A simple and effective synthesis of benzolactones and benzolactams by noncatalytic benzylic oxidation of cyclic benzylic ethers and N-protected cyclic benzylic amines with sodium chlorite as an oxidant

Synthesis (Germany)

Volumn 44, Issue 18, 2012, Pages 2903-2909

  Song, Ai Ru ^a,b   Yu, Jun ^a   Zhang, Chi ^a  

^a NANKAI UNIVERSITY   (China)

^b TIANJIN NORMAL UNIVERSITY   (China)

Author keywords

amines; ethers; heterocycles; lactams; lactones; oxidations

Indexed keywords

1 ,1 ,1-TRICHLOROETHANES; BENZYLIC; BENZYLIC AMINES; BENZYLIC OXIDATION; EFFECTIVE SYNTHESIS; HETEROCYCLES; LACTAMS; LACTONES; NON-CATALYTIC; SODIUM CHLORITE; SOLVENT SYSTEM;

AMIDES; ETHERS; OXIDATION; SODIUM;

AMINES;

2 ACETYL 3,4 DIHYDROISOQUINOLIN 1 [2H]ONE; 2 ACETYL 7 CHLORO 3,4 DIHYDROISOQUINOLINE 2 [1H]ONE; 2 ACETYL 7 NITRO 3,4 DIHYDROISOQUINOLINE 2 [1H]ONE; 2 BENZOFURAN 1 [3H]ONE; 2 BENZYL 3,4 DIHYDROISOQUINOLIN 1 [2H]ONE; 2 TOSYL 3,4 DIHYDROISOQUINOLIN 1 [2H]ONE; 2 TOSYLISOINDOLIN 1 ONE; 3,4 DIHYDRO 1H ISOCHROMEN 1 ONE; 6,7 DIMETHOXY 3,4 DIHYDRO 1H ISOCHROMEN 1 ONE; BENZOLACTAM DERIVATIVE; BENZOLACTONE DERIVATIVE; BENZYLAMINE DERIVATIVE; CYCLIC BENZYLAMINE DERIVATIVE; CYCLIC BENZYLETHER DERIVATIVE; ETHER DERIVATIVE; LACTAM DERIVATIVE; LACTONE DERIVATIVE; SODIUM CHLORITE; TERT BUTYL 1 OXO 3,4 DIHYDROISOQUINOLINE 2 [1H]CARBOXYLATE; TERT BUTYL 6 OXOPHENANTHRIDINE 5 [6H]CARBOXYLATE; TERT BUTYL 6,7 DIMETHOXY 1 OXO 3,4 DIHYDROISOQUINOLINE 2 [1H]CARBOXYLATE; TERT BUTYL 7 NITRO 1 OXO 3,4 DIHYDROISOQUINOLINE 2 [1H]CARBOXYLATE; UNCLASSIFIED DRUG;

ARTICLE; CATALYSIS; CHEMICAL COMPOSITION; CHEMICAL INTERACTION; CHEMICAL MODIFICATION; CHEMICAL REACTION KINETICS; CHEMICAL STRUCTURE; CYCLIZATION; OXIDATION; SOLVENT EFFECT; SYNTHESIS; TEMPERATURE SENSITIVITY;

EID: 84866084712     PISSN: 00397881     EISSN: 1437210X     Source Type: Journal    
DOI: 10.1055/s-0032-1316747     Document Type: Article

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