A novel one-pot method for αα-tosyloxylation of ketones using a catalytic amount of ammonium iodide

Synthesis

Volumn 44, Issue 8, 2012, Pages 1226-1232

  Hu, Jiantao ^a   Zhu, Min ^b   Xu, Yuan ^a   Yan, Jie ^a  

^a ZHEJIANG UNIVERSITY OF TECHNOLOGY   (China)

^b ZHEJIANG SHUREN UNIVERSITY   (China)

Author keywords

tosyloxylation; tosyloxy ketones; ammonium iodide; hypervalent iodine intermediate

Indexed keywords

2 ,2 ,2-TRIFLUOROETHANOL; AMMONIUM IODIDE; CATALYTIC AMOUNTS; GOOD YIELD; HYPERVALENT IODINE; M-CHLOROPEROXYBENZOIC ACIDS; ONE-POT METHOD; ONE-POT PROCEDURES; PTOLUENESULFONIC ACID; ROOM TEMPERATURE;

ACETONITRILE; BENZENE; ETHANOL; IODINE; KETONES; REACTION INTERMEDIATES;

AMMONIUM COMPOUNDS;

2 (ALPHA TOSYLOXYACETYL)THIOPHENE; 2 METHYL ALPHA TOSYLOXYACETOPHENONE; 2 TOSYLOXY 1 INDANONE; 2 TOSYLOXY 2 PENTANONE; 3 CHLOROPERBENZOIC ACID; 3 NITRO ALPHA TOSYLOXYACETOPHENONE; 4 BROMO ALPHA TOSYLOXYACETOPHENONE; 4 CHLORO ALPHA TOSYLOXYACETOPHENONE; 4 CHLORO ALPHA TOSYLOXYPROPIOPHENONE; 4 METHYL ALPHA TOSYLOXYACETOPHENONE; 4 NITRO ALPHA TOSYLOXYACETOPHENONE; 4 TOLUENESULFONIC ACID MONOHYDRATE; ACETONITRILE; ALPHA MESYLOXY 4 METHYLACETOPHENONE; ALPHA MESYLOXY 4 NITROACETOPHENONE; ALPHA MESYLOXYACETONE; ALPHA MESYLOXYACETOPHENONE; ALPHA TOSYLOXYACETONE; ALPHA TOSYLOXYACETOPHENONE; ALPHA TOSYLOXYBUTANONE; ALPHA TOSYLOXYPROPIOPHENONE; AMMONIUM IODIDE; BENZENE; ETHYL 2 TOSYLOXYACETOACETATE; GAMMA TOSYLOXYBUTANONE; IODINE DERIVATIVE; KETONE DERIVATIVE; TOLUENESULFONIC ACID DERIVATIVE; TRIFLUOROETHANOL; UNCLASSIFIED DRUG;

ALPHA TOSYLOXYLATION; ARTICLE; CATALYSIS; CHEMICAL COMPOSITION; CHEMICAL MODIFICATION; CHEMICAL REACTION KINETICS; ONE POT SYNTHESIS;

EID: 84862817462     PISSN: 00397881     EISSN: 1437210X     Source Type: Journal    
DOI: 10.1055/s-0031-1289750     Document Type: Article

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