Iron speciation and mixing in single aerosol particles from the Asian continental outflow

Journal of Geophysical Research Atmospheres

Volumn 117, Issue 7, 2012, Pages

  Moffet, Ryan C ^a,b   Furutani, Hiroshi ^c   Rödel, Tobias C ^a,d   Henn, Tobias R ^a,d   Sprau, Peter O ^a,d   Laskin, Alexander ^e   Uematsu, Mitsuo ^c   Gilles, Mary K ^a  

^a LAWRENCE BERKELEY NATIONAL LABORATORY   (United States)

^b UNIVERSITY OF THE PACIFIC   (United States)

^c UNIVERSITY OF TOKYO   (Japan)

^d UNIVERSITY OF WÜRZBURG   (Germany)

^e PACIFIC NORTHWEST NATIONAL LABORATORY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ATMOSPHERIC AEROSOLS; CLIMATE CONTROL; COAL COMBUSTION; DUST; IRON COMPOUNDS; SOLUBILITY;

AEROSOL PARTICLES; AMBIENT PARTICLES; ANTHROPOGENIC SOURCES; ATMOSPHERIC PARTICLES; ATMOSPHERIC POLLUTION; CARBON BUDGETS; CHEMICAL COMPOSITIONS; CONTINENTAL OUTFLOW; ESSENTIAL NUTRIENTS; EXPERIMENTAL UNCERTAINTY; IRON SOURCES; MINERAL DUST; OXIDATION STATE; SINGLE PARTICLE; WEIGHTED AVERAGES;

IRON;

AEROSOL; ANTHROPOGENIC SOURCE; ATMOSPHERIC POLLUTION; BIOAVAILABILITY; CARBON BUDGET; CHEMICAL COMPOSITION; DUST; IRON; MARINE ATMOSPHERE; MINERAL; MIXING; OUTFLOW; OXIDATION; POLLUTANT TRANSPORT; SOLUBILITY; SPECIATION (CHEMISTRY);

CHINA; JAPAN; OKINAWA ISLAND; OKINAWA ISLANDS; OKINAWA [RYUKYU ISLANDS]; RYUKYU ISLANDS;

EID: 84859720173     PISSN: 01480227     EISSN: None     Source Type: Journal    
DOI: 10.1029/2011JD016746     Document Type: Article

References (63)

1. Acker, J. G., and G. Leptoukh (2007), Online analysis enhances use of NASA Earth science data, Eos Trans. AGU, 88(2), 14, doi:10.1029/2007EO020003.
2. Baker, A. R., and P. L. Croot (2010), Atmospheric and marine controls on aerosol iron solubility in seawater, Mar. Chem., 120, 4-13, doi:10.1016/j. marchem.2008.09.003.
3. Boyd, P. W., and M. J. Ellwood (2010), The biogeochemical cycle of iron in the ocean, Nat. Geosci., 3, 675-682, doi:10.1038/ngeo964.
4. Boyd, P. W., et al. (2007), Mesoscale iron enrichment experiments 1993-2005: Synthesis and future directions, Science, 315, 612-617, doi:10.1126/science.1131669. (Pubitemid 46214699)
5. Cao, Y., et al. (2008), Abatement of mercury emissions in the coal combustion process equipped with a fabric filter baghouse, Fuel, 87, 3322-3330, doi:10.1016/j.fuel.2008.05.010.
6. Chan, C. K., and X. Yao (2008), Air pollution in mega cities in China, Atmos. Environ., 42, 1-42, doi:10.1016/j.atmosenv.2007.09.003. (Pubitemid 350298026)
7. Chen, H., et al. (2012), Coal fly ash as a source of iron in atmospheric dust, Environ. Sci. Technol., 46(4), 2112-2120, doi:10.1021/es204102f.
8. Chen, Y. Z., et al. (2004), Investigation of primary fine particulate matter from coal combustion by computer-controlled scanning electron microscopy, Fuel Process. Technol., 85, 743-761, doi:10.1016/j.fuproc.2003. 11.017.
9. Chen, Y. Z., et al. (2005), Transmission electron microscopy investigation of ultrafine coal fly ash particles, Environ. Sci. Technol., 39, 1144-1151, doi:10.1021/es049871p. (Pubitemid 40250319)
10. Chuang, P. Y., R. M. Duvall, M. M. Shafer, and J. J. Schauer (2005), The origin of water soluble particulate iron in the Asian atmospheric outflow, Geophys. Res. Lett., 32, L07813, doi:10.1029/2004GL021946. (Pubitemid 40959026)
11. Cprek, N., et al. (2007), Distinguishing respirable quartz in coal fly ash using computer-controlled scanning electron microscopy, Environ. Sci. Technol., 41, 3475-3480, doi:10.1021/es062938j. (Pubitemid 350067189)
12. Cwiertny, D. M., J. Baltrusaitis, G. J. Hunter, A. Laskin, M. M. Scherer, and V. H. Grassian (2008), Characterization and acid-mobilization study of iron-containing mineral dust source materials, J. Geophys. Res., 113, D05202, doi:10.1029/2007JD009332.
13. de Faria, D. L. A., et al. (1997), Raman microspectroscopy of some iron oxides and oxyhydroxides, J. Raman Spectrosc., 28, 873-878, doi:10.1002/(SICI) 1097-4555(199711)28:113.0. CO;2-B. (Pubitemid 127690621)
14. de Groot, F. M. F. (1994), X-ray absorption and dichroism of transition metals and their compounds, J. Electron Spectrosc. Relat. Phenom., 67, 529-622, doi:10.1016/0368-2048(93)02041-J.
15. Furutani, H., J. Jung, K. Miura, A. Takami, S. Kato, Y. Kajii, and M. Uematsu (2011), Single-particle chemical characterization and source apportionment of iron-containing atmospheric aerosols in Asian outflow, J. Geophys. Res., 116, D18204, doi:10.1029/2011JD015867.
16. Garvie, L. A. J., and P. R. Buseck (1998), Ratios of ferrous to ferric iron from nanometre-sized areas in minerals, Nature, 396, 667-670, doi:10.1038/25334. (Pubitemid 29003943)
17. Garvie, L. A. J., et al. (1994), Use of electron-energy loss near-edge fine structure in the study of minerals, Am. Mineral., 79, 411-425.
18. Guieu, C., S. Bonnet, T. Wagener, and M.-D. Loÿe-Pilot (2005), Biomass burning as a source of dissolved iron to the open ocean?, Geophys. Res. Lett., 32, L19608, doi:10.1029/2005GL022962. (Pubitemid 41694254)
19. Hanesch, M. (2009), Raman spectroscopy of iron oxides and (oxy)hydroxides at low laser power and possible applications in environmental magnetic studies, Geophys. J. Int., 177, 941-948, doi:10.1111/j.1365-246X. 2009.04122.x.
20. Hassler, C. S., et al. (2011), Saccharides enhance iron bioavailability to Southern Ocean phytoplankton, Proc. Natl. Acad. Sci. U. S. A., 108, 1076-1081, doi:10.1073/pnas.1010963108.
21. Hopkins, R. J., K. Lewis, Y. Desyaterik, Z. Wang, A. V. Tivanski, W. P. Arnott, A. Laskin, and M. K. Gilles (2007), Correlations between optical, chemical and physical properties of biomass burn aerosols, Geophys. Res. Lett., 34, L18806, doi:10.1029/2007GL030502. (Pubitemid 350186726)
22. Huang, K., G. Zhuang, J. Li, Q. Wang, Y. Sun, Y. Lin, and J. S. Fu (2010), Mixing of Asian dust with pollution aerosol and the transformation of aerosol components during the dust storm over China in spring 2007, J. Geophys. Res., 115, D00K13, doi:10.1029/2009JD013145.
23. Hwang, H., and C. U. Ro (2006), Single-particle characterization of "Asian Dust" certified reference materials using low-Z particle electron probe X-ray microanalysis, Spectrochim. Acta, B, 61, 400-406, doi:10.1016/j.sab.2006.01.013.
24. Iwamoto, Y., K. Yumimoto, M. Toratani, A. Tsuda, K. Miura, I. Uno, and M. Uematsu (2011), Biogeochemical implications of increased mineral particle concentrations in surface waters of the northwestern North Pacific during an Asian dust event, Geophys. Res. Lett., 38, L01604, doi:10.1029/2010GL045906.
25. Jickells, T. D. (1999), The inputs of dust derived elements to the Sargasso Sea: A synthesis, Mar. Chem., 68, 5-14, doi:10.1016/S0304-4203(99) 00061-4. (Pubitemid 30008201)
26. Jickells, T. D., et al. (2005), Global iron connections between desert dust, ocean biogeochemistry, and climate, Science, 308, 67-71, doi:10.1126/science.1105959. (Pubitemid 40470998)
27. Kauppinen, E. I., and T. A. Pakkanen (1990), Coal combustion aerosols- A field study, Environ. Sci. Technol., 24, 1811-1818, doi:10.1021/es00082a004.
28. Kilcoyne, A. L. D., et al. (2003), Interferometer-controlled scanning transmission X-ray microscopes at the advanced light source, J. Synchrotron Radiat., 10, 125-136, doi:10.1107/S0909049502017739. (Pubitemid 36515751)
29. Laskin, A., et al. (2006), Analysis of individual environmental particles using modern methods of electron microscopy and X-ray microanalysis, J. Electron Spectrosc. Relat. Phenom., 150, 260-274, doi:10.1016/j. elspec.2005.06.008. (Pubitemid 41737453)
30. Lewis, E. R., and S. E. Schwartz (2004), Sea Salt Aerosol Production: Mechanisms, Methods, Measurements, and Models-A Critical Review, Geophys. Monogr. Ser., vol. 152, AGU, Washington, D. C.
31. Lighty, J. S., et al. (2000), Combustion aerosols: Factors governing their size and composition and implications to human health, J. Air Waste Manage. Assoc., 50, 1565-1618.
32. Luo, C., N. Mahowald, T. Bond, P. Y. Chuang, P. Artaxo, R. Siefert, Y. Chen, and J. Schauer (2008), Combustion iron distribution and deposition, Global Biogeochem. Cycles, 22, GB1012, doi:10.1029/2007GB002964. (Pubitemid 351850859)
33. Mahowald, N. M., A. R. Baker, G. Bergametti, N. Brooks, R. A. Duce, T. D. Jickells, N. Kubilay, J. M. Prospero, and I. Tegen (2005), Atmospheric global dust cycle and iron inputs to the ocean, Global Biogeochem. Cycles, 19, GB4025, doi:10.1029/2004GB002402. (Pubitemid 43280688)
34. Mahowald, N. M., et al. (2009), Atmospheric iron deposition: Global distribution, variability, and human perturbations, Annu. Rev. Mar. Sci., 1, 245-278, doi:10.1146/annurev.marine.010908.163727.
35. Majestic, B. J., et al. (2006), Development of a wet-chemical method for the speciation of iron in atmospheric aerosols, Environ. Sci. Technol., 40, 2346-2351, doi:10.1021/es052023p.
36. Maldonado, M. T., and N. M. Price (1999), Utilization of iron bound to strong organic ligands by plankton communities in the subarctic Pacific Ocean, Deep Sea Res., Part II, 46, 2447-2473, doi:10.1016/S0967- 0645(99)00071-5. (Pubitemid 29508848)
37. Martin, J. H., et al. (1990), Iron in Antarctic waters, Nature, 345, 156-158, doi:10.1038/345156a0.
38. Meskhidze, N., W. L. Chameides, A. Nenes, and G. Chen (2003), Iron mobilization in mineral dust: Can anthropogenic SO2 emissions affect ocean productivity?, Geophys. Res. Lett., 30(21), 2085, doi:10.1029/ 2003GL018035.
39. Meskhidze, N., W. L. Chameides, and A. Nenes (2005), Dust and pollution: A recipe for enhanced ocean fertilization?, J. Geophys. Res., 110, D03301, doi:10.1029/2004JD005082. (Pubitemid 40533829)
40. Moffet, R. C., et al. (2010), Automated chemical analysis of internally mixed aerosol particles using X-ray spectromicroscopy at the carbon K-edge, Anal. Chem., 82, 7906-7914, doi:10.1021/ac1012909.
41. Nishikawa, M., et al. (2000), Preparation and evaluation of certified reference materials for Asian mineral dust, Global Environ. Res., 4, 103-113.
42. Ohta, A., et al. (2006), Chemical compositions and XANES speciations of Fe, Mn and Zn from aerosols collected in China and Japan during dust events, Geochem. J., 40, 363-376, doi:10.2343/geochemj.40.363. (Pubitemid 44509263)
43. Ooki, A., J. Nishioka, T. Ono, and S. Noriki (2009), Size dependence of iron solubility of Asian mineral dust particles, J. Geophys. Res., 114, D03202, doi:10.1029/2008JD010804.
44. Rebotier, T. P., and K. A. Prather (2007), Aerosol time-of-flight mass spectrometry data analysis: A benchmark of clustering algorithms, Anal. Chim. Acta, 585, 38-54, doi:10.1016/j.aca.2006.12.009. (Pubitemid 46176784)
45. Rue, E. L., and K. W. Bruland (1995), Complexation of iron(III) by natural organic-ligands in the central North Pacific as determined by a new competitive ligand equilibration adsorptive cathodic stripping voltammetric method, Mar. Chem., 50, 117-138, doi:10.1016/0304-4203(95)00031-L. (Pubitemid 26463192)
46. Schroth, A. W., et al. (2009), Iron solubility driven by speciation in dust sources to the ocean, Nat. Geosci., 2, 337-340, doi:10.1038/ngeo501.
47. Siefert, R. L., et al. (1994), Iron photochemistry of aqueous suspensions of ambient aerosol with added organic acids, Geochim. Cosmochim. Acta, 58, 3271-3279, doi:10.1016/0016-7037(94)90055-8.
48. Siefert, R. L., S. M. Webb, and M. R. Hoffmann (1996), Determination of photochemically available iron in ambient aerosols, J. Geophys. Res., 101, 14,441-14,449, doi:10.1029/96JD00857.
49. Song, Y., et al. (2006), Source apportionment of PM2.5 in Beijing by positive matrix factorization, Atmos. Environ., 40, 1526-1537, doi:10.1016/j. atmosenv.2005.10.039. (Pubitemid 43188904)
50. Streets, D. G., et al. (2003a), An inventory of gaseous and primary aerosol emissions in Asia in the year 2000, J. Geophys. Res., 108(D21), 8809, doi:10.1029/2002JD003093.
51. Streets, D. G., K. F. Yarber, J.-H. Woo, and G. R. Carmichael (2003b), Biomass burning in Asia: Annual and seasonal estimates and atmospheric emissions, Global Biogeochem. Cycles, 17(4), 1099, doi:10.1029/2003GB002040.
52. Stumm, W., and J. J. Morgan (1996), Aquatic Chemistry, Chemical Equilibria and Rates in Natural Waters, John Wiley, Hoboken, N. J.
53. Sun, Y. L., et al. (2010), Asian dust over northern China and its impact on the downstream aerosol chemistry in 2004, J. Geophys. Res., 115, D00K09, doi:10.1029/2009JD012757.
54. Sze, S. K., et al. (2001), Raman spectroscopic characterization of carbonaceous aerosols, Atmos. Environ., 35, 561-568, doi:10.1016/S1352-2310(00) 00325-3.
55. Uematsu, M., Z. Wang, and I. Uno (2003), Atmospheric input of mineral dust to the western North Pacific region based on direct measurements and a regional chemical transport model, Geophys. Res. Lett., 30(6), 1342, doi:10.1029/2002GL016645.
56. van Aken, P. A., et al. (1998), Quantitative determination of iron oxidation states in minerals using Fe L-2,L-3-edge electron energy-loss near-edge structure spectroscopy, Phys. Chem. Miner., 25, 323-327, doi:10.1007/s002690050122. (Pubitemid 128628047)
57. Van Vleck, J. H. (1932), Theory of the variations in paramagnetic anisotropy among different salts of the iron group, Phys. Rev., 41, 208-215, doi:10.1103/PhysRev.41.208.
58. Waheed, A., et al. (2011), Size distribution and sources of trace metals in ultrafine/fine/coarse airborne particles in the atmosphere of Shanghai, Aerosol Sci. Technol., 45, 163-171, doi:10.1080/02786826.2010. 528079.
59. Worms, I., et al. (2006), Bioavailability of trace metals to aquatic microorganisms: Importance of chemical, biological and physical processes on biouptake, Biochimie, 88, 1721-1731, doi:10.1016/j.biochi.2006.09.008. (Pubitemid 44802758)
60. Yao, Q., et al. (2010), Reprint of: Studies on formation and control of combustion particulate matter in China: A review, Energy, 35, 4480-4493, doi:10.1016/j.energy.2010.08.009.
61. Zhang, Q., et al. (2009), Asian emissions in 2006 for the NASA INTEX-B mission, Atmos. Chem. Phys., 9, 5131-5153, doi:10.5194/acp-9-5131- 2009.
62. Zheng, M., et al. (2005), Seasonal trends in PM2.5 source contributions in Beijing, China, Atmos. Environ., 39, 3967-3976, doi:10.1016/j. atmosenv.2005.03.036.
63. Zhuang, G. S., et al. (1992), Link between iron and sulfur cycles suggested by detection of Fe(II) in remote marine aerosols, Nature, 355, 537-539, doi:10.1038/355537a0.