A new reactivity pattern of heterodinuclear complexes [MnRe(CO) 6(μ-S 2CPR 3)] with nBuLi/ protonation and its electrochemistry properties investigation as structure and function models for the Fe-only hydrogenase active site

Journal of Organometallic Chemistry

Volumn 716, Issue , 2012, Pages 230-236

  Zhao, Jia ^a   Ma, Yongqiang ^b   Bai, Zhifeng ^a   Chang, Weixing ^a   Li, Jing ^a  

^a NANKAI UNIVERSITY   (China)

^b CHINA AGRICULTURAL UNIVERSITY   (China)

Author keywords

Binuclear complex; Electrochemical property; Hydrogenase; Nucleophilic attack

Indexed keywords

ACTIVE SITE; BINUCLEAR COMPLEXES; ELECTROCHEMICAL MECHANISMS; ELECTROCHEMICAL REDUCTIONS; ELECTROCHEMISTRY PROPERTIES; FUNCTION MODELS; HETERODINUCLEAR COMPLEXES; HYDROGENASES; NUCLEOPHILIC ATTACK; REACTION PATTERNS; REACTIVITY PATTERN; STRUCTURAL MODELS; WEAK ACIDS;

ACETIC ACID; ACETONITRILE; CHEMICAL BONDS; ELECTROCATALYSIS; ELECTROCATALYSTS; ELECTROCHEMICAL PROPERTIES; ELECTROLYTIC REDUCTION; MODEL STRUCTURES; PROTONATION; RHENIUM; RHENIUM COMPOUNDS; SODIUM;

MANGANESE;

EID: 84864979701     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jorganchem.2012.07.003     Document Type: Article

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