1,2-Ene dithiolate bridged diiron carbonyl-phosphine and -phosphite complexes in relevance to the active site of [FeFe]-hydrogenases: Synthesis, characterization and electrocatalysis

Journal of Organometallic Chemistry

Volumn 717, Issue , 2012, Pages 29-40

  Durgaprasad, Gummadi ^a   Das, Samar K ^a  

^a UNIVERSITY OF HYDERABAD   (India)

Author keywords

1,2 Ene dithiolate bridged diiron carbonyl complex; FeFe hydrogenase; Bioinorganic chemistry; CO displacement by tertiary P ligand; Electrochemistry

Indexed keywords

[FEFE]HYDROGENASES; ACTIVE SITE; BIOINORGANIC CHEMISTRY; CARBONYL COMPLEXES; CO-DISPLACEMENT BY TERTIARY P-LIGAND; CO-GROUP; DITHIOLATES; DONOR LIGANDS; ELECTROCATALYTIC ACTIVITY; ELECTROCHEMICAL EFFECTS; MASS SPECTROSCOPY; MODEL COMPLEXES; PHOSPHITE LIGANDS; PROTON REDUCTION; REDUCTION POTENTIAL; SINGLE CRYSTAL X-RAY STRUCTURES; SOLID-STATE STRUCTURES; STRONG ACIDS; SUBSTITUTED COMPOUNDS;

BIOCHEMISTRY; CRYSTAL STRUCTURE; CYCLIC VOLTAMMETRY; ELECTROCATALYSIS; ELECTROCHEMISTRY; IRON COMPOUNDS; LIGANDS; MASS SPECTROMETRY; PHOSPHORUS COMPOUNDS; REDUCTION;

SYNTHESIS (CHEMICAL);

EID: 84865303057     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jorganchem.2012.06.020     Document Type: Article

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