Deuterium-hydrogen exchange in olivine: Implications for point defects and electrical conductivity

Geochemistry, Geophysics, Geosystems

Volumn 13, Issue 3, 2012, Pages

  Du Frane, Wyatt L ^a,b   Tyburczy, James A ^a  

^a ARIZONA STATE UNIVERSITY   (United States)

^b LAWRENCE LIVERMORE NATIONAL LABORATORY   (United States)

Author keywords

diffusion; electrical conductivity; hydrogen; olivine; point defects; SIMS

Indexed keywords

ANISOTROPY; DEUTERIUM; DIFFUSION; ELECTRIC CONDUCTIVITY; ESTIMATION; EXPERIMENTAL MINERALOGY; KNOWLEDGE MANAGEMENT; OLIVINE; POINT DEFECTS; POLARONS; RADIOACTIVITY LOGGING; SECONDARY ION MASS SPECTROMETRY; THERMAL LOGGING;

ACTIVATION ENTHALPIES; CHEMICAL DIFFUSION; ELECTRICAL CONDUCTIVITY; HIGH ELECTRICAL CONDUCTIVITY; HIGHER TEMPERATURES; HYDROGEN DISTRIBUTION; LATTICE PREFERRED ORIENTATION; SELF-DIFFUSION; SMALL POLARONS;

HYDROGEN;

DEFECT; DEUTERIUM; DIFFUSION; ELECTRICAL CONDUCTIVITY; ION EXCHANGE; MASS SPECTROMETRY; OLIVINE; REDOX CONDITIONS;

EID: 84858627574     PISSN: None     EISSN: 15252027     Source Type: Journal    
DOI: 10.1029/2011GC003895     Document Type: Article

References (60)

1. Aubaud, C., A. C. Withers, M. M. Hirschmann, Y. Guan, L. A. Leshin, S. J. Mackwell, and D. R. Bell (2007), Intercalibration of FTIR and SIMS for hydrogen measurements in glasses and nominally anhydrous minerals, Am. Mineral., 92(5-6), 811-828, doi:10.2138/am.2007.2248. (Pubitemid 46851766)
2. Baba, K., A. D. Chave, R. L. Evans, G. Hirth, and R. L. Mackie (2006), Mantle dynamics beneath the East Pacific Rise at 17S°: Insights from the Mantle Electromagnetic and Tomography (MELT) experiment, J. Geophys. Res., 111, B02101, doi:10.1029/2004JB003598.
3. Bahr, K., and F. Simpson (2002), Electrical anisotropy below slow- and fast-moving plates: Paleoflow in the upper mantle-, Science, 295(5558), 1270-1272, doi:10.1126/science.1066161. (Pubitemid 34157614)
4. Bell, D. R., G. R. Rossman, J. Maldener, D. Endisch, and F. Rauch (2003), Hydroxide in olivine: A quantitative determination of the absolute amount and calibration of the IR spectrum, J. Geophys. Res., 108(B2), 2105, doi:10.1029/2001JB000679.
5. Bolfan-Casanova, N. (2005), Water in the Earth's mantle, Mineral. Mag., 69(3), 229-258, doi:10.1180/0026461056930248. (Pubitemid 41135810)
6. Carslaw, H. S., and J. C. Jaeger (1959), Conduction of Heat in Solids, Oxford Univ. Press, Oxford, U.K.
7. Constable, S. (2006), SEO3: A new model of olivine electrical conductivity, Geophys. J. Int., 166, 435-437, doi:10.1111/j.1365-246X.2006. 03041.x. (Pubitemid 43984379)
8. Constable, S., and J. J. Roberts (1997), Simultaneous modeling of thermopower and electrical conduction in olivine, Phys. Chem. Miner., 24(5), 319-325, doi:10.1007/s002690050044. (Pubitemid 127653140)
9. Constable, S., T. J. Shankland, and A. Duba (1992), The electrical conductivity of an olivine mantle, J. Geophys. Res., 97, 3397-3404, doi:10.1029/91JB02453.
10. Crank, J. (1975), The Mathematics of Diffusion, Oxford Univ. Press, Oxford, U.K.
11. Demouchy, S., and S. Mackwell (2003), Water diffusion in synthetic iron-free forsterite, Phys. Chem. Miner., 30(8), 486-494, doi:10.1007/s00269- 003-0342-2. (Pubitemid 37257041)
12. Demouchy, S., and S. Mackwell (2006), Mechanisms of hydrogen incorporation and diffusion in iron-bearing olivine, Phys. Chem. Miner., 33, 347-355, doi:10.1007/s00269-006- 0081-2. (Pubitemid 44143770)
13. Diedrich, T., T. G. Sharp, K. Leinenweber, and J. R. Holloway (2009), The effect of small amounts of H2O on olivine to ringwoodite transformation growth rates and implications for subduction of metastable olivine, Chem. Geol., 262(1-2), 87-99, doi:10.1016/j.chemgeo.2009.01.011.
14. Du Frane, W. L. (2005), Anisotropic electrical properties of olivine, M.S. thesis, Dep. of Geol. Sci., Ariz. State Univ., Tempe.
15. Du Frane, W. L. (2010), Hydrogen in the upper mantle: Diffusion and effects on olivine transformation kinetics, PhD dissertation, Sch. of Earth and Space Explor., Ariz. State Univ., Tempe.
16. Du Frane, W. L., J. J. Roberts, D. A. Toffelmier, and J. A. Tyburczy (2005), Anisotropy of electrical conductivity in dry olivine, Geophys. Res. Lett., 32, L24315, doi:10.1029/2005GL023879. (Pubitemid 43239946)
17. Evans, R. L., G. Hirth, K. Baba, D. Forsyth, A. Chave, and R. Mackie (2005), Geophysical evidence from the MELT area for compositional controls on oceanic plates, Nature, 437(7056), 249-252, doi:10.1038/nature04014. (Pubitemid 41294486)
18. Filloux, J. H. (1980), Magnetotelluric soundings over the northeast Pacific may reveal spatial dependence of depth and conductance of the asthenosphere, Earth Planet. Sci. Lett., 46(2), 244-252, doi:10.1016/0012- 821X(80)90010-2.
19. Hauri, E., J. H. Wang, J. E. Dixon, P. L. King, C. Mandeville, and S. Newman (2002), SIMS analysis of volatiles in silicate glasses 1. Calibration, matrix effects and comparisons with FTIR, Chem. Geol., 183, 99-114, doi:10.1016/S0009-2541 (01)00375-8. (Pubitemid 34268163)
20. Hirschmann, M. M., C. Aubaud, and A. C. Withers (2005), Storage capacity of H2O in nominally anhydrous minerals in the upper mantle, Earth Planet. Sci. Lett., 236(1-2), 167-181, doi:10.1016/j.epsl.2005.04.022. (Pubitemid 40984427)
21. Huang, X. G., Y. S. Xu, and S. I. Karato (2005), Water content in the transition zone from electrical conductivity of wadsleyite and ringwoodite, Nature, 434(7034), 746-749, doi:10.1038/nature03426. (Pubitemid 40558369)
22. Ichiki, M., M. Uyeshima, H. Utada, G. Z. Zhao, J. Tang, and M. Z. Ma (2001), Upper mantle conductivity structure of the back-arc region beneath northeastern China, Geophys. Res. Lett., 28(19), 3773-3776, doi:10.1029/ 2001GL012983. (Pubitemid 32997251)
23. Ingrin, J., and H. Skogby (2000), Hydrogen in nominally anhydrous upper-mantle minerals: Concentration levels and implications, Eur. J. Mineral., 12(3), 543-570. (Pubitemid 30343799)
24. Inoue, T., H. Yurimoto, and Y. Kudoh (1995), Hydrous modified spinel, Mg1.75SiH0.5O4: A new water reservoir in the mantle transition region, Geophys. Res. Lett., 22(2), 117-120, doi:10.1029/94GL02965.
25. Jacobsen, S. D., and S. van der Lee (Eds.) (2006), Earth's Deep Water Cycle, Geophys. Monogr. Ser., vol. 168, AGU, Washington, D.C.
26. Karato, S. (1990), The role of hydrogen in the electricalconductivity of the upper mantle, Nature, 347(6290), 272-273, doi:10.1038/347272a0. (Pubitemid 120015039)
27. Karato, S. (2006), Influence of hydrogen-related defects on the electrical conductivity and plastic deformation of mantle minerals: A critical review, in Earth's Deep Water Cycle, Geophys. Monogr. Ser., vol. 168, edited by S. D. Jacobsen and S. van der Lee, pp. 113-129, AGU, Washington, D. C., doi:10.1029/168GM09.
28. Keppler, H., and J. R. Smyth (2006), Water in Nominally Anhydrous Minerals, Rev. Mineral. Geochem., vol. 62, Mineral. Soc. of Am., Washington, D.C.
29. Koga, K., E. Hauri, M. Hirschmann, and D. Bell (2003), Hydrogen concentration analyses using SIMS and FTIR: Comparison and calibration for nominally anhydrous minerals, Geochem. Geophys. Geosyst., 4(2), 1019, doi:10.1029/2002GC000378.
30. Kohlstedt, D. L., and S. J. Mackwell (1998), Diffusion of hydrogen and intrinsic point defects in olivine, Z. Phys. Chem., 207, 147-162, doi:10.1524/zpch.1998.207.Part-1-2.147. (Pubitemid 128668829)
31. Kohlstedt, D. L., and S. J. Mackwell (1999), Solubility and diffusion of 'water' in silicate minerals, in Microscopic Properties and Processes in Minerals, edited by K. Wright and R. Catlow, pp. 539-559, Kluwer Acad., London.
32. Kohlstedt, D. L., H. Keppler, and D. C. Rubie (1996), Solubility of water in the a, b and g phases of (Mg,Fe)2SiO4, Contrib. Mineral. Petrol., 123(4), 345-357, doi:10.1007/s004100050161.
33. Leibecker, J., A. Gatzemeier, M. Honig, O. Kuras, and W. Soyer (2002), Evidence of electrical anisotropic structures in the lower crust and the upper mantle beneath the Rhenish Shield, Earth Planet. Sci. Lett., 202(2), 289-302, doi:10.1016/S0012-821X(02)00783-5. (Pubitemid 35225024)
34. Lizarralde, D., A. Chave, G. Hirth, and A. Schultz (1995), Northeastern Pacific mantle conductivity profile from long-period magnetotelluric sounding using Hawaii-to- California submarine cable data, J. Geophys. Res., 100(B9), 17,837-17,854, doi:10.1029/95JB01244.
35. Manthilake, M., T. Matsuzaki, T. Yoshino, S. Yamashita, E. Ito, and T. Katsura (2009), Electrical conductivity of wadsleyite as a function of temperature and water content, Phys. Earth Planet. Inter., 174(1-4), 10-18, doi:10.1016/j.pepi.2008.06.001.
36. Misener, D. J. (1973), Cationic diffusion in olivine to 1400°C and 35 kbar, in Geochemical Transport and Kinetics, Carnegie Inst. Wash. Publ., vol. 634, edited by A. W. Hofmann et al., pp. 117-129, Carnegie Inst., Washington, D.C.
37. Mosenfelder, J. L., N. I. Deligne, P. D. Asimow, and G. R. Rossman (2006), Hydrogen incorporation in olivine from 2-12 GPa, Am. Mineral., 91(2-3), 285-294, doi:10.2138/am.2006.1943. (Pubitemid 44056450)
38. Oldenburg, D. W. (1981), Conductivity structure of oceanic upper mantle beneath the Pacific Plate, Geophys. J. R. Astron. Soc., 65(2), 359-394.
39. Olsen, N. (1999), Long-period (30 days-1 year) electromagnetic sounding and the electrical conductivity of the lower mantle beneath Europe, Geophys. J. Int., 138(1), 179-187, doi:10.1046/j.1365-246x.1999.00854.x. (Pubitemid 29462074)
40. Paterson, M. S. (1982), The determination of hydroxyl by infrared-absorption in quartz, silicate-glasses and similar materials, Bull. Mineral., 105(1), 20-29.
41. Pitzer, K. S., and S. M. Sterner (1994), Equations of state valid continuously from zero to extreme pressures for H2O and CO 2, J. Chem. Phys., 101(4), 3111-3116, doi:10.1063/1.467624.
42. Poe, B. T., C. Romano, F. Nestola, and J. R. Smyth (2010), Electrical conductivity anisotropy of dry and hydrous olivine at 8 GPa, Phys. Earth Planet. Inter., 181(3-4), 103-111, doi:10.1016/j.pepi.2010.05.003.
43. Roberts, J. J., and A. G. Duba (1995), Transient electrical response of San Quintin dunite as a function of oxygen fugacity changes: Information about charge-carriers, Geophys. Res. Lett., 22(4), 453-456, doi:10.1029/94GL03347.
44. Romano, C., B. T. Poe, J. A. Tyburczy, and F. Nestola (2009), Electrical conductivity of hydrous wadsleyite, Eur. J. Mineral., 21(3), 615-622, doi:10.1127/0935-1221/2009/0021-1933.
45. Sato, H. (1986), High-temperature AC electrical-properties of olivine single-crystal with varying oxygen partialpressure- Implications for the point-defect chemistry, Phys. Earth Planet. Inter., 41(4), 269-282, doi:10.1016/0031- 9201(86)90006-3.
46. Schock, R. N., A. G. Duba, and T. J. Shankland (1989), Electrical conduction in olivine, J. Geophys. Res., 94(B5), 5829-5839, doi:10.1029/ JB094iB05p05829.
47. Shankland, T. J., and H. S. Waff (1977), Partial melting and electrical conductivity anomalies in the upper mantle, J. Geophys. Res., 82(33), 5409-5417, doi:10.1029/JB082i033p05409.
48. Shankland, T. J., R. J. Oconnell, and H. S. Waff (1981), Geophysical constraints on partial melt in the upper mantle, Rev. Geophys., 19(3), 394-406, doi:10.1029/RG019i003p00394. (Pubitemid 12504500)
49. Simpson, F. (2002), A comparison of electromagnetic distortion and resolution of upper mantle conductivities beneath continental Europe and the Mediterranean using islands as windows, Phys. Earth Planet. Inter., 129(1-2), 117-130, doi:10.1016/S0031-9201(01)00264-3. (Pubitemid 34134884)
50. Simpson, F., and A. Tommasi (2005), Hydrogen diffusivity and electrical anisotropy of a peridotite mantle, Geophys. J. Int., 160(3), 1092-1102, doi:10.1111/j.1365-246X.2005.02563.x. (Pubitemid 40440562)
51. Stalder, R., and H. Behrens (2006), D/H exchange in pure and Cr-doped enstatite: Implications for hydrogen diffusivity, Phys. Chem. Miner., 33(8-9), 601-611, doi:10.1007/s00269-006- 0112-z. (Pubitemid 44697370)
52. Tarits, P., S. Hautot, and F. Perrier (2004), Water in the mantle: Results from electrical conductivity beneath the French Alps, Geophys. Res. Lett., 31, L06612, doi:10.1029/2003GL019277.
53. Tenner, T. J., M. M. Hirschmann, A. C. Withers, and R. L. Hervig (2009), Hydrogen partitioning between nominally anhydrous upper mantle minerals and melt between 3 and 5 GPa and applications to hydrous peridotite partial melting, Chem. Geol., 262(1-2), 42-56, doi:10.1016/j.chemgeo. 2008.12.006.
54. Wang, D. J., M. Mookherjee, Y. S. Xu, and S. Karato (2006), The effect of water on the electrical conductivity of olivine, Nature, 443(7114), 977-980, doi:10.1038/nature05256. (Pubitemid 44646172)
55. Xu, Y. S., B. T. Poe, T. J. Shankland, and D. C. Rubie (1998), Electrical conductivity of olivine, wadsleyite, and ringwoodite under upper-mantle conditions, Science, 280(5368), 1415-1418, doi:10.1126/science.280.5368.1415. (Pubitemid 28264830)
56. Yoshino, T., T. Matsuzaki, S. Yamashita, and T. Katsura (2006), Hydrous olivine unable to account for conductivity anomaly at the top of the asthenosphere, Nature, 443(7114), 973-976, doi:10.1038/nature05223. (Pubitemid 44646171)
57. Yoshino, T., T. Matsuzaki, A. Shatskiy, and T. Katsura (2009), The effect of water on the electrical conductivity of olivine aggregates and its implications for the electrical structure of the upper mantle, Earth Planet. Sci. Lett., 288(1-2), 291-300, doi:10.1016/j.epsl.2009.09.032.
58. Yoshino, T., M. Laumonier, E. McIsaac, and T. Katsura (2010), Electrical conductivity of basaltic and carbonatite melt-bearing peridotites at high pressures: Implications for melt distribution and melt fraction in the upper mantle, Earth Planet. Sci. Lett., 295(3-4), 593-602, doi:10.1016/j.epsl. 2010.04.050.
59. Zhang, S. Q., and S. Karato (1995), Lattice preferred orientation of olivine aggregates deformed in simple shear, Nature, 375(6534), 774-777, doi:10.1038/375774a0.
60. Zhao, Y. H., S. B. Ginsberg, and D. L. Kohstedt (2004), Solubility of hydrogen in olivine: Dependence on temperature and iron content, Contrib. Mineral. Petrol., 147(2), 155-161, doi:10.1007/s00410-003-0524-4. (Pubitemid 38554525)