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Volumn 10, Issue 19, 2012, Pages 3841-3851

Origin of the synchronicity in bond formation in polar Diels-Alder reactions: An ELF analysis of the reaction between cyclopentadiene and tetracyanoethylene

Author keywords

[No Author keywords available]

Indexed keywords

BOND FORMATION; C-C BOND FORMATION; CHARGE TRANSFER PROCESS; COMPARATIVE ANALYSIS; CYCLOPENTADIENES; DIELS-ALDER; DIELS-ALDER REACTION; ELECTROPHILES; RADICAL ANIONS; SYMMETRIC DISTRIBUTIONS; TETRACYANOETHYLENE;

EID: 84860354384     PISSN: 14770520     EISSN: None     Source Type: Journal    
DOI: 10.1039/c2ob25152c     Document Type: Article
Times cited : (56)

References (54)
  • 11
    • 70349289161 scopus 로고    scopus 로고
    • Synchronous or asynchronous processes can be related to the extension of bond formation of the two C-C σ bonds that are being formed in a cycloaddition reaction. While in a synchronous process the two new σ bonds are formed to the same extent, in an asynchronous process formation of one σ bond is advanced with respect to the other
    • L. R. Domingo J. A. Sáez Org. Biomol. Chem. 2009 7 3576 3583
    • (2009) Org. Biomol. Chem. , vol.7 , pp. 3576-3583
    • Domingo, L.R.1    Sáez, J.A.2
  • 23
    • 78649505668 scopus 로고    scopus 로고
    • In 1960 Errede et al. studied the high chemical reactivity of p-xylylene, which was attributed to its pseudodiradical character. They defined a pseudodiradical as a diamagnetic compound that behaves chemically as if were a diradical.
    • L. R. Domingo E. Chamorro P. Pérez Org. Biomol. Chem. 2010 8 5495 5504
    • (2010) Org. Biomol. Chem. , vol.8 , pp. 5495-5504
    • Domingo, L.R.1    Chamorro, E.2    Pérez, P.3
  • 31
    • 0003354199 scopus 로고
    • Geometry Optimization on Potential Energy Surface
    • in, ed. D. R. Yarkony, World Scientific Publishing, Singapore
    • H. B. Schlegel, Geometry Optimization on Potential Energy Surface, in Modern Electronic Structure Theory, ed., D. R. Yarkony, World Scientific Publishing, Singapore, 1994
    • (1994) Modern Electronic Structure Theory
    • Schlegel, H.B.1
  • 54
    • 78651497656 scopus 로고    scopus 로고
    • A zwitterionic pseudodiradical species is a pseudodiradical which presents a charge separation between two fragments of the species
    • L. R. Domingo J. A. Sáez J. Org. Chem. 2011 76 373 379
    • (2011) J. Org. Chem. , vol.76 , pp. 373-379
    • Domingo, L.R.1    Sáez, J.A.2


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.