Reactions of titanocene bis(trimethylsilyl)acetylene complexes with carbodiimides: An experimental and theoretical study of complexation versus C-N bond activation

Journal of the American Chemical Society

Volumn 134, Issue 38, 2012, Pages 15979-15991

  Haehnel, Martin ^a   Ruhmann, Martin ^a   Theilmann, Oliver ^a   Roy, Subhendu ^b   Beweries, Torsten ^a   Arndt, Perdita ^a   Spannenberg, Anke ^a   Villinger, Alexander ^a   Jemmis, Eluvathingal D ^b,c   Schulz, Axel ^a   Rosenthal, Uwe ^a  

^a UNIVERSITY OF ROSTOCK   (Germany)

^b INDIAN INSTITUTE OF SCIENCE   (India)

^c INDIAN INSTITUTE OF SCIENCE EDUCATION AND RESEARCH   (India)

Author keywords

[No Author keywords available]

Indexed keywords

ACETYLENE COMPLEX; BOND ACTIVATION; C-C COUPLING; CARBODIIMIDES; CYCLOPENTADIENYLS; LOW-VALENT; PENTAMETHYLCYCLOPENTADIENYL; PRODUCT COMPLEX; STERIC EFFECT; THEORETICAL STUDY; TITANOCENES; TRIMETHYLSILYL;

ORGANOMETALLICS; SILICON CARBIDE; TITANIUM;

ACETYLENE;

CYANAMIDE; METAL COMPLEX; TITANIUM; TITANOCENE BIS(TRIMETHYLSILYL)ACETYLENE COMPLEX; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL BOND; CHEMICAL REACTION; COMPLEX FORMATION; EXPERIMENTAL STUDY; ISOMERIZATION; THEORETICAL STUDY;

EID: 84866699491     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja3070649     Document Type: Article

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