Molecular catalysis of the oxygen reduction reaction by iron porphyrin catalysts tethered into Nafion layers: An electrochemical study in solution and a membrane-electrode-assembly study in fuel cells

Journal of Power Sources

Volumn 216, Issue , 2012, Pages 67-75

  He, Qinggang ^a   Mugadza, Tawanda ^b   Kang, Xiongwu ^c   Zhu, Xiaobing ^a   Chen, Shaowei ^c   Kerr, John ^a   Nyokong, Tebello ^b  

^a LAWRENCE BERKELEY NATIONAL LABORATORY   (United States)

^b RHODES UNIVERSITY   (South Africa)

^c UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

Iron porphyrin; Nafion; Non noble metal; Oxygen reduction reaction; Three dimensional catalysis

Indexed keywords

CHARGE-TRANSFER RATE; DIRECT INTERACTIONS; ELECTROCHEMICAL STUDIES; FTIR; HALF-WAVE POTENTIAL; HOMOGENEOUS CATALYST; IN-SITU; IRON PORPHYRIN; IRON PORPHYRIN CATALYST; MEMBRANE ELECTRODE ASSEMBLIES; NAFION; NAFION IONOMERS; NAFION LAYERS; OXYGEN REDUCTION REACTION; PORPHINE; POSITIVE SHIFT; SPECTROELECTROCHEMICAL CHARACTERIZATION; SULFONIC GROUP; TRANSPORT PHENOMENA; WORKING ELECTRODE;

CATALYSIS; CATALYSTS; CHARGE TRANSFER; CHLORINE COMPOUNDS; ELECTROLYTIC REDUCTION; IRON; IRON COMPOUNDS; PLATINUM; PORPHYRINS; PRECIOUS METALS; PROTON EXCHANGE MEMBRANE FUEL CELLS (PEMFC); REACTION KINETICS; SPECTROELECTROCHEMISTRY; THREE DIMENSIONAL;

ELECTROCHEMICAL ELECTRODES;

EID: 84861984097     PISSN: 03787753     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jpowsour.2012.05.043     Document Type: Article

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