Cluster reactivity experiments: Employing mass spectrometry to investigate the molecular level details of catalytic oxidation reactions

Proceedings of the National Academy of Sciences of the United States of America

Volumn 105, Issue 47, 2008, Pages 18108-18113

  Johnson, Grant E ^a   Tyo, Eric C ^a   Castleman Jr , A W ^a  

^a PENNSYLVANIA STATE UNIVERSITY   (United States)

Author keywords

Carbon monoxide; Catalysis; Oxygen radical; Propylene; Tungsten oxide

Indexed keywords

CARBON DIOXIDE; CARBON MONOXIDE; OXYGEN; PLASTIC; PROPYLENE; PROPYLENE OXIDE; TUNGSTEN DERIVATIVE;

ARTICLE; CATALYSIS; CATALYST; CHEMICAL BOND; CHEMICAL REACTION; CLUSTER ANALYSIS; INDUSTRIAL PRODUCTION; MASS SPECTROMETRY; OXIDATION; POLLUTION; PRIORITY JOURNAL; QUADRUPOLE MASS SPECTROMETRY; STOICHIOMETRY;

EID: 57449110192     PISSN: 00278424     EISSN: 10916490     Source Type: Journal    
DOI: 10.1073/pnas.0801539105     Document Type: Article

References (67)

1. Castleman AW, Jr, Keesee RG (1988) Gas-phase clusters - Spanning the states of matter. Science 241:36-42.
2. Castleman AW, Jr, Keesee RG (1986) Clusters - Bridging the gas and condensed phases. Acc Chem Res 19:413-419.
3. Wei S, Tzeng WB, Castleman AW, Jr (1990) Kinetic energy release measurements of ammonia cluster ions during metastable decomposition and determination of cluster ion binding energies. J Chem Phys 92:332-339.
4. Dermota TE, Zhong Q, Castleman AW, Jr (2004) Ultrafast dynamics in cluster systems. Chem Rev 104:1861-1886.
5. Castleman AW, Jr, Jena P (2006) Clusters: A bridge between disciplines. Proc Natl Acad Sci USA 103:10552-10553.
6. Castleman AW, Jr, Jena P (2006) Clusters: A bridge across the disciplines of environment, materials science, and biology. Proc Natl Acad Sci USA 103:10554-10559.
7. Jena P, Castleman AW, Jr (2006) Clusters: A bridge across the disciplines of physics and chemistry. Proc Natl Acad Sci USA 103:10560-10569.
8. Castleman AW, Jr, Bowen KH (1996) Clusters: Structure, energetics, and dynamics of intermediate states of matter. J Phys Chem 100:12911-12944.
9. Khanna SN, Castleman AW, Jr (2003) in Quantum Phenomena in Clusters and Nanostructures, eds Khanna SN, Castleman AW, Jr (Springer, New York)
10. Milani P, deHeer WA (1990) Improved pulsed laser vaporization source for production of intense beams of neutral and ionized clusters. Rev Sci Instrum 61:1835-1838.
11. Wagner RL, Vann WD, Castleman AW, Jr (1997) A technique for efficiently generating bimetallic clusters. Rev Sci Instrum 68:3010-3013.
12. Bouwen W, et al. (2000) Production of bimetallic clusters by a dual-target dual-laser vaporization source. Rev Sci Instrum 71:54-58.
13. Siekmann HR, Luder C, Faehrmann J, Lutz HO, Meiwesbroer KH (1991) The pulsed arc cluster ion source (PACIS). Z Phys D 20:417-420.
14. Milani P, Piseri P, Barborini E, Iannotta S (1995) Pulsed vaporization sources for high efficiency production of metal clusters. Nanophase Materials 195:43-48.
15. Klipp B, et al. (2001) Deposition of mass-selected cluster ions using a pulsed arc cluster-ion source. Appl Phys A 73:547-554.
16. Schröder D, Roithova J, Schwarz H (2006) Electrospray ionization as a convenient new method for the generation of catalytically active iron-oxide ions in the gas phase. Int J Mass Spectrom 254:197-201.
17. Baker SH, et al. (1997) The construction of a gas aggregation source for the preparation of mass-selected ultrasmall metal particles. Rev Sci Instrum 68:1853-1857.
18. de Heer WA (1993) The physics of simple metal clusters: Experimental aspects and simple models. Rev Modern Phys 65:611-676.
19. 2,HD) from thermal to 30 eV c.m. J Chem Phys 83:166-189.
20. Rodgers MT, Armentrout PB (2000) Noncovalent metal-ligand bond energies as studied by threshold collision-induced dissociation. Mass Spectrom Rev 19:215-247.
21. Armentrout PB (2003) Guided ion beam studies of transition metal-ligand thermochemistry. Int J Mass Spectrom 227:289-302.
22. Armentrout PB (2003) Threshold collision-induced dissociations for the determination of accurate gas-phase binding energies and reaction barriers. Top Curr Chem 225:233-262.
23. Neal CM, Starace AK, Jarrold MF (2007) Ion calorimetry: Using mass spectrometry to measure melting points. J Am Soc Mass Spectrom 18:74-81.
24. Keesee RG, Castleman AW, Jr (1985) Thermochemical data on gas-phase ion-molecule association and clustering reactions. J Phys Chem Ref Data 15:1011-1072.
25. Adams NG (1994) Afterglow techniques with spectroscopic detection for determining the rate coefficients and products of dissociative electron-ion recombination. Int J Mass Spectrom Ion Processes 132:1-27.
26. Bronstrup M, Schröder D, Kretzschmar I, Schwarz H, Harvey J (2001) Platinum dioxide cation: easy to generate experimentally but difficult to describe theoretically. J Am Chem Soc 123:142-147.
27. -: Experiment and theory. J Am Chem Soc 125:10437-10445.
28. 2 mixtures. Eur J Inorg Chem 6:1171-1175.
29. +, m+n <6): Ion mobility measurements and density-functional calculations. J Chem Phys 120:677-684.
30. Wang LS, Wu HW (1998) in Advances in Metal and Semiconductor Clusters (JAI., Stamford. CT), Vol 4, pp 299-342.
31. Wang LS (2000) in Advanced Series in Physical Chemistry, ed Ng CY (World Scientific, Singapore), Vol 10, pp 854-957.
32. Sanov A, Lineberger WC (2004) Cluster anions: Structure, interactions, and dynamics in the sub-nanoscale regime. Phys Chem Chem Phys 6:2018-2032.
33. von Helden G, van Heijnsbergen D, Meijer G (2003) Resonant ionization using IR light: A new tool to study the spectroscopy and dynamics of gas-phase molecules and clusters. J Phys Chem A 107:1671-1688.
34. Oomens J, Sartakov BG, Meijer G, von Helden G (2006) Gas-phase infrared multiple photon dissociation spectroscopy of mass-selected molecular ions. Int J Mass Spectrom 254:1-19.
35. Zemski KA, Justes DR, Castleman AW, Jr (2002) Studies of metal oxide clusters: Elucidating reactive sites responsible for the activity of transition metal oxide catalysts. J Phys Chem B 106:6136-6148.
36. Bohme DK, Schwarz H (2005) Gas-phase catalysis by atomic and cluster metal ions: The ultimate single-site catalysts. Angew Chem Int Ed 44:2336-2354.
37. Kim YD (2004) Chemical properties of mass-selected coinage metal cluster anions: Towards obtaining molecular-level understanding of nanocatalysis. Int J Mass Spectrom 238:17-31.
38. Sanchez A, et al. (1999)) When gold is not noble: Nanoscale gold catalysts. J Phys Chem A 103:9573-9578.
39. Yoon B, et al. (2005) Charging effects on bonding and catalyzed oxidation of CO on Au-8 clusters on MgO. Science 307:403-407.
40. Greenwood NN, Earnshaw A (1997) in Chemistry of the Elements (Elsevier: Amsterdam).
41. Bordoloi A, Vinu A, Halligudi SB (2007) One-step synthesis of SBA-15 containing tungsten oxide nanoclusters: A chemoselective catalyst for oxidation of sulfides to sulfoxides under ambient conditions. Chem Commun 45:4806-4808.
42. Alvarez-Merino MA, Ribeiro MF, Silva JM, Carrasco-Marin F, Maldonado-Hodar FJ (2004) Activated carbon and tungsten oxide supported on activated carbon catalysts for toluene catalytic combustion. Environ Sci Technol 38:4664-4670.
43. Gielgens LH, van Kampen MGH, Broek MM, van Hardeveld R, Ponec V (1995) Skeletal isomerization of 1-butene on tungsten oxide catalysts. J Catal 154:201-207.
44. 2 Catalysts. Appl Catal A 107:249-266.
45. Moreno-Castilla C, Alvarez-Merina MA, Carrasco-Marin F (2000) Decomposition reactions of methanol and ethanol catalyzed by tungsten oxide supported on activated carbon. React Kinet Catal Lett 71:137-142.
46. n clusters (M = Mo, W; n = 3-5): A photoelectron spectroscopy and ab initio study. J Am Chem Soc 126:16134-16141.
47. 2 with reduced W sites on tungsten oxide surfaces. Angew Chem Int Ed 45:657-660.
48. 8 as a potential molecular model for O-deficient defect sites in tungsten oxides. J Phys Chem A 110:85-92.
49. Sun Q, et al. (2004) Effect of sequential oxidation on the electronic structure of tungsten clusters. Chem Phys Lett 387:29-34.
50. Sun Q, et al. (2004) Appearance of bulk properties in small tungsten oxide clusters. J Chem Phys 121:9417-9422.
51. Li S, Dixon D (2006) Molecular and electronic structures, Brönsted basicities, and Lewis acidities of group VIB transition metal oxide clusters. J Phys Chem A 110:6231-6244.
52. 2- (M = Mo, W) J Phys Chem A 111:11093-11099.
53. 2. Science 319:438-442.
54. + and ethylene. J Am Chem Soc 125:6289-6299.
55. + Angew Chem Int Ed 45:4681-4685, 2006.
56. Schröder D, Roithova J (2006) Low-temperature activation of methane: It also works without a transition metal. Angew Chem Int Ed 45:5705-5708.
57. Sierka M, et al. (2007) Unexpected structures of aluminum oxide clusters in the gas phase. Angew Chem Int Ed 46:3372-3375.
58. Bell RC, Zemski KA, Justes DR, Castleman AW, Jr (2001) Formation, structure and bond dissociation thresholds of gas-phase vanadium oxide cluster ions. J Chem Phys 114:798-811.
59. Anderson JB, Fenn JB (1965) Velocity distributions in molecular beams from nozzle sources. Phys Fluids 8:780.
60. +and ethylene. J Phys Chem B 110:3015-3022.
61. +. J Am Chem Soc 129:15311-15318.
62. Kobayashi H, Shimodaira Y (2006) Density functional study of propylene oxidation on Ag and Au surfaces. Comparison to ethylene oxidation. Theor Chem 762:57-67.
63. Song Z, et al. (2007) Gas-phase epoxidation of propylene through radicals generated by silica-supported molybdenum oxide. Appl Catal A 316:142-151.
64. Jakubikova E, Rappe A, Bernstein ER (2007) Density functional theory study of small vanadium oxide clusters. J Phys Chem A 111:12938-12943.
65. Fielicke A, et al. (2005) Gold cluster carbonyls: Saturated adsorption of CO on gold cluster cations, vib spectroscopy, and implications for their structures. J Am Chem Soc 127:8416-8423.
66. Bürgel C, et al. (2008) Influence of charge state on the mechanism of CO oxidation on gold clusters. J Am Chem Soc 130:1694-1698.
67. + (m = 1, 2; n = 1-5) with CO. J Phys Chem C 111:19086-19097.