Bimetallic complexes of metallacyclopentynes: Cis versus trans and planarity versus nonplanarity

Organometallics

Volumn 26, Issue 9, 2007, Pages 2149-2156

  Bach, Marc A ^a   Parameswaran, Pattiyil ^b   Jemmis, Eluvathingal D ^b   Rosenthal, Uwe ^a  

^a UNIVERSITY OF ROSTOCK   (Germany)

^b INDIAN INSTITUTE OF SCIENCE   (India)

Author keywords

[No Author keywords available]

Indexed keywords

BIMETALS; CHEMICAL BONDS; DENSITY FUNCTIONAL THEORY; ELECTRONS; NICKEL COMPOUNDS; REACTION KINETICS;

HOMODIMETALLABICYCLES; ISODESMIC EQUATIONS; LEWIS BASE; METAL FRAGMENTS; METALLACYCLOPENTYNES;

ORGANOMETALLICS;

EID: 34248338784     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om061030z     Document Type: Article

References (56)

1. Beckhaus, R. In Metallocenes - Synthesis, Reactivity, Applications; Togni, A., Halterman, R. L., Eds.; Wiley-VCH: Weinheim, 1998; Vol. 1, Chapter 4, p 153, and references therein.
2. Negishi, E.; Montchamp, J.-L. In Metallocenes - Synthesis, Reactivity, Applications; Togni, A., Halterman, R. L., Eds.; Wiley-VCH: Weinheim, 1998; Vol. 1, Chapter 5, p 241, and references therein.
3. Rosenthal, U. Angew. Chem. 2004, 116, 3972;
4. Angew. Chem., Int. Ed. 2004, 43, 3882.
5. (a) Rosenthal, U.; Burlakov, V. V.; Arndt, P.; Baumann, W.; Spannenberg, A. Organometallics 2005, 24, 456, and references therein.
6. (b) Jemmis, E. D.; Phukan, A. K.; Jiao, H.; Rosenthal, U. Organometallics 2003, 22, 4958.
7. (a) Pulst, S.; Arndt, P.; Heller, B.; Baumann, W.; Kempe, R.; Rosenthal, U. Angew. Chem. 1996, 108, 1175;
8. Angew. Chem., Int. Ed. 1996, 35, 1112.
9. (b) Bach, M. A.; Burlakov, V. V.; Arndt, P.; Baumann, W.; Spannenberg, A.; Rosenthal, U. Organometallics 2005, 24, 3047.
10. (a) Pavan Kumar, P. N. V.; Jemmis, E. D. J. Am. Chem. Soc. 1988, 110, 125.
11. (b) Jemmis, E. D.; Giju, K. T. Angew. Chem. 1997, 109, 633;
12. Angew. Chem., Int. Ed. 1997, 36, 606.
13. (c) Jemmis, E. D.; Parameswaran, P.; Phukan, A. K. Mol. Phys. 2005, 103, 897.
14. (a) Suzuki, N.; Aihara, N.; Takahara, H.; Watanabe, T.; Iwasaki, M.; Saburi, M.; Hashizume, D.; Chihara, T. J. Am. Chem. Soc. 2004, 126, 60.
15. (b) Suzuki, N.; Watanabe, T.; Iwasaki, M.; Chihara, T. Organometallics 2005, 24, 2065.
16. (a) Summerscales, O. T.; Cloke, F. G. N.; Hitchcock, P. B.; Green, J. C.; Hazari, N. Science 2006, 311, 829.
17. (b) Summerscales, O. T.; Cloke, F. G. N.; Hitchcock, P. B.; Green, J. C.; Hazari, N. J. Am. Chem. Soc. 2006, 128, 9602.
18. Hehre, W.; Radom, L.; Schleyer, P. v. R.; Pople, J. A. Ab Initio Molecular Orbital Theory; Wiley: New York, 1986.
19. (a) Becke, A. D. J. Chem. Phys. 1993, 98, 5648.
20. (b) Becke, A. D. Phys. Rev. A 1988, 38, 3098.
21. (c) Lee, C.; Yang, W.; Parr, R. G. Phys. Rev. B 1988, 37, 785.
22. (a) Hay, P. J.; Wadt, W. R. J. Chem. Phys. 1985, 82, 270.
23. (b) Wadt, W. R.; Hay, P. J. J. Chem. Phys. 1985, 82, 284.
24. (c) Hay, P. J.; Wadt, W. R. J. Chem. Phys. 1985, 82, 299.
25. Frisch, M. J.; Pople, J. A.; et al. Gaussian 03, Revision C.02; Gaussian, Inc.: Wallingford, CT, 2004.
26. Jemmis, E. D.; Giju, K. T. J. Am. Chem. Soc. 1998, 120, 6952.
27. (a) ADF2005.01; SCM, Theoretical Chemistry, Vrije Universiteit: Amsterdam, The Netherlands, http://www.scm.com.
28. (b) te Velde, G.; Bickelhaupt, F. M.; Baerends, E. J.; Fonseca Guerra, C.; van Gisbergen, S. J. A.; Snijders, J. G.; Ziegler, T. J. Comput. Chem. 2001, 22, 931.
29. (c) Fonseca Guerra, C.; Snijders, J.; te Velde, G.; Baerends, E. J. Theor. Chem. Acc. 1998, 99, 391.
30. Perdew, J. P. Phys. Rev. B 1986, 33, 8822.
31. (a) Snijders, J. G.; Baerends, E. J. Mol. Phys. 1978, 36, 1789.
32. (b) Snijders, J. G.; Baerends, E J.; Ros, P. Mol. Phys. 1979, 38, 1909.
33. (a) Jemmis, E. D.; Phukan, A. K.; Giju, K. T. Organometallics 2002, 21, 2254.
34. (b) Lam, K. C.; Lin, Z. Organometallics 2003, 22, 3466.
35. (c) Hashizume, D.; Suzuki, N.; Chihara, T. Chem. Commun. 2006, 1233.
36. (a) Reed, A. E.; Weinstock, R. B.; Weinhold, F. J. Chem. Phys. 1985, 83, 735.
37. (b) Reed, A. E.; Weinhold, F. J. Chem. Phys. 1985, 83, 1736.
38. (c) Reed, A. E.; Curtiss, L. A.; Weinhold, F. Chem. Rev. 1988, 88, 899.
39. Rosenthal, U.; Pellny, P.-M.; Kirchbauer, F. G.; Burlakov, V. V. Acc. Chem. Res. 2000, 33, 119.
40. (a) Giju, K. T.; Phukan, A. K.; Jemmis, E. D. Angew. Chem. 2003, 115, 557;
41. Angew. Chem., Int. Ed. 2003, 42, 539.
42. (b) Srinivas, G. N.; Anoop, A.; Jemmis, E. D.; Hamilton, T. P.; Lammertsma, K.; Leszczynski, J.; Schaefer, H. F., III. J. Am. Chem. Soc. 2003, 125, 16397.
43. (c) Jemmis, E. D.; Parameswaran, P. Chem. - Eur. J. 2007, 13, 2622.
44. (a) Wagner, H. U.; Szeimies, G.; Chandrasekhar, J.; Schleyer, P. v. R.; Pople, J. A.; Binkley, J. S. J. Am. Chem. Soc. 1978, 100, 1210.
45. (b) Wiberg, K. B.; Bonneville, G. Tetrahedron Lett. 1982, 23, 5385.
46. (c) Andersen, R. A.; Galyer, A. L.; Wilkinson, G. Angew. Chem. 1976, 88, 692;
47. Angew. Chem., Int. Ed. Engl. 1976, 15, 609.
48. (d) Chisholm, M. H.; Cotton, F. A.; Extine, M.; Murrilo, C. A. Inorg. Chem. 1978, 17, 696.
49. (e) Cotton, F. A.; Schwotzer, W.; Shamshoum, E. S. Organometallics 1983, 2, 1167.
50. (f) Chisholm, M. H.; Huffman, J. C.; Heppert, J. A. J. Am. Chem. Soc. 1985, 107, 5116.
51. Jemmis, E. D.; Giju, K. T. Organometallics 1997, 16, 1425.
52. Burlakov, V. V.; Arndt, P.; Baumann, W.; Spannenberg, A.; Rosenthal, U.; Parameswaran, P.; Jemmis, E. D. Chem. Commun. 2004, 2074.
53. Hessen, B.; Blenkers, J.; Teuben, J. H.; Helgesson, G.; Jagner, S. Organometallics 1989, 8, 830.
54. Lentz, D.; Brüdgam, I.; Hartl, H. Angew. Chem. 1984, 96, 511;
55. Angew. Chem., Int. Ed. Engl. 1984, 23, 525.
56. Rosenthal, U.; Burlakov, V. V.; Bach, M. A.; Beweries, T. Chem. Soc. Rev., in press (DOI: 10.1039/b605734a).