Identification, quantification and carbon stable isotopes determinations of organic acids in monofloral honeys. A powerful tool for botanical and authenticity control

Rapid Communications in Mass Spectrometry

Volumn 26, Issue 17, 2012, Pages 1993-1998

  Daniele, Gaëlle ^a   Maitre, Dany ^a   Casabianca, Hervé ^a  

^a Institut des Sciences Analytiques   (France)

Author keywords

[No Author keywords available]

Indexed keywords

CARBON; CHROMATOGRAPHIC ANALYSIS; FOOD PRODUCTS; ION CHROMATOGRAPHY; ION EXCHANGE; ION EXCHANGE RESINS; ISOTOPES; MASS SPECTROMETRY; ORGANIC ACIDS; PRINCIPAL COMPONENT ANALYSIS; QUALITY CONTROL;

ANION EXCHANGE RESINS; AUTHENTICITY CONTROL; B-Y IONS; CARBON STABLE ISOTOPES; DETERMINATION OF ORGANIC ACIDS; ELECTROCHEMICAL DETECTORS; INTERNAL STANDARDS; ISOTOPIC RATIOS; QUALITATIVE AND QUANTITATIVE ANALYSIS; WHITE METHODS;

PROTEINS;

EID: 84864780870     PISSN: 09514198     EISSN: 10970231     Source Type: Journal    
DOI: 10.1002/rcm.6310     Document Type: Article

References (33)

1. A. Anklam,. A review of the analytical methods to determine the geographical and botanical origin of honey. Food Chem. 1998, 63, 549.
2. J. M. Alavarez-Suarez, S. Tulipani, S. Romandini, E. Bertoli, M. Battino,. Contribution of honey in nutrition and human health: a review. Mediterr. J. Nutr. Metab. 2010, 3, 15.
3. R. A. Pérez,. Analysis of volatiles from Spanish honeys by solid-phase microextraction and gas chromatography-mass spectrometry. J. Agric. Food Chem. 2002, 50, 3050.
4. A. Terrab, M. L. Gonzále, A. G. González, M. F. Díez, M. L. Escudero, F. J. Heredia,. Characterisatin of Morroccan unifloral honeys using multivariate analysis. Eur. Food Res. Technol. 2003, 218, 88.
5. J. Wang, Q. X. Li,. Chemical composition, characterisation, and differentiation of honey botanical and geographical origins. Adv. Food Nutr. Res. 2011, 62, 89.
6. K. Pyrzynska, M. Biesaga,. Analysis of phenolic acids and flavonoids in honey. Trends Anal. Chem. 2009, 28, 893.
7. S. Bogdanov, M. Haldimann, W. Luginbühl, P. Gallmann,. Minerals in honey: environmental, geographical and botanical aspects. J. Apic. Res. Bee World 2007, 46, 269.
8. J. F. Cotte, H. Casabianca, S. Chardon, J. Lheritier, M. F. Grenier-Loustalot,. Application of carbohydrate analysis to verify honey authenticity. J. Chromatogr. A 2003, 1021, 145.
9. A. I. Ruiz-Matute, S. Rodríguez-Sánchez, M. L. Sanz, I. Martínez-Castro,. Detection of adulterations of honey with high fructose syrups from inulin by GC analysis. J. Food Compos. Anal. 2010, 23, 273.
10. X. Zhu, S. Li, Y. Shan, Z. Zhang, G. Li, D. Su, F. Liu,. Detection of adulterants such as sweeteners materials in honey using near-infrared spectroscopy and chemometrics. J. Food Engin. 2010, 101, 92.
11. 13C measurements. Apidologie 2000, 31, 717.
12. J. D. Kerkvliet, M. Shrestha, K. Tuladhar, H. Manandhar,. Microscopic detection of adulteration of honey with cane sugar and cane sugar products. Apidologie 1995, 26, 131.
13. J. Louveaux, A. Maurizio, G. Vorwohl,. Methods of melissopalynology. Bee World 1978, 59, 139.
14. L. W. Doner, J. W. White Jr,. Carbon-13/carbon-12 ratio is relatively uniform among honeys. Science 1977, 197, 891.
15. 12C ratios of plants in relation to the pathway of photosynthetic carbon dioxide fixation. Phytochemistry 1971, 10, 1239.
16. 12C ratios for higher plants. Plant Physiol. 1971, 47, 380.
17. J. W. White, K. Winters,. Honey protein as internal standard for stable carbon isotope ratio detection of adulteration of honey. J. Assoc. Off. Anal. Chem. Int. 1989, 72, 907.
18. 4 plant sugar in honey: collaborative study. J. Assoc. Off. Anal. Chem. 1992, 61, 746.
19. J. W. White, K. Winters, P. Martin, A. Rossman,. Stable carbon isotope ratio analysis of honey: validation of internal standard procedure for worldwide application. J. Assoc. Off. Anal. Chem. Int. 1998, 81, 610.
20. 12C isotopic ratio. Food Chem. 2003, 82, 633.
21. 2H SNIF-NMR isotopic measurements to characterize and control the authenticity of honey. Anal. Chim. Acta 2007, 582, 125.
22. I. Mato, J. F. Huidobro, J. Simal-Lozano, M. T. Sancho,. Analytical methods for the determination of organic acids in honey. Crit. Rev. Anal. Chem. 2006, 36, 3.
23. S. Suarez-Luque, I. Mato, J. F. Huidobro, J. Simal-Lozano, M. T. Sancho,. Rapid determination of minority organic acids in honey by high-performance liquid chromatography. J. Chromatogr. A 2002, 955, 207.
24. J. W. White,. Studies on honey inhibine. 2. A chemical assay. J. Apicult. Res. 1963, 2, 93.
25. A. L. Wilkins, Y. Lu, S. T. Tan,. Extractives from New Zealand honeys. 5. Aliphatic dicarboxylic acids in New Zealand Rewarewa (Knightea excelsa) honey. J. Agric. Food Chem. 1995, 43, 3021.
26. I. Molnar-Perl, A. Vasanits, K. Horvath,. Simultaneous GC-MS quantification of benzoic and aralkyl carboxylic acids as their trimethylsilyl derivatives: in model solutions I. Chromatographia 1998, 48, 111.
27. K. Horvath, I. Molnar-Perl,. Simultaneous GC-MS quantification of phosphoric, aliphatic and aromatic carboxylic acids, proline and hydroxymethylfurfurol as their trimethylsilyl derivatives: in honeys. Chromatographia 1998, 48, 120.
28. J. W. White, M. L. Riethof, M.H. Subers, I. Kushnir,. Composition of American honey. Tech. Bull. U.S. Dept. Agric. 1962, 1261, 1.
29. I. Mato, J. F. Huidobro, V. Cendon, S. Muniategui, M. A. Fernandez-Muino, M. T. Sancho,. Enzymatic determination of citric acid in honey by using polyvinylpolypyrrolidone clarification. J. Agric. Food Chem. 1998, 46, 141.
30. A. Cherchi, L. Spanedda, C. Tuberoso, P. Cabras,. Solid-phase extraction and high-performance liquid chromatographic determination of organic acids in honey. J. Chromatogr. A 1994, 669, 59.
31. B. Talpay,. Inhaltsstoffe des Honigs-Citronensäure (Citrat.) Dtsch. Lebensm. Rundsch 1998, 84, 41.
32. S. Bogdanov, K. Ruoff, L. Persano Oddo,. Physico-chemical methods for the characterization of unifloral honeys: A review. Apidologie 2004, 35, S4.
33. I. Mato, J. F. Huidobro, M. P. Sanchez, S. Muniategui, M. A. Fernandez-Muino, M. T. Sancho,. Enzymatic determination of total D-gluconic acid in honey. J. Agric. Food Chem. 1997, 45, 3550.