A mild, palladium-catalyzed method for the dehydrohalogenation of alkyl bromides: Synthetic and mechanistic studies

Journal of the American Chemical Society

Volumn 134, Issue 34, 2012, Pages 14232-14237

  Bissember, Alex C ^a,b   Levina, Anna ^a   Fu, Gregory C ^a,b  

^a MASSACHUSETTS INSTITUTE OF TECHNOLOGY   (United States)

^b California Institute of Technology   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ALKYL BROMIDES; CATALYTIC CYCLES; CROSS COUPLING REACTIONS; DEHYDROHALOGENATION; ELEMENTARY STEPS; HECK REACTIONS; HYDRIDE ELIMINATION; MECHANISTIC STUDIES; PALLADIUM-CATALYZED; RATE DETERMINING STEP; ROOM TEMPERATURE; TERMINAL OLEFINS; TOTAL SYNTHESIS;

BROMINE COMPOUNDS; FUNCTIONAL GROUPS; IONIC LIQUIDS; MECHANICS; OLEFINS; PHOSPHORUS COMPOUNDS;

CATALYSIS;

ALKENE; ALKYL BROMIDE; BROMINE DERIVATIVE; FUNCTIONAL GROUP; MEVALONOLACTONE; PALLADIUM; PHOSPHINE; UNCLASSIFIED DRUG;

ARTICLE; CATALYSIS; CHEMICAL STRUCTURE; CROSS COUPLING REACTION; DEHYDROHALOGENATION; ELIMINATION REACTION; HALOGENATION; HECK REACTION; ROOM TEMPERATURE; SYNTHESIS;

ALKANES; ALKENES; BROMINE; CATALYSIS; HALOGENATION; PALLADIUM; PHOSPHINES;

EID: 84865663327     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja306323x     Document Type: Article

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