Asymmetric [4 + 3] cycloadditions between vinylcarbenoids and dienes: Application to the total synthesis of the natural product (-)-5-epi-vibsanin E

Journal of the American Chemical Society

Volumn 131, Issue 23, 2009, Pages 8329-8332

  Schwartz, Brett D ^a   Denton, Justin R ^b   Lian, Yajing ^c   Davies, Huw M L ^c   Williams, Craig M ^a  

^a UNIVERSITY OF QUEENSLAND   (Australia)

^b UNIVERSITY AT BUFFALO   (United States)

^c EMORY UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ASYMMETRIC INDUCTION; COPE REARRANGEMENT; CYCLOADDITIONS; CYCLOPROPANATION; DIRHODIUM COMPLEX; END-GAME; NATURAL PRODUCTS; RHODIUM-CATALYZED; SIDE CHAINS; STEREOGENIC CENTERS; TOTAL SYNTHESIS;

CYCLOADDITION; RHODIUM;

RHODIUM COMPOUNDS;

5 EPI VIBSANIN E; ALKADIENE; CARBENOID; CYCLOHEPTADIENE; CYCLOHEPTANE DERIVATIVE; NATURAL PRODUCT; RHODIUM; RHODIUM COMPLEX; UNCLASSIFIED DRUG; VINYLCARBENOID; BIOLOGICAL PRODUCT; DITERPENE; VIBSANIN E;

ARTICLE; ASYMMETRIC SYNTHESIS; CATALYSIS; CHEMICAL REACTION; CHIRALITY; COPE REARRANGEMENT; CYCLOADDITION; CYCLOPROPANATION; DIELS ALDER REACTION; STEREOCHEMISTRY; STEREOISOMERISM; CHEMISTRY; CYCLIZATION; SYNTHESIS;

BIOLOGICAL PRODUCTS; CATALYSIS; CYCLIZATION; DITERPENES; RHODIUM;

EID: 67650561139     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja9019484     Document Type: Article

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