Hydroxide in olivine: A quantitative determination of the absolute amount and calibration of the IR spectrum

Journal of Geophysical Research: Solid Earth

Volumn 108, Issue 2, 2003, Pages

  Bell, David R ^a   Rossman, George R ^a   Maldener, Joachim ^b   Endisch, Denis ^b   Rauch, Friedel ^b  

^a CALIFORNIA INSTITUTE OF TECHNOLOGY   (United States)

^b GOETHE UNIVERSITY   (Germany)

Author keywords

Defect; Hydrogen; Infrared; Mantle; Spectroscopy; Water

Indexed keywords

INFRARED SPECTROSCOPY; MANTLE; OLIVINE; WATER;

EID: 0037593539     PISSN: 21699313     EISSN: 21699356     Source Type: Journal    
DOI: None     Document Type: Article

References (31)

1. Bai, Q., and D. L. Kohlstedt, Substantial hydrogen solubility in olivine and implications for water storage in the mantle, Nature, 357, 672-674, 1992.
2. Bai, Q., and D. L. Kohlstedt, Effects of chemical environment and solubility and incorporation mechanism for hydrogen in olivine, Phys. Chem. Miner., 19, 460-471, 1993.
3. Bell, D. R., and G. R. Rossman, Water in the Earth's mantle: The role of nominally anhydrous minerals, Science, 225, 1391-1397, 1992.
4. Bell, D. R., P. D. Ihinger, and G. R. Rossman, Quantitative analysis of trace OH in garnet and pyroxenes, Am. Mineral., 80, 465-474, 1995.
5. Endisch, D., H. Sturm, and F. Rauch, Nuclear reaction analysis of hydrogen at levels below 10 at. ppm, Nucl. Instrum. Methods Phys. Res., Sect. B, 84, 380-392, 1994.
6. Fisher, G. W., and L. G. Medaris Jr., Cell dimensions and X-ray determinative curve for synthetic Mg-Fe olivines, Am. Mineral., 54, 741-753, 1969.
7. Freund, F., Volume instabilities in the mantle as a possible source for kimberlite formation, in Developments in Petrology 11A. Kimberlites I. Kimberlites and Related Rocks, edited by J. Kornprobst, pp. 405-415, Elsevier Sci., New York, 1984.
8. Freund, F., and G. Oberheuser, Water dissolved in olivine: A single-crystal infrared study, J. Geophys. Res., 91, 745-761, 1986.
9. Hammer, V. M. F., A. Beran, D. Endisch, and F. Rauch, OH concentrations in natural titanates determined by FTIR spectroscopy and nuclear reaction analysis, Eur. J. Mineral., 8, 281-288, 1996.
10. Jamtveit, B., R. Brooker, K. Brooks, L. M. Larsen, and T. Pedersen, The water content of olivines from the North Atlantic Volcanic Province, Earth Planet. Sci. Lett., 186, 401-415, 2001.
11. Keppler, H., and M. Rauch, Water solubility in nominally anhydrous minerals measured by FTIR and IHMAS NMR: The effect of sample preparation, Phys. Chem. Miner., 27, 371-376, 2000.
12. Koga, K., E. Hauri, M. Hirschmann, and D. Bell, Hydrogen concentration analyses using SIMS and FTIR: Comparison and calibration for nominally anhydrous minerals, Geochem. Geophys. Geosyst., 4, doi:10.1029/ 2002GC000378, in press, 2003.
13. 4, Contrib. Mineral. Petrol., 123, 345-357, 1996.
14. 1H MAS NMR, Am. Mineral., 81, 1523-1526, 1996.
15. Kurosawa, M., H. Yurimoto, K. Matsumoto, and S. Sueno, Hydrogen analysis of mantle olivine by secondary ion mass spectrometry, in High Pressure Research: Applications to Earth and Planetary Sciences, edited by Y. Syono and M. Manghnani, pp. 283-287, Terra Sci., Tokyo/AGU. Washington, D. C., 1992.
16. Kurosawa, M., H. Yurimoto, and S. Sueno, Water in Earth's mantle: Hydrogen analysis of mantle olivine, pyroxenes and garnet using the SIMS, Proc. Lunar Planet. Sci. Conf., 24th, Abstract, 839-840, 1993.
17. Kurosawa, M., H. Yurimoto, and S. Sueno, Patterns in the hydrogen and trace element compositions of mantle olivines. Phys. Chem. Miner., 24, 385-395, 1997.
18. 15N Hydrogen profiling: Scientific applications, Nucl. Instrum. Methods Phys. Res., Sect. B., 149, 1-8, 1978.
19. Libowitzky, E., and A. Beran, OH defects in forsterite, Phys. Chem. Miner., 22, 387-392, 1995.
20. Libowitzky, E., and G. R. Rossman, Principles of quantitative absorbance measurements in anisotropic crystals. Phys. Chem. Miner., 23, 319-327, 1996.
21. Libowitzky, E., and G. R. Rossman, An IR absorption calibration for water in minerals, Am. Mineral., 82, 1111-1115, 1997.
22. Mackwell, S. J., and D. L. Kohlstedt, Diffusion of hydrogen in olivine: implications for water in the mantle, J. Geophys. Res., 95, 5079-5088, 1990.
23. Mackwell, S. J., D. L. Kohlstedt, and M. S. Paterson, The role of water in the deformation of olivine single crystals, J. Geophys. Res., 90, 11,319-11,333, 1985.
24. Maldener, J., and F. Rauch, High energy ion-beam analysis in combination with keV sputtering, in Application of Accelerators in Research and Industry, edited by J. L. Duggan and I. L. Morgan, pp. 689-692, AIP Press, New York, 1997.
25. Maldener, J., F. Rauch, M. Gavranic, and A. Beran, OH absorption coefficients of rutile and cassiterite deduced from nuclear reaction analysis and FTIR spectroscopy. Mineral. Petrol., 71, 21-29, 2001.
26. 2 mantle metasomatism, J. Petrol., 42, 721-729, 2001.
27. Miller, G. H., G. R. Rossman, and G. E. Harlow, The natural occurrence of hydroxide in olivine, Phys. Chem. Miner., 14, 461-472, 1987.
28. Paterson, M. S., The determination of hydroxyl by infrared absorption in quartz, silicate glasses and similar materials, Bull. Mineral., 105, 20-29, 1982.
29. Rossman, G. R., and R. D. Aines, The hydrous component in garnets: grossular-hydrogrossular, Am. Mineral., 76, 1153-1164, 1991.
30. Sweeney, R. J., V. M. Prozesky, and K. A. Springhorn, Use of the ERDA microbeam technique for the quantitative determination of hydrogen in materials and hydrogen partitioning between olivine and melt at high pressures, Geochim. Cosmochim. Acta, 61, 101-113, 1997.
31. Sweeney, R. J., J. Konzett, and V. M. Prozesky, The determination of hydrogen in peridotitic minerals by nuclear methods, paper presented at Ext. Abstr., 7th Int. Kimberlite Conf., Cape Town, 874-876, 1998.