The uptake of SO2 on Saharan dust: A flow tube study

Atmospheric Chemistry and Physics

Volumn 5, Issue 10, 2005, Pages 2679-2689

  Adams, J W ^a   Rodriguez, D ^b   Cox, R A ^a  

^a UNIVERSITY OF CAMBRIDGE   (United Kingdom)

^b UNIVERSITY OF CASTILLA LA MANCHA   (Spain)

Author keywords

[No Author keywords available]

Indexed keywords

ATMOSPHERIC CHEMISTRY; DUST; SULFUR DIOXIDE;

EID: 27844497023     PISSN: 16807316     EISSN: 16807324     Source Type: Journal    
DOI: 10.5194/acp-5-2679-2005     Document Type: Article

References (34)

1. Ammann, M., Pöschl, U., and Rudich, Y.: Effects of reversible adsorption and Langmuir-Hinshelwood surface reactions on gas uptake by atmospheric particles, Phys. Chem. Chem. Phys., 5, 351-356, 2003.
2. Andreae, M. O., Andreae, T. W., Meyerdierks, D., and Thiel, C.: Marine sulfur cycling and the atmospheric aerosol over the springtime North Atlantic, Chemosphere, 52, 1321-1343, 2003.
3. Aymoz, G., Jaffrezo, J.-L., Jacob, V., Colomb, A., and George, C.: Evolution of organic and inorganic components of aerosol during a Saharan dust episode observed in the French Alps, Atmos. Chem. Phys., 4, 2499-2512, 2004, SRef-ID: 1680-7324/acp/2004-4-2499.
4. Börensen, C.: Kinetische und mechanistische Untersuchung der heterogenen Reaktionen von Stickoxiden an Mineralstaub-Oberflächen, PhD thesis, University of Essen, Essen, Germany, 2000.
5. Brown, R. L.: Tubular flow reactors with first-order kinetics, J. Res. Nat. Bur. Standards, 83, 1-8, 1978.
6. Chameides, W. L. and Stelson, A. W.: Aqueous-phase chemical processes in deliquescent sea-salt aerosols - a mechanism that couples the atmospheric cycles of S and sea salt, J. Geophys. Res.-A, 97, 20 565-20 580, 1992.
7. 3 and HCl on ice in a coated wall flow system, Phys. Chem. Chem. Phys., 7, 3434-3442, 2005.
8. Curtis, A. R. and Sweetenham, W. P.: FACSIMILE, AERE Harwell, Publication R 12805, Computer Science and Systems Division, Harwell Laboratory, Oxfordshire, U.K., 1987.
9. Dentener, F. J., Carmichael, G. R., Zhang, Y., Lelieveld, J., and Crutzen, P. J.: Role of mineral aerosol as a reactive surface in the global troposphere, J. Geophys. Res.-A, 101, 22 869-22 889, 1996.
10. 2 emissions and downwind aerosol sulfate concentrations in the northeastern US, Atmos. Environ., 34, 1821-1832, 2000.
11. Formenti, P., Andreae, M. O., Lange, L., Roberts, G., Cafmeyer, J., Rajta, I., Maenhaut, W., Holben, B. N., Artaxo, P., and Lelieveld, J.: Saharan dust in Brazil and Suriname during the Large-Scale Biosphere-Atmosphere Experiment in Amazonia (LBA) - Cooperative LBA Regional Experiment (CLAIRE) in March 1998, J. Geophys. Res.-A, 106, 14 919-14 934, 2001.
12. Goodman, A. L., Li, P., Usher, C. R., and Grassian, V. H.: Heterogeneous uptake of sulfur dioxide on aluminum and magnesium oxide particles, J. Phys. Chem. A, 105, 6109-6120, 2001.
13. Hanisch, F. and Crowley, J. N.: Ozone decomposition on Saharan dust: an experimental investigation, Atmos. Chem. Phys., 3, 119-130, 2003, SRef-ID: 1680-7324/acp/2003-3-119.
14. 2 using chemical ionization mass spectrometry during the MINATROC field campaign 2000 on Monte Cimone, Atmos. Chem. Phys., 3, 417-436, 2003, SRef-ID: 1680-7324/aep/2003-3-417.
15. Hirschfelder, J. O., Curtiss, C. F., and Bird, R. B.: The kinetic theory of dilute gases, in: Molecular theory of gases and liquids, John Wiley and Sons, New York, 441-511, 1954.
16. Howard, C. J.: Kinetic measurements using flow tubes, J. Phys. Chem., 83, 3-9, 1979.
17. 2, Atmos. Environ., 12, 1663-1641, 1978.
18. Keene, W. C., Sander, R., Pszenny, A. A. P., Vogt, R., Crutzen, P. J., and Galloway, J. N.: Aerosol pH in the marine boundary layer: A review and model evaluation, J. Aerosol. Sci., 29, 339-356, 1998.
19. Keyser, L. F., Moore, S. B., and Leu, M.-T.: Surface reaction and pore diffusion in flow-tube reactors, J. Phys. Chem., 95, 5496-5502, 1991.
20. 2 from the marine boundary layer over the Atlantic Ocean: A case study on the kinetics of the heterogeneous S(IV) oxidation on marine aerosols, J. Geophys. Res.-A, 105, 14 413-14 422, 2000.
21. 2 conversion in nonurban tropospheric clouds, J. Geophys. Res.-A, 88, 721-732, 1983.
22. Mamane, Y. and Gottlieb, J.: Heterogeneous reactions of minerals with sulfur and nitrogen-oxides, J. Aerosol. Sci., 20, 303-311, 1989.
23. Penner, J. E., Andreae, M., Annegarn, H., et al.: Aerosols, their direct and indirect effects, in: Climate Change 2001: The Scientific Basis, Contribution of Working Group I to the Third Assessment Report of the Intergovernmental Panel on Climate Change, edited by: Houghton, J. T. et al., Cambridge Univ. Press, Cambridge, UK, and New York, NY, USA, 291-336, 2001.
24. Prospero, J. M.: Long-range transport of mineral dust in the global atmosphere: Impact of African dust on the environment of the southeastern United States, Proc. Natl. Acad. Sci. U.S.A., 96, 3396-3403, 1999.
25. Prospero, J. M., Ginoux, P., Torres, O., Nicholson, S. E., and Gill, T. E.: Environmental characterization of global sources of atmospheric soil dust identified with the Nimbus 7 Total Ozone Mapping Spectrometer (TOMS) absorbing aerosol product, Rev. Geophys., 40, art. no. 1002, 2002.
26. Song, C. H. and Carmichael, G. R.: The aging process of naturally emitted aerosol (sea-salt and mineral aerosol) during long range transport, Atmos. Environ., 33, 2203-2218, 1999.
27. 3 (s), J. Phys. Chem., 98, 9509-9517, 1994.
28. Tang, Y. H., Carmichael, G. R., Kurata, G., Uno, I., Weber, R. J., Song, C. H., Guttikunda, S. K., Woo, J. H., Streets, D. G., Wei, C., Clarke, A. D., Huebert, B., and Anderson, T. L.: Impacts of dust on regional tropospheric chemistry during the ACE-Asia experiment: A model study with observations, J. Geophys. Res.-A, 109, art. no. D19S21, 2004.
29. 3 on mineral dust, Phys. Chem. Chem. Phys., 4, 4694-4699, 2002.
30. 2 on mineral dust, Atmos. Chem. Phys., 3, 2043-2051, 2003, SRef-ID: 1680-7324/ acp/2003-3-2043.
31. Underwood, G. M., Li, P., Usher, C. R., and Grassian, V. H.: Determining accurate kinetic parameters of potentially important heterogeneous atmospheric reactions on solid particle surfaces with a Knudsen cell reactor, J. Phys. Chem. A, 104, 819-829, 2000.
32. Usher, C. R., Al-Hosney, H., Carlos-Cuellar, S., and Grassian, V. H.: A laboratory study of the heterogeneous uptake and oxidation of sulfur dioxide on mineral dust particles, J. Geophys. Res.-A, 107, art. no. 4713, 2002.
33. Usher, C. R., Michel, A. E., and Grassian, V. H.: Reactions on mineral dust, Chem. Rev., 103, 4883-4939, 2003.
34. VanCuren, R. A. and Cahill, T. A.: Asian aerosols in North America: Frequency and concentration of fine dust, J. Geophys. Res.-A, 107, art. no. 4804, 2002.