Isotopic constraints on the formation pathways of sulfate aerosol in the marine boundary layer of the subtropical northeast Atlantic Ocean

Journal of Geophysical Research Atmospheres

Volumn 117, Issue 6, 2012, Pages

  Alexander, B ^a   Allman, D J ^a   Amos, H M ^a,b   Fairlie, T D ^c   Dachs, J ^d   Hegg, Dean A ^a   Sletten, Ronald S ^a  

^a UNIVERSITY OF WASHINGTON   (United States)

^b HARVARD UNIVERSITY   (United States)

^c NASA LANGLEY RESEARCH CENTER   (United States)

^d CSIC   (Spain)

Author keywords

[No Author keywords available]

Indexed keywords

ATMOSPHERIC AEROSOLS; BOUNDARY LAYERS; COASTAL ZONES; COMPUTER SIMULATION; OXIDATION; SULFUR; TROPICS;

ANTHROPOGENIC EMISSIONS; CHEMICAL HETEROGENEITIES; CHEMICAL TRANSPORT MODELS; CLOUD DROPLETS; COASTAL REGIONS; FORMATION PATHWAYS; IBERIAN PENINSULA; MARINE BOUNDARY LAYERS; MODEL PARAMETERIZATION; MODEL SIMULATION; NORTH EAST ATLANTIC; NORTHEAST ATLANTIC OCEAN; OXYGEN-17; SEA SALT AEROSOL; SHIP CRUISE; SULFATE AEROSOLS; SULFATE PRODUCTION; SULFUR EMISSIONS; TEMPORAL SCALE;

SULFUR COMPOUNDS;

AEROSOL COMPOSITION; ANTHROPOGENIC EFFECT; ATMOSPHERIC POLLUTION; BOUNDARY LAYER; CLOUD DROPLET; ISOTOPIC ANALYSIS; OXYGEN ISOTOPE; POLLUTANT TRANSPORT; SULFATE;

ATLANTIC OCEAN; ATLANTIC OCEAN (SUBTROPICAL); IBERIAN PENINSULA;

EID: 84859127503     PISSN: 01480227     EISSN: None     Source Type: Journal    
DOI: 10.1029/2011JD016773     Document Type: Article

References (109)

1. Adams, J. W., et al. (2005), The uptake of SO2 on Saharan dust: A flow tube study, Atmos. Chem. Phys., 5, 2679-2689, doi:10.5194/acp-5- 2679-2005. (Pubitemid 41646210)
2. Alexander, B., R. J. Park, D. J. Jacob, Q. B. Li, R. M. Yantosca, J. Savarino, C. C. W. Lee, and M. H. Thiemens (2005), Sulfate formation in sea-salt aerosols: Constraints from oxygen isotopes, J. Geophys. Res., 110, D10307, doi:10.1029/2004JD005659. (Pubitemid 40919779)
3. Alexander, B., R. J. Park, D. J. Jacob, and S. Gong (2009), Transition metal catalyzed oxidation of atmospheric sulfur: Global implications for the sulfur budget, J. Geophys. Res., 114, D02309, doi:10.1029/2008JD010486.
4. Andronache, C., W. L. Chameides, D. D. Davis, B. E. Anderson, R. F. Pueschel, A. R. Bandy, D. C. Thornton, R. W. Talbot, P. Kasibhatla, and C. S. Kiang (1997), Gas-to-particle conversion of tropospheric sulfur as estimated from observations in the western North Pacific during PEMWest B, J. Geophys. Res., 102(D23), 28,511-28,538, doi:10.1029/97JD01969.
5. Barkan, E., and B. Luz (2005), High precision measurements of 17O/16O and 18O/16O ratios in H 2O, Rapid Comm. Mass Spectrom., 19, 3737-3742, doi:10.1002/rcm.2250. (Pubitemid 41812683)
6. Burkholder, J. B., T. Baynard, A. R. Ravishankara, and E. R. Lovejoy (2007), Particle nucleation following the O and OH initiated oxidation of α-pinene and β-pinene between 278 and 320 K, J. Geophys. Res., 112, D10216, doi:10.1029/2006JD007783. (Pubitemid 47193643)
7. Cavalli, F., et al. (2004), Advances in characterization of size-resolved organic matter in marine aerosol over the North Atlantic, J. Geophys. Res., 109, D24215, doi:10.1029/2004JD005137. (Pubitemid 40335215)
8. Calvert, J. G., A. Lazrus, G. L. Kok, B. G. Heikes, J. G. Walega, J. Lind, and C. A. Cantrell (1985), Chemical mechanisms of acid generation in the troposphere, Nature, 317, 27-35, doi:10.1038/317027a0.
9. Chameides, W. L. (1984), The photochemistry of remote marine stratiform cloud, J. Geophys. Res., 89, 4739-4755, doi:10.1029/JD089iD03p04739.
10. Chameides, W. L., and A. W. Stelson (1992), Aqueous-phase chemical processes in deliquescent sea-salt aerosols: A mechanism that couples the atmospheric cycles of S and sea salt, J. Geophys. Res., 97(D18), 20,565-20,580.
11. Dachs, J., M. L. Calleja, C. M. Duarte, S. del Vento, B. Turpin, A. Polidori, G. J. Herndl, and S. Agustí (2005), High atmosphere-ocean exchange of organic carbon in the NE subtropical Atlantic, Geophys. Res. Lett., 32, L21807, doi:10.1029/2005GL023799. (Pubitemid 43000774)
12. Dentener, F., et al. (2002), Aqueous phase reaction of HNO4: The impact on tropospheric chemistry, J. Atmos. Chem., 41, 109-133, doi:10.1023/A:1014233910126. (Pubitemid 34213291)
13. Dominguez, G., et al. (2008), Discovery and measurement of an isotopically distinct source of sulfate in Earth's atmosphere, Proc. Natl. Acad. Sci. U. S. A., 105(35), 12,769-12,773, doi:10.1073/pnas.0805255105.
14. Duarte, C. M., J. Dachs, M. Llabrés, P. Alonso-Laita, J. M. Gasol, A. Tovar-Sánchez, S. Sañudo-Wilhemy, and S. Agustí (2006), Aerosol inputs enhance new production in the subtropical northeast Atlantic, J. Geophys. Res., 111, G04006, doi:10.1029/2005JG000140. (Pubitemid 47491020)
15. Fahey, K. M., and S. N. Pandis (2001), Optimizing model performance: Variable size resolution in cloud chemistry modeling, Atmos. Environ., 35, 4471-4478, doi:10.1016/S1352-2310(01)00224-2.
16. Fahey, K. M., and S. N. Pandis (2003), Size-resolved aqueous-phase atmospheric chemistry in a three-dimensional chemical transport model, J. Geophys. Res., 108(D22), 4690, doi:10.1029/2003JD003564.
17. Fairlie, T. D., et al. (2007), The impact of transpacific transport of mineral dust in the United States, Atmos. Environ., 41, 1251-1266, doi:10.1016/j. atmosenv.2006.09.048.
18. Fairlie, T. D., et al. (2010), Impact of mineral dust on nitrate, sulfate and ozone in transpacific Asian pollution plumes, Atmos. Chem. Phys., 10, 3999-4012, doi:10.5194/acp-10-3999-2010.
19. Faloona, I. (2009), Sulfur processing in the marine atmospheric boundary layer: A review and critical assessment of modeling uncertainties, Atmos. Environ., 43(18), 2841-2854, doi:10.1016/j.atmosenv.2009.02.043.
20. Faloona, I., et al. (2010), Sulfur dioxide in the tropical marine boundary layer: Dry deposition and heterogeneous oxidation observed during the Pacific Atmospheric Sulfur Experiment, J. Atmos. Chem., 63(1), 13-32, doi:10.1007/s10874-010-9155-0.
21. Feingold, G., G. J. Frost, and A. R. Ravishankara (2002), Role of NO 3 in sulfate production in wintertime northern latitudes, J. Geophys. Res., 107(D22), 4640, doi:10.1029/2002JD002288. (Pubitemid 43211906)
22. Fernández-Fernández, M. I., et al. (2011), A study of surface ozone variability over the Iberian Peninsula during the last fifty years, Atmos. Environ., 45, 1946-1959, doi:10.1016/j.atmosenv.2011.01.027.
23. Fogelman, K. D., et al. (1989), Non-metal redox kinetics-Hypochlorite and hypochlorous acid reactions with sulfite, Inorg. Chem., 28, 986-993, doi:10.1021/ic00305a002.
24. Fountoukis, C., and A. Nenes (2007), ISORROPIA II: A computationally efficient thermodynamic equilibrium model for K+-Ca 2+-Mg2+-NH4+-Na+-SO 42--NO3--Cl--H 2O aerosols, Atmos. Chem. Phys., 7, 4639-4659, doi:10.5194/acp-7- 4639-2007. (Pubitemid 47409768)
25. Frenzel, A., et al. (1998), Heterogeneous interconversion reactions of BrNO2, ClNO2, Br2, and Cl2, J. Phys. Chem. A, 102, 1329-1337, doi:10.1021/jp973044b. (Pubitemid 128576509)
26. Generoso, S., I. Bey, M. Labonne, and F.-M. Bréon (2008), Aerosol vertical distribution in dust outflow over the Atlantic: Comparisons between GEOS-Chem and Cloud-Aerosol Lidar and infrared Pathfinder Satellite Observation (CALIPSO), J. Geophys. Res., 113, D24209, doi:10.1029/2008JD010154.
27. Gioda, A., et al. (2009), Chemical composition of cloud water in the Puerto Rican tropical trade wind cumuli, Water Air Soil Pollut., 200, 3-14, doi:10.1007/s11270-008-9888-4.
28. Gong, S. L., L. A. Barrie, and M. Lazare (2002), Canadian aerosol module (CAM): A size-segregated simulation of atmospheric aerosol processes for climate and air quality models-2. Global sea-salt aerosol and its budgets, J. Geophys. Res., 107(D24), 4779, doi:10.1029/2001JD002004. (Pubitemid 44793946)
29. Hahn, C. J., and S. G. Warren (2007), A gridded climatology of clouds over land (1971-96) and ocean (1954-97) from surface observations worldwide, Numer. Data Package NDP-026E, Carbon Dioxide Inf. Anal. Cent., Dep. of Energy, Oak Ridge, Tenn.
30. Halperin, J., and H. Taube (1952), The transfer of oxygen atoms in oxidation-reduction reactions. III. The reaction of halogenates with sulfite in aqueous solution, J. Am. Chem. Soc., 74(2), 375-380, doi:10.1021/ja01122a026.
31. Hegg, D. A., and P. V. Hobbs (1986), Sulfate and nitrate chemistry in cumuliform clouds, Atmos. Environ., 20(5), 901-909, doi:10.1016/0004-6981(86) 90274-X. (Pubitemid 16041449)
32. Hegg, D. A., et al. (1984a), Measurements of the scavenging of sulfate and nitrate in clouds, Atmos. Environ., 18(9), 1939-1946, doi:10.1016/0004- 6981(84)90371-8. (Pubitemid 15190856)
33. Hegg, D. A., et al. (1984b), Measurements of transformations in the physical and chemical properties of clouds associated with onshore flow in Washington State, J. Appl. Clim. Meteorol., 23, 979-984, doi:10.1175/1520- 0450(1984)023<0979:MOTITP>2.0.CO;2.
34. Hegg, D. A., P.-F. Yuen, and T. V. Larson (1992), Modeling the effects of heterogeneous cloud chemistry on the marine particle size distribution, J. Geophys. Res, 97(D12), 12,927-912,933.
35. Hoag, K. J., et al. (1999), The influence of drop size-dependent fog chemistry on aerosol processing by San Joaquin Valley fogs, Atmos. Environ., 33, 4817-4832, doi:10.1016/S1352-2310(99)00268-X. (Pubitemid 29488598)
36. Hoffmann, M. R., and D. J. Jacob (1984), Kinetics and mechanisms of the catalytic oxidation of dissolved sulfur dioxide in aqueous solution: An application to nighttime fog water chemistry, in SO2, NO, and NO 2 Oxidation Mechanisms: Atmospheric Considerations, edited by J. G. Calvert, pp. 63-100, Butterworth, Stoneham, Mass.
37. Holland, H. D. (1978), The Chemistry of the Atmosphere and Oceans, Wiley-Interscience, New York.
38. Holt, B. C., R. Kumar, and P. T. Cunningham (1981), Oxygen-18 study of the aqueous-phase oxidation of sulfur dioxide, Atmos. Environ., 15(4), 557-566, doi:10.1016/0004-6981(81)90186-4. (Pubitemid 11104150)
39. Iraci, L. T., et al. (2005), Uptake of hypobromous acid (HOBr) by aqueous sulfuric acid solutions: Low-temperature solubility and reaction, Atmos. Chem. Phys., 5, 1577-1587, doi:10.5194/acp-5-1577-2005. (Pubitemid 41136716)
40. Jaeglé, L., et al. (2011), Global distribution of sea salt aerosols: New constraints from in situ and remote sensing observations, Atmos. Chem. Phys., 11, 3137-3157, doi:10.5194/acp-11-3137-2011.
41. Jenkins, K. A., and H. Bao (2006), Multiple oxygen and sulfur isotope compositions of atmospheric sulfate in Baton Rouge, LA, USA, Atmos. Environ., 40(24), 4528-4537, doi:10.1016/j.atmosenv.2006.04.010.
42. Kaufman, Y. J., and D. Tanre (1994), Effect of variations in supersaturation on the formation of cloud condensation nuclei, Nature, 369(6475), 45-48, doi:10.1038/369045a0.
43. Klein, S. A., and S. L. Hartmann (1993), The seasonal cycle of low stratiform clouds, J. Clim., 6, 1587-1606, doi:10.1175/1520-0442(1993) 006<1587:TSCOLS>2.0.CO;2. (Pubitemid 24396418)
44. Krueger, B. J., et al. (2004), Heterogeneous chemistry of individual mineral dust particles from different dust source regions: The importance of particle mineralogy, Atmos. Environ., 38(36), 6253-6261, doi:10.1016/j. atmosenv.2004.07.010. (Pubitemid 39445802)
45. Kulmala, M., et al. (2000), Stable sulphate clusters as a source of new atmospheric particles, Nature, 404(6773), 66-69, doi:10.1038/35003550. (Pubitemid 30143131)
46. Kunasek, S. A., B. Alexander, E. J. Steig, M. G. Hastings, D. J. Gleason, and J. C. Jarvis (2008), Measurements and modeling of Δ17O of nitrate in a snowpit from Summit, Greenland, J. Geophys. Res., 113, D24302, doi:10.1029/2008JD010103.
47. Kunasek, S. A., B. Alexander, E. J. Steig, E. D. Sofen, T. L. Jackson, M. H. Thiemens, J. R. McConnell, D. J. Gleason, and H. M. Amos (2010), Sulfate sources and oxidation chemistry over the past ∼230 years from sulfur and oxygen isotopes of sulfate in a West Antarctic ice core, J. Geophys. Res., 115, D18313, doi:10.1029/2010JD013846.
48. Lapina, K., et al. (2011), Investigating organic aerosol loading in the remote marine environment, Atmos. Chem. Phys., 11, 8847-8860, doi:10.5194/acp-11-8847-2011.
49. Lawler, M. J., et al. (2011), HOCl and Cl2 observations in marine air, Atmos. Chem. Phys., 11, 7617-7628, doi:10.5194/acp-11-7617-2011.
50. Lee, C. C. W., and M. H. Thiemens (2001), The δ17O and δ18O measurements of atmospheric sulfate from a coastal and high alpine region: A massindependent anomaly, J. Geophys. Res., 105(D15), 17,359-317,373.
51. Lee, C. C.-W., J. Savarino, and M. H. Thiemens (2001), Mass independent oxygen isotopic composition of atmospheric sulfate: Origin and implications for the present and past atmospheres of Earth and Mars, Geophys. Res. Lett., 28(9), 1783-1786, doi:10.1029/2000GL011826. (Pubitemid 32579663)
52. Lee, Y. N., and S. E. Schwartz (1983), Kinetics of oxidation of aqueous sulfur(IV) by nitrogen dioxide, in Precipitation Scavenging, Dry Deposition and Resuspension, Proceedings of the Fourth International Conference, Santa Monica, California, 29 November-3 December 1982, edited by H. R. Pruppacher, R. G. Semonin, and W. G. N. Slinn, pp. 453-470, Elsevier, New York.
53. Lenschow, D. H., et al. (1988), Dynamics and Chemistry of Marine Stratocumulus (DYCOMS) experiment, Bull. Am. Meteorol. Soc., 69(9), 1058-1067, doi:10.1175/1520-0477(1988)069<1058:DACOMS>2.0.CO;2.
54. Leser, H., G. Honninger, and U. Platt (2003), MAX-DOAS measurements of BrO and NO2 in the marine boundary layer, Geophys. Res. Lett., 30(10), 1537, doi:10.1029/2002GL015811.
55. Lewis, E. R., and S. E. Schwartz (2006), Comment on "Size distribution of sea-salt emissions as a function of relative humidity," Atmos. Environ., 40(3), 588-590, doi:10.1016/j.atmosenv.2005.08.043. (Pubitemid 41797518)
56. Li, L., et al. (2006), Kinetics and mechanism of heterogeneous oxidation of sulfur dioxide by ozone on surface of calcium carbonate, Atmos. Chem. Phys., 6, 2453-2464, doi:10.5194/acp-6-2453-2006. (Pubitemid 43980754)
57. Lyons, J. R. (2001), Transfer of mass-independent fractionation on ozone to other oxygen-containing molecules in the atmosphere, Geophys. Res. Lett., 28, 3231-3234, doi:10.1029/2000GL012791. (Pubitemid 32931856)
58. Mace, G. G., et al. (2011), Critical evaluation of the ISCCP simulator using ground-based remote sensing data, J. Clim., 24, 1598-1612, doi:10.1175/2010JCLI3517.1.
59. Mahajan, A. S., et al. (2010), Measurement and modelling of tropospheric reactive halogen species over the tropical Atlantic Ocean, Atmos. Chem. Phys., 10, 4611-4624, doi:10.5194/acp-10-4611-2010.
60. Matsuhisa, Y., et al. (1978), Mechanisms of hydrothermal crystallization of quartz at 250°C and 15 kbar, Geochim. Cosmochim. Acta, 42, 173-182, doi:10.1016/0016-7037(78)90130-8.
61. McCabe, J. R., J. Savarino, B. Alexander, S. Gong, and M. H. Thiemens (2006), Isotopic constraints on non-photochemical sulfate production in the Arctic winter, Geophys. Res. Lett., 33, L05810, doi:10.1029/2005GL025164.
62. Millet, D. B., D. J. Jacob, K. F. Boersma, T.-M. Fu, T. P. Kurosu, K. Chance, C. L. Heald, and A. Guenther (2008), Spatial distribution of isoprene emissions from North America derived from formaldehyde column measurements by the OMI satellite sensor, J. Geophys. Res., 113, D02307, doi:10.1029/ 2007JD008950.
63. Moore, K. F., et al. (2004), Drop size-dependent chemical composition in clouds and fogs. I. Observations, Atmos. Environ., 38(10), 1389-1402, doi:10.1016/j.atmosenv.2003.12.013. (Pubitemid 38209973)
64. Mvula, E., and C. von Sonntag (2003), Ozonolysis of phenols in aqueous solution, Org. Biomol. Chem., 1, 1749-1756, doi:10.1039/b301824p.
65. Nenes, A., et al. (1998), ISORROPIA: A new thermodynamic equilibrium model formultiphasemulticomponent inorganic aerosols, Aquat. Geochem., 4, 123-152, doi:10.1023/A:1009604003981. (Pubitemid 29126367)
66. Neuman, J. A., et al. (2010), Bromine measurements in ozone depleted air over the Arctic Ocean, Atmos. Chem. Phys., 10, 6503-6514, doi:10.5194/acp-10- 6503-2010.
67. O'Dowd, C. D., J. A. Lowe, N. Clegg, M. H. Smith, and S. L. Clegg (2000), Modeling heterogeneous sulphate formation in maritime stratiform clouds, J. Geophys. Res., 105(D6), 7143-7160, doi:10.1029/1999JD900915.
68. O'Dowd, C. D., et al. (2002), Marine aerosol formation from biogenic iodine emissions, Nature, 417(6889), 632-636, doi:10.1038/nature00775. (Pubitemid 34614818)
69. Ovadnevaite, J., C. O'Dowd, M. Dall'Osto, D. Ceburnis, D. R. Worsnop, and H. Berresheim (2011), Detecting high contributions of primary organic matter to marine aerosol: A case study, Geophys. Res. Lett., 38, L02807, doi:10.1029/2010GL046083.
70. Park, R. J., D. J. Jacob, B. D. Field, R. M. Yantosca, and M. Chin (2004), Natural and transboundary pollution influences on sulfate- nitrateammonium aerosols in the United States: Implications for policy, J. Geophys. Res., 109, D15204, doi:10.1029/2003JD004473.
71. Patris, N., R. J. Delmas, and J. Jouzel (2000), Isotopic signatures of sulfur in shallow Antarctic ice cores, J. Geophys. Res., 105(D6), 7071-7078, doi:10.1029/1999JD900974.
72. Patris, N., S. S. Cliff, P. K. Quinn, M. Kasem, and M. H. Thiemens (2007), Isotopic analysis of aerosol sulfate and nitrate during ITCT-2k2: Determination of different formation pathways as a function of particle size, J. Geophys. Res., 112, D23301, doi:10.1029/2005JD006214.
73. Pope, F. D., et al. (2010), Ozonolysis of maleic acid aerosols: Effect upon aerosol hygroscopicity, phase and mass, Environ. Sci. Technol., 44, 6656-6660, doi:10.1021/es1008278.
74. Preszler Prince, A., et al. (2007), Heterogeneous interactions of calcite aerosol with sulfur dioxide and sulfur dioxide nitric acid mixtures, Phys. Chem. Chem. Phys., 9, 3432-3439, doi:10.1039/b703296j.
75. Read, K. A., et al. (2008), Extensive halogen-mediated ozone destruction over the tropical Atlantic Ocean, Nature, 453(7199), 1232-1235, doi:10.1038/nature07035. (Pubitemid 351913601)
76. Roelofs, G. J. H. (1993), A cloud chemistry sensitivity study and comparison of explicit and bulk cloud model performance, Atmos. Environ., Part A, 27(15), 2255-2264.
77. Saiz-Lopez, A., J. M. C. Plane, and J. A. Shillito (2004), Bromine oxide in the mid-latitude marine boundary layer, Geophys. Res. Lett., 31, L03111, doi:10.1029/2003GL018956.
78. Saiz-Lopez, A., et al. (2006), Measurements and modelling of I 2, IO, OIO, BrO and NO3 in the mid-latitude marine boundary layer, Atmos. Chem. Phys., 6, 1513-1528, doi:10.5194/acp-6-1513-2006. (Pubitemid 44198627)
79. Sakamoto, K., et al. (2004), Influence of ozone, relative humidity, and flow rate on the deposition and oxidation of sulfur dioxide on yellow sand, Atmos. Environ., 38, 6961-6967, doi:10.1016/j.atmosenv.2004.05.060. (Pubitemid 39572382)
80. Savarino, J., and M. H. Thiemens (1999), Analytical procedure to determine both δ18O and δ17O of H 2O2 in natural water and first measurements, Atmos. Environ., 33, 3683-3690, doi:10.1016/S1352-2310(99)00122-3. (Pubitemid 29324725)
81. Savarino, J., C. C. W. Lee, and M. H. Thiemens (2000), Laboratory oxygen isotopic study of sulfur (IV) oxidation: Origin of the mass-independent isotopic anomaly in atmospheric sulfates and sulfate mineral deposits on Earth, J. Geophys. Res., 105, 29,079-29,088, doi:10.1029/2000JD900456. (Pubitemid 32281854)
82. Savarino, J., et al. (2001), Sulfur and oxygen isotope analysis of sulfate at micromole levels using a pyrolysis technique in a continuous flow system, Anal. Chem., 73, 4457-4462, doi:10.1021/ac010017f. (Pubitemid 32868246)
83. Savarino, J., S. Bekki, J. Cole-Dai, and M. H. Thiemens (2003), Evidence from sulfate mass independent oxygen isotopic compositions of dramatic changes in atmospheric oxidation following massive volcanic eruptions, J. Geophys. Res., 108(D21), 4671, doi:10.1029/2003JD003737.
84. Savarino, J., et al. (2008), The NO+O3 reaction: A triple oxygen isotope perspective on the reaction dynamics and atmospheric implications for the transfer of the ozone isotope anomaly, J. Chem. Phys., 128(19), 194303, doi:10.1063/1.2917581. (Pubitemid 351733973)
85. Schumann, T. (1991), Aerosol and hydrometeor concentrations and their chemical-composition during winter precipitation along a mountain slope. 3. Size-differentiated in-cloud scavenging efficiencies, Atmos. Environ., 35(3-4), 809-824.
86. Schwartz, S. E. (1986), Mass-transport considerations pertinent to aqueousphase reactions of gases in liquid-water clouds, in Chemistry of Multiphase Atmospheric Systems, edited by W. Jaechske, pp. 415-471, Springer, Heidelberg, Germany, doi:10.1007/978-3-642-70627-1-16.
87. Schwartz, S. E. (1987), Aqueous-phase reactions in clouds, in The Chemistry of Acid Rain: Sources and Atmospheric Processes, edited by G. E. G. Russell and W. Johnson, pp. 93-108, Am. Chem. Soc., Washington, D. C., doi:10.1021/bk-1987-0349.ch008.
88. Seinfeld, J. H., and S. N. Pandis (1998), Chemistry of the aqueous phase, in Atmospheric Chemistry and Physics: From Air Pollution to Climate Change, pp. 337-407, Wiley-Interscience, New York.
89. Seisel, S., et al. (2006), Kinetics of the uptake of SO2 on mineral oxides: Improved initial uptake coefficients at 298 K from pulsed Knudsen cell experiments, Int. J. Chem. Kinet., 38(4), 242-249, doi:10.1002/kin.20148.
90. Sellegri, K., P. Laj, R. Dupuy, M. Legrand, S. Preunkert, and J.-P. Putaud (2003), Size-dependent scavenging efficiencies of multicomponent atmospheric aerosols in clouds, J. Geophys. Res., 108(D11), 4334, doi:10.1029/2002JD002749.
91. Smith, S. J., et al. (2011), Anthropogenic sulfur dioxide emissions: 1850-2005, Atmos. Chem. Phys., 11, 1101-1116, doi:10.5194/acp-11-1101-2011.
92. Sofen, E. D., et al. (2011), The impact of anthropogenic emissions on atmospheric sulfate production pathways, oxidants, and ice core Δ17O(SO42-), Atmos. Chem. Phys., 11, 3565-3578, doi:10.5194/acp-11-3565-2011.
93. Solomon, S. et al. (2007), Technical summary, in Climate Change 2007: The Physical Science Basis. Contribution of Working Group I to the Fourth Assessment Report of the Intergovernmental Panel on Climate Change, edited by S. Solomon et al., pp. 19-87, Cambridge Univ. Press, Cambridge, U. K.
94. Stockwell, W. R., and J. G. Calvert (1983), The mechanism of the HO-SO2 reaction, Atmos. Environ., 17(11), 2231-2235, doi:10.1016/0004-6981(83)90220-2. (Pubitemid 14179967)
95. Troy, R. C., and D. W. Margerum (1991), Non-metal redox kinetics: Hypobromite and hypobromous acid reactions with iodide and with sulfite and the hydrolysis of bromosulfate, Inorg. Chem., 30, 3538-3543, doi:10.1021/ ic00018a028.
96. Ullerstam, M., et al. (2002), The kinetics and mechanism of SO 2 oxidation by O3 on mineral dust, Phys. Chem. Chem. Phys., 4, 4694-4699, doi:10.1039/b203529b.
97. Usher, C. R., H. Al-Hosney, S. Carlos-Cuellar, and V. H. Grassian (2002), A laboratory study of the heterogeneous uptake and oxidation of sulfur dioxide on mineral dust particles, J. Geophys. Res., 107(D23), 4713, doi:10.1029/2002JD002051.
98. Vogt, R., et al. (1996), A mechanism for halogen release from sea-salt aerosol in the marine boundary layer, Nature, 383, 327-330, doi:10.1038/ 383327a0. (Pubitemid 26321759)
99. Vong, R. J., et al. (1997), Ionic and trace element composition of cloud water collected on the Olympic peninsula of Washington State, Atmos. Environ., 31(13), 1991-2001, doi:10.1016/S1352-2310(96)00337-8. (Pubitemid 27223209)
100. von Glasow, R., R. Sander, A. Bott, and P. J. Crutzen (2002), Modeling halogen chemistry in the marine boundary layer: 2. Interactions with sulfur and the cloud-covered MBL, J. Geophys. Res., 107(D17), 4323, doi:10.1029/ 2001JD000943. (Pubitemid 43206141)
101. Warneck, P. (2000), Chemistry of Natural Atmospheres, 2nd ed., Academic, San Diego, Calif.
102. Watanabe, K., et al. (2001), Chemical characteristics of cloud water over the Japan Sea and the northwestern Pacific Ocean near the central part of Japan: Airborne measurements, Atmos. Environ., 35, 645-655, doi:10.1016/S1352- 2310(00)00358-7.
103. Weber, R. J., G. Chen, D. D. Davis, R. L. Mauldin III, D. J. Tanner, F. L. Eisele, A. D. Clarke, D. C. Thornton, and A. R. Bandy (2001), Measurements of enhanced H2SO4 and 3-4 nm particles near a frontal cloud during the First Aerosol Characterization Experiment (ACE 1), J. Geophys. Res., 106(D20), 24,107-124,117.
104. Worsnop, D. R., M. S. Zahniser, C. E. Colb, J. A. Gardner, L. R. Watson, J. M. van Doren, J. T. Jayne, and P. Davidovits (1989), The temperature dependence of mass accommodation of SO2 and H2O 2 on aqueous surfaces, J. Phys. Chem., 93, 1159-1172, doi:10.1021/j100340a027.
105. Wyant, M. C., et al. (2010), The PreVOCA experiment: Modeling the lower troposphere in the southeast Pacific, Atmos. Chem. Phys., 10, 4757-4774, doi:10.5194/acp-10-4757-2010.
106. Yiin, B. S., and D. W. Margerum (1988), Kinetics of hydrolysis of the chlorosulfate ion, Inorg. Chem., 27, 1670-1672, doi:10.1021/ic00283a002.
107. Yuen, P.-F., et al. (1996), Paramerization of heterogeneous droplet chemistry for use in bulk cloud models, J. Appl. Meteorol., 35(5), 679-689, doi:10.1175/1520-0450(1996)035<0679:POHDCF>2.0.CO;2. (Pubitemid 126566934)
108. Zhang, M. H., et al. (2005), Comparing clouds and their seasonal variations in 10 atmospheric general circulation models with satellite measurements, J. Geophys. Res., 110, D15S02, doi:10.1029/2004JD005021. (Pubitemid 41388466)
109. Zhang, Q., et al. (2007), Ubiquity and dominance of oxygenated species in organic aerosols in anthropogenically influenced Northern Hemisphere midlatitudes, Geophys. Res. Lett., 34, L13801, doi:10.1029/2007GL029979. (Pubitemid 47399659)