Photoinduced dynamics of oxyluciferin analogues: Unusual enol "super"photoacidity and evidence for keto-enol isomerization

Journal of the American Chemical Society

Volumn 134, Issue 40, 2012, Pages 16452-16455

  Solntsev, Kyril M ^a   Laptenok, Sergey P ^b,c   Naumov, Panče ^d,e  

^a GEORGIA INSTITUTE OF TECHNOLOGY   (United States)

^b LABORATOIRE D OPTIQUE ET BIOSCIENCES   (France)

^c INSERM   (France)

^d NEW YORK UNIVERSITY ABU DHABI   (United Arab Emirates)

^e KYOTO UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

CHEMICALLY MODIFIED; ENOLATES; EXCITED-STATE PROTON TRANSFER; EXPERIMENTAL EVIDENCE; NON-POLAR; PHENOL GROUPS; PHOTOACIDITY; PHOTOACIDS; PHOTOINDUCED DYNAMICS; STABLE ENOL; TAUTOMERIZATIONS; TIME-RESOLVED SPECTROSCOPIC STUDIES;

DIMETHYL SULFOXIDE; EXCITED STATES; OLEFINS; PHENOLS; SPECTROSCOPIC ANALYSIS;

BIOLUMINESCENCE;

DIMETHYL SULFOXIDE; LUCIFERIN; OXYLUCIFERIN DERIVATIVE; PROTON; UNCLASSIFIED DRUG; WATER;

ARTICLE; CHEMICAL ANALYSIS; EVIDENCE BASED MEDICINE; FIREFLY; ISOMERIZATION; MOLECULAR DYNAMICS; PROTON TRANSPORT; SPECTROSCOPY; TAUTOMERIZATION;

ANIMALS; FIREFLIES; INDOLES; ISOMERISM; LUMINESCENT AGENTS; PROTONS; PYRAZINES; SPECTROMETRY, FLUORESCENCE; WATER;

EID: 84867366650     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja3045212     Document Type: Article

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