Synthesis and phase behavior of block-random copolymers of styrene and hydrogenated isoprene

Macromolecules

Volumn 44, Issue 11, 2011, Pages 4313-4319

  Beckingham, Bryan S ^a   Register, Richard A ^a  

^a Princeton University   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

COMPOSITIONAL GRADIENTS; CONTROLLED POLYMERIZATION; COPOLYMER ARCHITECTURE; DIBLOCKS; HOMOPOLYMER BLOCKS; INTERACTION ENERGIES; INTERBLOCK INTERACTIONS; LAMELLAR MORPHOLOGY; MEAN-FIELD; ORGANOLITHIUMS; RANDOM COPOLYMER; SELF-ASSEMBLE; THERMALLY STABLE;

BLOCK COPOLYMERS; COPOLYMERIZATION; HYDROGENATION; MOLECULAR WEIGHT; ORDER DISORDER TRANSITIONS; POLYSTYRENES; SCALES (WEIGHING INSTRUMENTS); STYRENE;

PLASTIC PRODUCTS;

EID: 79958778406     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma200913k     Document Type: Article

References (33)

1. Tierney, N. K.; Register, R. A. Macromolecules 2003, 36, 1170-1177
2. Smith, S. D.; Ashraf, A.; Satkowski, M. M.; Spontak, R. J. Polym. Prepr. (Am. Chem. Soc., Div. Polym. Chem.) 1994, 35 (1) 651-652
3. Kotani, Y.; Kamigaito, M.; Sawamoto, M. Macromolecules 1998, 31, 5582-5587
4. Quinn, J. D.; Register, R. A. J. Polym. Sci., Part B: Polym. Phys. 2009, 47, 2106-2113
5. Gromadzki, D.; Lokaj, J.; Cernoch, P.; Diat, O.; Nallet, F.; Stepanek, P. Eur. Polym. J. 2008, 44, 189-199
6. Morton, M. Anionic Polymerization: Principles and Practice; Academic Press: New York, 1983; pp 134-145.
7. Antkowiak, T. A.; Oberster, A. E.; Halasa, A. F.; Tate, D. P. J. Polym. Sci., Part A 1972, 10, 1319-1334
8. Chang, C. C.; Halasa, A. F.; Miller, J. W., Jr. ; Hsu, W. L. Polym. Int. 1994, 33, 151-159
9. Loo, Y. L.; Register, R. A.; Ryan, A. J. Macromolecules 2002, 35, 2365-2374
10. Graessley, W. W.; Krishnamoorti, R.; Reichart, G. C.; Balsara, N. P.; Fetters, L. J.; Lohse, D. J. Macromolecules 1995, 28, 1260-1270
11. Wofford, C. F.; Hsieh, H. L. J. Polym. Sci., Part A-1 1969, 7, 461-469
12. Smith, S. D.; Ashraf, A.; Clarson, S. J. Polym. Prepr. (Am. Chem. Soc., Div. Polym. Chem.) 1993, 34 (2) 672-673
13. Hodrokoukes, P.; Pispas, S.; Hadjichristidis, N. Macromolecules 2002, 38, 834-840
14. Kelley, D. J.; Tobolsky, A. V. J. Am. Chem. Soc. 1959, 81, 1597-1600
15. Annighöfer, F.; Gronski, W. Colloid Polym. Sci. 1983, 261, 15-25
16. Hahn, S. F. J. Polym. Sci., Part A: Polym. Chem. 1992, 30, 397-408
17. Adams, J. L.; Quiram, D. J.; Graessley, W. W.; Register, R. A.; Marchand, G. R. Macromolecules 1998, 31, 201-204
18. Sebastian, J. M.; Register, R. A. J. Appl. Polym. Sci. 2001, 82, 2056-2069
19. Register, R. A.; Bell, T. R. J. Polym. Sci., Part B: Polym. Phys. 1992, 30, 569-575
20. Huang, T. C.; Toraya, H.; Blanton, T. N.; Wu, Y. J. Appl. Crystallogr. 1993, 26, 180-184
21. Russell, T. P. In Handbook on Synchrotron Radiation; Brown, G. S.; Moncton, D. E., Eds.; North-Holland: New York, 1991; Vol. 3, Chapter 11, pp 379-469.
22. Worsfold, D. J. J. Polym. Sci., Part A 1967, 5, 2783-2789
23. Tobolsky, A. V.; Rogers, C. E. J. Polym. Sci. 1959, 40, 73-89
24. Krishnamoorti, R.; Graessley, W. W.; Dee, G. T.; Walsh, D. J.; Fetters, L. J.; Lohse, D. J. Macromolecules 1996, 29, 367-376
25. 1H NMR spectrum for the unsaturated precursor to 50SPI confirmed its microstructure to contain 50% 3,4-addition and that the balance is 37% 1,4- and 13% 1,2-addition, rather than the 50% 1,4-addition originally assigned.
26. Richardson, M. J.; Savill, N. G. Polymer 1977, 18, 3-9
27. Hashimoto, Y.; Shibayama, M.; Kawai, H. Macromolecules 1980, 13, 1237-1247
28. Winey, K. I.; Gobran, D. A.; Xu, Z.; Fetters, L. J.; Thomas, E. L. Macromolecules 1994, 27, 2392-2397
29. Matsen, M. W.; Bates, F. S. Macromolecules 1996, 29, 1091-1098
30. ten Brinke, G.; Karasz, F. E.; MacKnight, W. J. Macromolecules 1983, 16, 1827-1832
31. van Krevelen, P. W. Properties of Polymers, 3 rd ed.; Elsevier: New York, 1990.
32. Graessley, W. W. Polymeric Liquids & Networks: Structure and Properties; Garland Science: New York, 2004; pp 341-407.
33. Lai, C. J. Ph.D Thesis, Princeton University, 1999.