Solvolysis of vinyl iodonium salts. New insights into vinyl cation intermediates

Accounts of Chemical Research

Volumn 35, Issue 1, 2002, Pages 12-18

  Okuyama, Tadashi ^a  

^a UNIVERSITY OF HYOGO   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

4 METHYLCYCLOHEXYLIDENEMETHYLIODONIUM SALT; BENZENE DERIVATIVE; CATION; IODINE DERIVATIVE; METHYL GROUP; UNCLASSIFIED DRUG; VINYL DERIVATIVE;

ARTICLE; CHEMICAL REACTION; CHIRALITY; SOLVOLYSIS;

EID: 0036149635     PISSN: 00014842     EISSN: None     Source Type: Journal    
DOI: 10.1021/ar0100374     Document Type: Article

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6. Stereospecific synthesis of trisubstituted alkenyl(phenyl)iodonium salts from vinylstannanes
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9. Kinetics of acid-ctatalyzed hydration of acetylene. Evidence for the presence in the solution phase of unsubstituted vinyl cation
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16. +
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18. +
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21. The correlation of solvolysis rates
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28. N2 pathway
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30. N2 reaction of 1-decenyliodonium salt with halide ions
31. 3-iodanes
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34. Facile fragmentation of alkenyl(aryl)iodonium triflates
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41. Chirality transfer from 4-methylcyclohexylidenemethyl(phenyl)iodonium tetrafluoroborate to 4-methylcycloheptanone during solvolysis: Evidence against a primary vinylic cation as intermediate
42. Solvolyse von cycloalkylidenemethyl- und 1-cyclopenten-1-yl-triflaten
43. Solvolysis of optically active 4-methylcyclohexylidenemethyl triflate: Evidence against a primary vinyl cation as an intermediate