Highly stereoselective C-C bond formation by rhodium-catalyzed tandem ylide formation/[2,3]-sigmatropic rearrangement between donor/acceptor carbenoids and chiral allylic alcohols

Journal of the American Chemical Society

Volumn 134, Issue 26, 2012, Pages 10942-10946

  Li, Zhanjie ^a   Parr, Brendan T ^a   Davies, Huw M L ^a  

^a EMORY UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ALLYL ALCOHOLS; ALLYLIC ALCOHOL; C-C BOND FORMATION; C-C BOND FORMING; CARBENOIDS; CHIRAL ALCOHOLS; CHIRAL CATALYST; RHODIUM CARBENOIDS; RHODIUM-CATALYZED; SIGMATROPIC REARRANGEMENTS; STEREO-SELECTIVE; STEREOGENIC CENTERS; YLIDE FORMATION;

STEREOCHEMISTRY;

RHODIUM;

ALCOHOL; ALLYL COMPOUND; CARBENOID; RHODIUM;

ALLYLIC REARRANGEMENT; ARTICLE; CATALYSIS; CATALYST; CHEMICAL BOND; CHIRALITY; CONFORMATION; DONOR; STEREOCHEMISTRY; STEREOISOMERISM; SYNTHESIS;

ALLYL COMPOUNDS; AZO COMPOUNDS; CATALYSIS; ORGANOMETALLIC COMPOUNDS; PROLINE; PROPANOLS; RHODIUM; STEREOISOMERISM;

EID: 84863528326     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja303023n     Document Type: Article

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