAL THEORY; DEUTERIUM; HYDRIDES; HYDROGEN; RUTHENIUM;

RUTHENIUM COMPOUNDS;

EID: 84870033118     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.201202400     Document Type: Article

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