Mechanisms of hydrogen incorporation and diffusion in iron-bearing olivine

Physics and Chemistry of Minerals

Volumn 33, Issue 5, 2006, Pages 347-355

  Demouchy, Sylvie ^a,c   Mackwell, Stephen ^a,b  

^a UNIVERSITÄT BAYREUTH   (Germany)

^b LUNAR AND PLANETARY INSTITUTE   (United States)

^c UNIVERSITY OF MINNESOTA   (United States)

Author keywords

Diffusion; Hydrogen; Olivine; Point defects; Polarized FTIR spectroscopy

Indexed keywords

ACTIVATION ENERGY; CRYSTALLOGRAPHY; DIFFUSION; FOURIER TRANSFORM INFRARED SPECTROSCOPY; HYDROGEN; HYDROGENATION; POINT DEFECTS; SINGLE CRYSTALS;

CRYSTALLOGRAPHIC AXES; IRON-BEARING OLIVINE; XENOLITH;

OLIVINE;

CRYSTAL; CRYSTALLOGRAPHY; DIFFUSION; FTIR SPECTROSCOPY; HYDROGEN; OLIVINE; SOLUBILITY; WATER CONTENT; XENOLITH;

EID: 33746647824     PISSN: 03421791     EISSN: 14322021     Source Type: Journal    
DOI: 10.1007/s00269-006-0081-2     Document Type: Article

References (46)

1. Arndt NT, Ginibre C, Chauvel C, Albarède F, Cheadle M, Herzberg C, Jenner G, Lahaye Y (1998) Were Komatiites wet? Geology 26:739-742
2. Bai Q, Kohlstedt DL (1992) Substantial hydrogen solubility in olivine and implications for water storage in the mantle. Nature 357:672-674
3. Bai Q, Kohlstedt DL (1993) Effects of chemical environment on the solubility and incorporation mechanism for hydrogen in olivine. Phys Chem Miner 19:460-471
4. Bell D, Rossman G (1992), Water in Earth's mantle: The role of nominally anhydrous minerals. Science 255:1391-1397
5. Bell DR, Rossman GR, Maldener J, Endisch D and Rauch F (2003) Hydroxide in olivine: A quantitative determination of the absolute amount and calibration of the IR spectrum. J Geophys Res 108:B2, ECV 8-1/9, doi: 1029/2001JB000679
6. Berry A, Hermann J, O'Neill HSC, Foran GJ (2005) Fingerprinting the water site in mantle olivine. Geology 33:869-872
7. Bromiley GD, Keppler H (2004) An experimental investigation of hydroxyl solubility in jadeite and Na-rich clinopyroxenes. Contrib Mineral Petrol 147(2):189-200
8. Carslaw HS, Jaeger JC (1959) Conduction of head in solids, 2nd edn. Clarendon, Oxford, p 510
9. Chopra PN, Paterson MS (1984) The role of water in the deformation of dunite. J Geophys Res 89:7861-7876
10. Constable S, Duba A (2002) Diffusion and mobility of electrically conducting defects in olivine. Phys Chem Miner 29:446-454
11. Demouchy S, Mackwell SJ (2003) Water diffusion in synthetic iron-free forsterite. Phys Chem Miner 30:486-494
12. Demouchy S, Jacobsen SD, Gaillard F, Stern CR (2006) Rapid magma ascent recorded by water diffusion profiles in mantle olivine. Geology (in press)
13. Gaetani GA, Grove TL (1998) The influence of water on melting of mantle peridotite. Contrib Mineral Petrol 131:323-346
14. Hirth G, Evans RL, Chave AD (2000) Comparison of continental and oceanic mantle electrical conductivity: Is the Archean lithosphere dry? Geochem Geophys Geosys 1(12), doi:10.1029/2000GC000048
15. Hudson P, Baker DR, Toft PB (1994) A high-temperature assembly for 1.91 cm (3/4-in) piston-cylinder apparatus. Am Mineral 79:145-147
16. Ingrin J, Skogby H (2000) Hydrogen in nominally anhydrous upper-mantle minerals: Concentration levels and implications. Eur J Minerals 12:543-570
17. Karato SI (1990) The role of hydrogen diffusivity in the electrical conductivity of the upper mantle. Nature 347:272-273
18. Karato SI, Paterson MS, Fitz Gerald JD (1986) Rheology of synthetic olivine aggregates: Influence of grain size and water. J Geophys Res 91:8151-8176
19. Kohlstedt DL, Mackwell SJ (1998) Diffusion of hydrogen and intrinsic point defects in olivine. Z Phys Chem 207:147-162
20. Kohlstedt DL, Mackwell SJ (1999) Solubility and diffusion of "water" in silicate minerals. In: Catlow R (eds) Microscopic properties and processes in minerals. Kluwer, Netherlands, pp 539-559
21. 4. Contrib Mineral Petrol 123:345-357
22. Lemaire C, Kohn SC, Brooker R (2003) The effect of the silica activity on the incorporation mechanisms of water in synthetic forsterite: A polarized spectroscopic study. Contrib Mineral Petrol 147:48-57
23. Mackwell SJ, Kohlstedt DL (1990) Diffusion of hydrogen in olivine: implications for water in the mantle. J Geophys Res 95:5079-5088
24. Mackwell SJ, Kohlstedt DL, Paterson MS (1985) The role of water in the deformation of olivine single crystals. J Geophys Res 90:11,319-11,333
25. Mackwell SJ, Dimos D, Kohlstedt DL (1988) Transient creep of olivine: point-defect relaxation times. Philo Mag A 57:779-789
26. Matsyuk SS, Langer K (2004) Hydroxyl in olivines from mantles xenoliths in kimberlites of the Siberian platform. Contrib Mineral Petrol 147:413-437
27. 2 mantle metasomatism. J Petrol 42:721-729
28. Matveev S, Portnyagin M, Ballhaus C, Brooker R, Geiger CA (2004) FTIR spectrum of phenocryst olivine as an indicator of silica saturation in magmas. J Petrol v. Advance Acces J Petrol, 4th Dec 2004, doi:10.1093/ petrology/egh090
29. Mattioli GS, Wood BJ (1986) Upper mantle oxygen fugacity recorded by spinel lherzolites. Nature 322:626-628
30. McCammon CA (2005) The paradox of mantle redox. Science 308:807-807
31. Mei S, Kohlstedt DL (2000) Influence of water on plastic deformation of olivine aggregates 2 dislocation creep regime. J Geophys Res 105:21471-21481
32. Miller GH, Rossman GR, Harlow GE (1987) The natural occurrence of hydroxide in olivine. Phys Chem Miner 14:461-472
33. Mosenfelder JL, Deligne NI, Asimow PD, Rossman GR (2006) Hydrogen incorporation in olivine from 2-12 GPa. Am Mineral 91:285-294
34. 2O during crystallization of primitive arc magmas under uppermost mantle conditions and genesis of igneous pyroxenites:aN experimental study. Contrib Mineral Petrol 141:643-658
35. Nakamura A, Schmalzried H (1983) On the nonstoichiometry and point defects of olivine. Phys Chem Miner 10:27-37
36. 2+ interdiffusion in olivine (II). Ber Bunsen Phys Chem 88:140-145
37. O'Neill HStC, Wall VJ (1987) The olivine-orthopyroxene-spinel oxygen geobarometer, the nickel precipitation curve, and the oxygen fugacity of Earth's upper mantle. J Petrol 28:1169-1191
38. Paterson MS (1982) The determination of hydroxyl by infrared absorption in quartz, silicate glasses and similar materials. Bull Minéral 105:20-29
39. 2 precipitation in olivine: ATEM investigation of two dunites annealed at 300 MPa in hydrous conditions. Earth Planet Sci Lett 180:415-423
40. Regenauer-Lieb K, Kohl T (2003) Water solubility and diffusivity in olivine: Its role in planetary tectonics. Mineral Mag 67(4):697-715
41. Regenauer-Lieb K, Yuen D, Branlund J (2001) The initiation of subduction: Criticaly by addition of water? Science 294:578-580
42. Sato H (1986) High temperature ac electrical properties of olivine single crystal with varying oxygen partial pressure: Implications for the point defect chemistry. Earth Planet Inter 41:269-282
43. 4 Mat Sci Forum 239-241:399-402
44. 4, 0.2 < x < 1.0. Phys Chem Miner 29:680-694
45. Wanamaker BJ (1994) Point defect diffusivities in San Carlos olivine derived from reequilibration of electrical conductivity following changes in oxygen fugacity. Geophys Res Lett 21:21-24
46. Zhao YH, Ginsberg SB, Kohlstedt DL (2004) Solubility of hydrogen in olivine: Dependence on temperature and iron content. Contrib Mineral Petrol 147:155-161