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Volumn 999, Issue , 2012, Pages 74-82

A computational study on the competing intramolecular amidation and aziridination reactions catalyzed by dirhodium tetracarboxylate

Author keywords

Amidation; Aziridination; Density functional calculation; Dirhodium tetracarboxylate

Indexed keywords


EID: 84869082792     PISSN: 2210271X     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.comptc.2012.08.016     Document Type: Article
Times cited : (9)

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    • Analysis of the Rh(1)Rh(2)N(3) bonding system with ligand field theory (see Figure 1S in the supplementary data) one may found that there are delocalized Π bonds formed from Rh(4d), Rh(4d) and N(2p) orbitals for all singlet and triplet diRh-nitrene complexes and product complexes. Therefore the singly occupied electron is on a delocalized Π bond, leading to the spin
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* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.