A thermodynamic and kinetic study of the heterolytic activation of hydrogen by frustrated borane-amine Lewis pairs

Dalton Transactions

Volumn 42, Issue 3, 2013, Pages 615-619

  Karkamkar, Abhi ^a   Parab, Kshitij ^a   Camaioni, Donald M ^a   Neiner, Doinita ^a   Cho, Herman ^a   Nielsen, Thomas K ^b   Autrey, Tom ^a  

^a PACIFIC NORTHWEST NATIONAL LABORATORY   (United States)

^b AARHUS UNIVERSITY   (Denmark)

Author keywords

[No Author keywords available]

Indexed keywords

BROMOBENZENE; DATIVE BONDS; FUNCTION OF TIME; HALF LIVES; HEAT RELEASE; IONIC PAIRS; KINETIC STUDY; LEWIS ACID; LEWIS BASE; REACTION ENTHALPIES; RELATIVE RATES; STERICS; TRIS(PENTAFLUOROPHENYL) BORANE;

ENTHALPY; HYDROGEN; HYDROGENATION; PYRIDINE; TOLUENE;

THERMOMECHANICAL PULPING PROCESS;

EID: 84869425193     PISSN: 14779226     EISSN: 14779234     Source Type: Journal    
DOI: 10.1039/c2dt31628e     Document Type: Article

References (28)

1. G. C. Welch R. R. S. Juan J. D. Masuda D. W. Stephan Science 2006 314 1124
2. D. W. Stephan S. Greenberg T. W. Graham P. Chase J. J. Hastie S. J. Geier J. M. Farrell C. C. Brown Z. M. Heiden G. C. Welch M. Ullrich Inorg. Chem. 2011 40 12338
3. T. J. Herrington A. J. W. Thom A. J. P. White A. E. Ashley Dalton Trans. 2012 41 9019
4. D. W. Stephan Dalton Trans. 2012 41 9015
5. S. J. Geier D. W. Stephan J. Am. Chem. Soc. 2009 131 3476
6. P. A. Chase G. C. Welch T. Junea G. Erker D. W. Stephan Angew. Chem., Int. Ed. 2007 46 8050
7. V. Sumerin F. Schulz M. Nieger M. Leskel T. Repo B. Rieger Angew. Chem., Int. Ed. 2008 47 6001
8. G. Ers H. Mehdi I. Pápai T. A. Rokob P. Király G. Tárkányi T. Soós Angew. Chem., Int. Ed. 2010 49 6559
9. F. Bertini V. Lyaskovskyy B. J. J. Timmer F. J. J. de Kanter M. Lutz A. W. Ehlers J. C. Slootweg K. Lammertsma J. Am. Chem. Soc. 2012 134 201
10. W. E. Piers A. J. V. Marwitz L. G. Mercier Inorg. Chem. 2011 40 12252
11. S. Grimme H. Kruse L. Goerigk G. Erker Angew. Chem., Int. Ed. 2010 49 1402
12. D. M. Camaioni B. Ginovska-Pangovska G. K. Schenter S. M. Kathmann T. Autrey J. Phys. Chem. A 2012 116 7228
13. R. C. Neu E. Y. Ouyang S. J. Geier X. Zhao A. Ramos D. W. Stephan Dalton Trans. 2010 39 4285
14. S. Kronig E. Theuergarten D. Holschumacher T. Bannenberg C. G. Daniliuc P. G. Jones M. Tamm Inorg. Chem. 2011 50 7344
15. T. A. Rokob A. Hamza I. Pápai J. Am. Chem. Soc. 2009 131 10701
16. P. Pyykko C. Wang Phys. Chem. Chem. Phys. 2010 12 149
17. T. Autrey M. Bowden A. Karkamkar Faraday Discuss. 2011 151 157
18. -1 from mixing TMP and BCF. This is comparable to the independent heats of dilution of the Lewis acid and Lewis base in bromobenzene.
19. D. Wu D. Jia L. Liu L. Zhang J. Guo J. Phys. Chem. A 2010 114 11738
20. R. G. Potter D. M. Camaioni M. Vasiliu D. A. Dixon Inorg. Chem. 2010 49 10512
21. 2 in toluene.
22. C. M. Mömming E. Otten G. Kehr R. Fröhlich S. Grimme D. W. Stephan G. Erker Angew. Chem., Int. Ed. 2009 48 6643
23. Calculated gas phase enthalpies were obtained from supplemental material in ref. 14. Correction of the gas phase enthalpy values for solvation effects may not be as large as the free energy corrections.
24. C. LeBlond J. Wang R. D. Larsen C. J. Orella A. L. Forman R. N. Landau J. Laquidara J. R. Sowa, Jr. D. G. Blackmond Y.-K. Sun Thermochim. Acta 1996 189
25. D. G. Blackmond Angew. Chem., Int. Ed. 2005 44 4302
26. C. W. Hansen L. D. Hansen A. D. Nicholson M. C. Chilton N. Thomas J. Clark J. C. Hansen Int. J. Chem. Kinet. 2011 43 53
27. E. Calvet, in Experimental Thermochemistry, ed., H. A. Skinner, Interscience, New York, 1962, vol. 2, pp. 385-410
28. 2 dissolved in 4 mL PhBr at 294 K.