Expanding the scope of arylsulfonylacetylenes as alkynylating reagents and mechanistic insights in the formation of Csp 2-Csp and Csp 3-Csp bonds from organolithiums

Chemistry - A European Journal

Volumn 18, Issue 27, 2012, Pages 8414-8422

  García Ruano, José Luis ^a   Alemán, José ^a   Marzo, Leyre ^a   Alvarado, Cuauhtémoc ^a   Tortosa, Mariola ^a   Díaz Tendero, Sergio ^a   Fraile, Alberto ^a  

^a UNIVERSIDAD AUTÓNOMA DE MADRID   (Spain)

Author keywords

alkynylation; anti Michael reactions; density functional calculations; organolithiums; sulfonylacetylenes

Indexed keywords

ALKYNYLATIONS; ALKYNYLS; ANTI-MICHAEL REACTIONS; ELECTROPHILES; EXPERIMENTAL PROCEDURE; HIGH YIELD; INTRAMOLECULAR ATTACK; ORGANOLITHIUM SPECIES; ORGANOLITHIUMS; SULFONYLACETYLENES; THEORETICAL CALCULATIONS;

ADDITION REACTIONS; DENSITY FUNCTIONAL THEORY; ISOMERS; TRANSITION METALS;

ASSOCIATION REACTIONS;

ALKYNE; DYES, REAGENTS, INDICATORS, MARKERS AND BUFFERS; LITHIUM; ORGANOMETALLIC COMPOUND;

ARTICLE; CATALYSIS; CHEMISTRY; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; SYNTHESIS;

ALKYNES; CATALYSIS; INDICATORS AND REAGENTS; LITHIUM; MAGNETIC RESONANCE SPECTROSCOPY; ORGANOMETALLIC COMPOUNDS;

EID: 84862740343     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.201200939     Document Type: Article

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