Exploring between the extremes: Conversion-dependent kinetics of phosphite-modified hydroformylation catalysis

Chemistry - A European Journal

Volumn 18, Issue 28, 2012, Pages 8780-8794

  Kubis, Christoph ^a   Selent, Detlef ^a   Sawall, Mathias ^a   Ludwig, Ralf ^a   Neymeyr, Klaus ^a   Baumann, Wolfgang ^a   Franke, Robert ^b,c   Börner, Armin ^a  

^a UNIVERSITY OF ROSTOCK   (Germany)

^b EVONIK INDUSTRIES AG   (Germany)

^c RUHR UNIVERSITY BOCHUM   (Germany)

Author keywords

density functional calculations; hydroformylation; in situ spectroscopy; kinetics; phosphites; rhodium

Indexed keywords

ACYL COMPLEXES; AXIAL POSITIONS; CATALYTIC INTERMEDIATES; CONCENTRATION PROFILES; DFT CALCULATION; FIRST ORDER; FTIR; HIGH CONVERSIONS; HYDROGEN CONCENTRATION; IN-SITU; IN-SITU FT-IR; IN-SITU SPECTROSCOPY; MICHAELIS-MENTEN-TYPE KINETICS; ORGANIC COMPONENTS; PHOSPHITE LIGANDS; PHOSPHITES; RATE LIMITING; RESTING STATE; RHODIUM COMPLEXES; RHODIUM HYDRIDES; SIDE REACTIONS; SPECTROSCOPIC DATA; SUBSTRATE COMPLEXES; TIME-DEPENDENT; TRIGONAL BIPYRAMIDAL;

BUTENES; CATALYSTS; COORDINATION REACTIONS; DENSITY FUNCTIONAL THEORY; ENZYME KINETICS; FOURIER TRANSFORM INFRARED SPECTROSCOPY; HYDROFORMYLATION; HYDROGEN; KINETICS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; REACTION INTERMEDIATES; RHODIUM;

RHODIUM COMPOUNDS;

EID: 84863465122     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.201200603     Document Type: Article

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