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Volumn , Issue 31, 2012, Pages 6140-6143

An alternative reaction outcome in the gold-catalyzed rearrangement of 1-alkynyloxiranes

Author keywords

Alkynes; Gold; Oxophilicity; Oxygen heterocycles; Rearrangement

Indexed keywords


EID: 84867820977     PISSN: 1434193X     EISSN: 10990690     Source Type: Journal    
DOI: 10.1002/ejoc.201201191     Document Type: Article
Times cited : (15)

References (53)
  • 1
    • 0000496226 scopus 로고    scopus 로고
    • (Eds.:, E. N. Jacobsen, A. Pfaltz, H. Yamamoto), Springer, New York
    • E. N. Jacobsen, M. H. Wu in Comprehensive Asymmetric Catalysis (Eds.:, E. N. Jacobsen, A. Pfaltz, H. Yamamoto), Springer, New York, 1999, vol. 3, pp. 1309-1326.
    • (1999) Comprehensive Asymmetric Catalysis , vol.3 , pp. 1309-1326
    • Jacobsen, E.N.1    Wu, M.H.2
  • 25
    • 79953192510 scopus 로고    scopus 로고
    • For an indium-catalyzed reaction, which is proposed to occur through a distinct mechanism, see:, J. Y. Kang, B. T. Connell, J. Org. Chem. 2011, 76, 2379.
    • (2011) J. Org. Chem. , vol.76 , pp. 2379
    • Kang, J.Y.1    Connell, B.T.2
  • 30
    • 37249012791 scopus 로고    scopus 로고
    • 3)AuCl] did not promote this reaction. Trifluoromethanesulfonic acid (TfOH) proved active, albeit in lower yield and reproducibility (40-50 %). For analogous reactivity of gold and TfOH, see for example:, T. Jin, Y. Yamamoto, Org. Lett. 2007, 9, 5259.
    • (2007) Org. Lett. , vol.9 , pp. 5259
    • Jin, T.1    Yamamoto, Y.2
  • 38
    • 53849089263 scopus 로고    scopus 로고
    • B. Crone, S. F. Kirsch, Chem. Eur. J. 2008, 14, 3514 for a review on gold-catalyzed ring expansion, see
    • (2008) Chem. Eur. J. , vol.14 , pp. 3514
    • Crone, B.1    Kirsch, S.F.2


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.