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Volumn , Issue 22, 2007, Pages 3565-3572

Repeated dihydrogen elimination from boranes and gallanes stabilized by guanidine-type bases: A quantum chemical study motivated by recent experimental results

Author keywords

Group 13 elements; Hydrides; Hydrogen storage; Quantum chemical calculations

Indexed keywords

BORON COMPOUNDS; CHEMICAL BONDS; CYCLOADDITION; ELECTRONEGATIVITY; HYDROGEN STORAGE; QUANTUM CHEMISTRY; THERMODYNAMICS;

EID: 34547813635     PISSN: 14341948     EISSN: 10990682     Source Type: Journal    
DOI: 10.1002/ejic.200700336     Document Type: Article
Times cited : (15)

References (49)
  • 1
    • 85163224315 scopus 로고    scopus 로고
    • See, for example: M. P. Coles, Dalton Trans. 2006, 985-1001, and references given therein.
    • See, for example: M. P. Coles, Dalton Trans. 2006, 985-1001, and references given therein.
  • 9
    • 85152993567 scopus 로고    scopus 로고
    • Angew. Chem. Int. Ed. 2002, 41, 796-799;
    • (2002) Chem. Int. Ed , vol.41 , pp. 796-799
    • Angew1
  • 28
    • 85163225055 scopus 로고    scopus 로고
    • Angew. Chem. Int. Ed. 2004, 43, 4780-4782.
    • (2004) Chem. Int. Ed , vol.43 , pp. 4780-4782
    • Angew1
  • 29
    • 85163229446 scopus 로고    scopus 로고
    • Of course, it cannot be completely excluded that an intramolecular process is the first step of the dehydrogenation reaction. However, the strong intramolecular H⋯H contacts favour an intramolecular process
    • Of course, it cannot be completely excluded that an intramolecular process is the first step of the dehydrogenation reaction. However, the strong intramolecular H⋯H contacts favour an intramolecular process.
  • 39
    • 85163228160 scopus 로고    scopus 로고
    • Earlier examples of molecules with B=B bonds include tris-(mesity) phenyldiborate and 1,2-bis(dimethylamino)-1,2-diphenyldiborate. See:a) A. Moezzi, M. M. Olmstead, P. P. Power, J. Am. Chem. Soc. 1992, 114, 2715-2717;
    • Earlier examples of molecules with B=B bonds include tris-(mesity) phenyldiborate and 1,2-bis(dimethylamino)-1,2-diphenyldiborate. See:a) A. Moezzi, M. M. Olmstead, P. P. Power, J. Am. Chem. Soc. 1992, 114, 2715-2717;
  • 41
    • 85163228357 scopus 로고
    • Angew. Chem. Int. Ed. 1992, 31, 1082-1083.
    • (1992) Chem. Int. Ed , vol.31 , pp. 1082-1083
    • Angew1
  • 42
    • 85163233834 scopus 로고    scopus 로고
    • 2 (O. Ciobanu, P. Roquette, S. Leingang, H. Wadepohl, J. Mautz, H.-J. Himmel, Eur. J. Inorg. Chem., in press).
    • 2 (O. Ciobanu, P. Roquette, S. Leingang, H. Wadepohl, J. Mautz, H.-J. Himmel, Eur. J. Inorg. Chem., in press).


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.