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(b) Frenich, A. G.; Galera, M. M.; Vidal, J. L. M.; Massart, D. L.; Torres-Lapasio, J. R.; De Braekeleer, K.; Wang, J.; Hopke, P. K. Anal. Chim. Acta 2000, 411, 145.
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The latter methods often assume the number of observable species present and the existence of a so-called "pure wavelength" for each species. Both conditions are particularly restrictive, especially when a large but unknown number of species are present and their pure component spectra are highly overlapping.
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(a) Sasaki, K.; Kawata, S.; Minami, S. Appl. Opt. 1983, 22, 3599.
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0038699753
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note
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As shown (vide infra), there are two soluble species present and one suspended solid spectrum. Since at least four vectors are needed to represent three species, serious spectral nonlinearities exist (nonstationary signals). Statistical tests for determining the rank of the spectroscopic data would conflict with the actual number of species present.
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-
-
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37
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0037685394
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note
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-1, respectively.
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38
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0038023303
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note
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-1.
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39
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Widjaja, E.; Li, C.; Garland, M. Organometallics 2002, 21, 1991.
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0038699754
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Safety issues include the toxicity of rhodium carbonyls, as well as the pyrophoric nature of Na/K alloy
-
Safety issues include the toxicity of rhodium carbonyls, as well as the pyrophoric nature of Na/K alloy.
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(b) Bor, G.; Sbrignadello, G.; Noack, K. Helv. Chim. Acta 1975, 58, 815.
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