Tunable phase behavior of polystyrene-polypeptoid block copolymers

Macromolecules

Volumn 45, Issue 15, 2012, Pages 6027-6035

  Rosales, Adrianne M ^a   McCulloch, Bryan L ^a   Zuckermann, Ronald N ^b   Segalman, Rachel A ^a,b  

^a University of California   (United States)

^b LAWRENCE BERKELEY NATIONAL LABORATORY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CO-MONOMER; COMONOMERS; GLYCINE RESIDUES; INTERACTION STRENGTH; LAMELLAR MORPHOLOGY; POLYMER PROPERTIES; POLYSTYRENE BLOCK; SELF-ASSEMBLE; SEQUENCE DESIGNS; SIDE-CHAINS;

ACETYLENE; AMINO ACIDS; POLYSTYRENES; STYRENE;

BLOCK COPOLYMERS;

EID: 84865140197     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma300625b     Document Type: Article

References (47)

1. Bates, F. S.; Fredrickson, G. H. Block copolymers-Designer soft materials Phys. Today 1999, 52 (2) 32-38 (Pubitemid 129600640)
2. Beckingham, B. S.; Register, R. A. Synthesis and Phase Behavior of Block-Random Copolymers of Styrene and Hydrogenated Isoprene Macromolecules 2011, 44 (11) 4313-4319
3. Mok, M. M.; Ellison, C. J.; Torkelson, J. M. Effect of Gradient Sequencing on Copolymer Order-Disorder Transitions: Phase Behavior of Styrene/n-Butyl Acrylate Block and Gradient Copolymers Macromolecules 2011, 44 (15) 6220-6226
4. Quinn, J. D.; Register, R. A. Microphase Separation in Block-Random Copolymers of Styrene, 4-Acetoxystyrene, and 4-Hydroxystyrene J. Polym. Sci., Part B: Polym. Phys. 2009, 47 (21) 2106-2113
5. Roy, R.; Park, J. K.; Young, W. S.; Mastroianni, S. E.; Tureau, M. S.; Epps, T. H. Double-Gyroid Network Morphology in Tapered Diblock Copolymers Macromolecules 2011, 44 (10) 3910-3915
6. Samseth, J.; Spontak, R. J.; Smith, S. D.; Ashraf, A.; Mortensen, K. Microphase-Separated Tapered Triblock Copolymers J. Phys. IV 1993, 3 (C8) 59-62
7. Singh, N.; Tureau, M. S.; Epps, T. H. Manipulating ordering transitions in interfacially modified block copolymers Soft Matter 2009, 5 (23) 4757-4762
8. Hodrokoukes, P.; Floudas, G.; Pispas, S.; Hadjichristidis, N. Microphase separation in normal and inverse tapered block copolymers of polystyrene and polyisoprene. 1. Phase state Macromolecules 2001, 34 (3) 650-657 (Pubitemid 32190840)
9. Mayo, F. R.; Lewis, F. M. Copolymerization I A basis for comparing the behavior of monomers in copolymerization, the copolymerization of styrene and methyl methacrylate J. Am. Chem. Soc. 1944, 66, 1594-1601
10. Lutz, J. F.; Pakula, T.; Matyjaszewski, K. Synthesis and properties of copolymers with tailored sequence distribution by controlled/living radical polymerization. In Advances in Controlled/Living Radical Polymerization, Matyjaszewski, K., Ed. American Chemical Society: Washington, DC, 2003; Vol. 854, pp 268-282.
11. Antkowia, Ta; Tate, D. P.; Oberster, A. E.; Halasa, A. F. Temperature and Concentration Effects on Polar-Modified Alkyllithium Polymerizations and Copolymerizations J. Polym. Sci., Part A-1: Polym. Chem. 1972, 10 (5) 1319
12. Badi, N.; Lutz, J. F. Sequence control in polymer synthesis Chem. Soc. Rev. 2009, 38 (12) 3383-3390
13. Lutz, J. F. Sequence-controlled polymerizations: the next Holy Grail in polymer science? Polym. Chem. 2010, 1 (1) 55-62
14. Lutz, J. F.; Kirci, B.; Matyjaszewski, K. Synthesis of well-defined alternating copolymers by controlled/living radical polymerization in the presence of Lewis acids Macromolecules 2003, 36 (9) 3136-3145
15. Ouchi, M.; Terashima, T.; Sawamoto, M. Transition Metal-Catalyzed Living Radical Polymerization: Toward Perfection in Catalysis and Precision Polymer Synthesis Chem. Rev. 2009, 109 (11) 4963-5050
16. Smith, J. A.; Brzezinska, K. R.; Valenti, D. J.; Wagener, K. B. Precisely controlled methyl branching in polyethylene via acyclic diene metathesis (ADMET) polymerization Macromolecules 2000, 33 (10) 3781-3794
17. Soeriyadi, A. H.; Boyer, C.; Nystrom, F.; Zetterlund, P. B.; Whittaker, M. R. High-Order Multiblock Copolymers via Iterative Cu(0)-Mediated Radical Polymerizations (SET-LRP): Toward Biological Precision J. Am. Chem. Soc. 2011, 133 (29) 11128-11131
18. Link, A. J.; Mock, M. L.; Tirrell, D. A. Non-canonical amino acids in protein engineering Curr. Opin. Biotechnol. 2003, 14 (6) 603-609 (Pubitemid 37518438)
19. van Hest, J. C. M.; Tirrell, D. A. Protein-based materials, toward a new level of structural control Chem. Commun. 2001, 19, 1897-1904 (Pubitemid 32964507)
20. Barron, A. E.; Zuckermann, R. N. Bioinspired polymeric materials: in-between proteins and plastics Curr. Opin. Chem. Biol. 1999, 3 (6) 681-687
21. Borner, H. G. Precision Polymers-Modern Tools to Understand and Program Macromolecular Interactions Macromol. Rapid Commun. 2011, 32 (2) 115-126
22. Borner, H. G.; Schlaad, H. Bioinspired functional block copolymers Soft Matter 2007, 3 (4) 394-408 (Pubitemid 46453741)
23. Hartmann, L.; Borner, H. G. Precision Polymers: Monodisperse, Monomer-Sequence-Defined Segments to Target Future Demands of Polymers in Medicine Adv. Mater. 2009, 21 (32-33) 3425-3431
24. Lutz, J. F.; Borner, H. G. Modern trends in polymer bioconjugates design Prog. Polym. Sci. 2008, 33 (1) 1-39 (Pubitemid 350266041)
25. Rosales, A. M.; Murnen, H. K.; Zuckermann, R. N.; Segalman, R. A. Control of Crystallization and Melting Behavior in Sequence Specific Polypeptoids. Macromolecules 43 (13), 5627-5636.
26. Rosales, A. M.; Murnen, H. K.; Kline, S. R.; Zuckermann, R. N.; Segalman, R. A. Determination of the persistence length of helical and non-helical polypeptoids in solution Soft Matter 2012, 8 (13) 3673-3680
27. Figliozzi, G. M.; Goldsmith, R.; Ng, S. C.; Banville, S. C.; Zuckermann, R. N. Synthesis of N-substituted glycine peptoid libraries Methods Enzymol. 1996, 267, 437-447 (Pubitemid 26159237)
28. Zuckermann, R. N.; Kerr, J. M.; Kent, S. B. H.; Moos, W. H. Efficient Method for the Preparation of Peptoids [Oligo(N-substituted glycines)] by Submonomer Solid-Phase Synthesis J. Am. Chem. Soc. 1992, 114 (26) 10646-10647
29. Wu, C. W.; Sanborn, T. J.; Huang, K.; Zuckermann, R. N.; Barron, A. E. Peptoid oligomers with alpha-chiral, aromatic side chains: Sequence requirements for the formation of stable peptoid helices J. Am. Chem. Soc. 2001, 123 (28) 6778-6784 (Pubitemid 32884537)
30. Murnen, H. K.; Rosales, A. M.; Jaworsk, J. N.; Segalman, R. A.; Zuckermann, R. N. Hierarchical Self-Assembly of a Biomimetic Diblock Copolypeptoid into Homochiral Superhelices J. Am. Chem. Soc. 2010, 132 (45) 16112-16119
31. Nam, K. T.; Shelby, S. A.; Choi, P. H.; Marciel, A. B.; Chen, R.; Tan, L.; Chu, T. K.; Mesch, R. A.; Lee, B. C.; Connolly, M. D.; Kisielowski, C.; Zuckermann, R. N. Free-floating ultrathin two-dimensional crystals from sequence-specific peptoid polymers Nat. Mater. 2010, 9 (5) 454-460
32. Lee, C.-U.; Smart, T. P.; Guo, L.; Epps, T. H.; Zhang, D. Synthesis and Characterization of Amphiphilic Cyclic Diblock Copolypeptoids from N-Heterocyclic Carbene-Mediated Zwitterionic Polymerization of N-Substituted N-Carboxyanhydride. Macromolecules 2011, not supplied.
33. Lee, B. C.; Chu, T. K.; Dill, K. A.; Zuckermann, R. N. Biomimetic nanostructures: Creating a high-affinity zinc-binding site in a folded nonbiological polymer J. Am. Chem. Soc. 2008, 130 (27) 8847-8855 (Pubitemid 351962520)
34. Kudirka, R.; Tran, H.; Sanii, B.; Nam, K. T.; Choi, P. H.; Venkateswaran, N.; Chen, R.; Whitelam, S.; Zuckermann, R. N. Folding of a Single-Chain, Information-Rich Polypeptoid Sequence into a Highly Ordered Nanosheet Biopolymers 2011, 96 (5) 586-595
35. Bothe, M.; Schmidt-Naake, G. An improved catalytic method for alkoxyamine synthesis-Functionalized and biradical initiators for nitroxide-mediated radical polymerization Macromol. Rapid Commun. 2003, 24 (10) 609-613
36. Holub, J. M.; Jang, H. J.; Kirshenbaum, K. Clickity-click: highly functionalized peptoid oligomers generated by sequential conjugation reactions on solid-phase support Org. Biomol. Chem. 2006, 4 (8) 1497-1502 (Pubitemid 43797654)
37. Ilavsky, J. Nika: software for two-dimensional data reduction J. Appl. Crystallogr. 2012, 45 (2) 324-328
38. Hashimoto, T.; Kawamura, T.; Harada, M.; Tanaka, H. Small-Angle Scattering from Hexagonally Packed Cylindrical Particles with Paracrystalline Distortion Macromolecules 1994, 27 (11) 3063-3072
39. Billot, J. P.; Douy, A.; Gallot, B. Synthesis and Structural Study of Block Copolymers with a Hydrophobic Polyvinyl Block and a Hydrophilic Polypeptide Block-Copolymers Polystyrene-Poly(L-lysine) and Polybutadiene- Poly(L-lysine) Makromol. Chem.-Macromol. Chem. Phys. 1976, 177 (6) 1889-1893
40. Douy, A.; Gallot, B. Block Copolymers with a Polyvinyl and a Polypeptide Block-Factors Governing the Folding of the Polypeptide-Chains Polymer 1982, 23 (7) 1039-1044 (Pubitemid 12575255)
41. Perly, B.; Douy, A.; Gallot, B. Block Copolymers Polybutadiene- Poly(benzyl-L-glutamate) and Polybutadiene-Poly(N5-hydroxypropylglutamine) Preparation and Structural Study by X-Ray and Electron-Microscopy Makromol. Chem.-Macromol. Chem. Phys. 1976, 177 (9) 2569-2589
42. Minich, E. A.; Nowak, A. P.; Deming, T. J.; Pochan, D. J. Rod-rod and rod-coil self-assembly and phase behavior of polypeptide diblock copolymers Polymer 2004, 45 (6) 1951-1957 (Pubitemid 38224326)
43. Babin, J.; Taton, D.; Brinkmann, M.; Lecommandoux, S. Synthesis and Self-Assembly in Bulk of Linear and Mikto-Arm Star Block Copolymers Based on Polystyrene and Poly(glutamic acid) Macromolecules 2008, 41 (4) 1384-1392 (Pubitemid 351363144)
44. Klok, H. A.; Langenwalter, J. F.; Lecommandoux, S. Self-assembly of peptide-based diblock oligomers Macromolecules 2000, 33 (21) 7819-7826
45. Klok, H. A.; Lecommandoux, S. Solid-state structure, organization and properties of peptide-Synthetic hybrid block copolymers. In Peptide Hybrid Polymers; Klok, H. A.; Schlaad, H., Eds.; Springer-Verlag: Berlin, 2006; Vol. 202, pp 75-111.
46. Lecommandoux, S.; Achard, M. F.; Langenwalter, J. F.; Klok, H. A. Self-assembly of rod-coil diblock oligomers based on alpha-helical peptides Macromolecules 2001, 34 (26) 9100-9111 (Pubitemid 34050753)
47. Matsen, M. W.; Bates, F. S. Unifying weak- and strong-segregation block copolymer theories Macromolecules 1996, 29 (4) 1091-1098