Excited-state proton transfer: From constrained systems to "super" photoacids to superfast proton transfer

Accounts of Chemical Research

Volumn 35, Issue 1, 2002, Pages 19-27

  Tolbert, Laren M ^a   Solntsev, Kyril M ^a  

^a GEORGIA INSTITUTE OF TECHNOLOGY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ACID; HYDROGEN; ORGANIC SOLVENT; PROTON;

ACIDITY; ARTICLE; CHEMICAL STRUCTURE; DIFFUSION; DISSOCIATION; ELECTRONICS; EXCITATION; HYDROGEN BOND; MOLECULE; PROTON TRANSPORT; TIME;

EID: 0036149612     PISSN: 00014842     EISSN: None     Source Type: Journal    
DOI: 10.1021/ar990109f     Document Type: Article

References (56)

1. Acid - Base properties of electronically excited stated of organic molecules
2. Excited-state proton-transfer reactions and proton-induced quenching of aromatic compounds
3. Excited-state proton transfer reactions. I. Fundamentals and intermolecular reactions
4. Quantitative untersuchungen der fluoreszenzumwandlung bei naphtholen
5. Acid - Base chemistry of excited singlet states
6. The photoexcited states of allyl anions
7. Utility of acid - Base behavior of excited-states of organic-molecules
8. Photo- and radiation chemical induced degradation of lignin model compounds
9. Geminate recombination in excited-state proton-transfer reactions: Numerical solution of the Debye - Smoluchowski equation with backreaction and comparison with experimental results
10. Temperature dependence of excited-state proton transfer and geminate recombination processes in water and in glycerol-doped ice
11. Primary ultrafast events preceding the photoinduced proton transfer from pyranine to water
12. Intermolecular excited-state proton transfer in clusters of 1-naphthol with water and with ammonia
13. Picosecond kinetics of the excited-state, proton-transfer reaction of 1-naphthol with water
14. Relaxation of solvate environment and degradation of electron excitation energy during proton phototransfer in complexes with hydrogen bonds
15. Solvatochromism of β-Naphthol
16. b dual state emission in 1-naphthol and 1-methoxynaphthalene fluorescence in liquid solutions
17. Solvent dependence of pyranine fluorescence and UV-visible absorption spectra
18. Linear solvation energy relationships. 23. A comprehensive collection of the solvatrochromic parameters, π*, α, and β and some methods for simplifying the generated solvatochromic equation
19. Subpicosecond measurements of polar solvation dynamics - Coumarin-153 revisited
20. Solvation ultrafast dynamics of reactions. 8. Acid - Base reactions in finite-sized clusters of naphthol in ammonia, water, and piperidine
21. Ultrafast structural response of hydrogen bonded complexes to electronic excitation in the liquid phase
22. Isotope effect on weak acid dissociation
23. Proton transfer in mixed water-organic solvent solutions: Correlation between rate, equilibrium constant, and the proton free energy of transfer
24. Excited-state proton transfer to methanol - Water mixtures
25. HCI acid ionization in water - A theoretical molecular modeling
26. Excited-state proton-transfer from hydroxyalkylnaphthols
27. Primary events in photoacid dissociation
28. Rate constants of protolytic reactions in aqueous solutions
29. Observation of geminate recombination in excited-state proton transfer
30. Spherical symmetric diffusion problem
31. Self-quenching of 1-naphthol. Connection between time-resolved and steady-state measurements
32. Excited-state reversible geminate reaction. I. Two different lifetimes
33. n
34. Time- and internal energy-dependent fluorescence spectra of 1-naphthol·water clusters
35. Photoexcited proton-transfer from enhanced photoacids
36. Isotope and temperature effects in ultrafast proton-transfer from a strong excited-state acid
37. Direct measurement of intrinsic proton-transfer rates in diffusion-controlled reactions
38. Ultrafast direct photoacid - Base reaction
39. Enhanced photoacidities of cyanonaphthols
40. Molecular beam studies of the "Super" photoacid 5-cyano-2-naphthol in solvent clusters
41. Photochemistry of "Super"-photoacids. Solvent effects
42. Solvatochromic shifts of "Super" photoacids
43. Ultrafast excited-state proton-transfer from cyano-substituted 2-naphthols
44. Excited-state proton transfer in bifunctional compounds
45. Hydrogen bonding and cooperativity effects on the assembly of alkyl- and perfluoroalkyl-sulfonyl naphthols: F···F non-bonded interactions
46. Evidence for a continuous transition from nonadiabatic to adiabatic proton-transfer dynamics in protic liquids
47. Photochemistry of "Super" photoacids. 2. Excited-state proton transfer in methanol/water mixtures
48. Dual asymptotic behavior in geminate diffusion-influenced reaction
49. Experimental evidence for kinetic transition in reversible reaction