Intensification of epoxidation of soybean oil using sonochemical reactors

Chemical Engineering and Processing: Process Intensification

Volumn 54, Issue , 2012, Pages 22-28

  Chavan, Vivek P ^a   Patwardhan, Anand V ^a   Gogate, Parag R ^a  

^a INSTITUTE OF CHEMICAL TECHNOLOGY   (India)

Author keywords

Epoxidation; Hydrogen peroxide; Phase transfer catalyst; Sonochemical reactors; Soybean oil

Indexed keywords

COMMERCIAL EXPLOITATION; CONVENTIONAL METHODS; EPOXIDATION REACTIONS; EXTERNAL TEMPERATURE; IODINE VALUE; OPTIMISED CONDITIONS; OXIRANES; PHASE TRANSFER CATALYST; PHASE TRANSFER CATALYSTS; REACTOR CONFIGURATION; SONOCHEMICAL; SONOCHEMICAL REACTORS; SOYBEAN OIL; SUBSTANTIAL REDUCTION; TETRA-N-BUTYL AMMONIUM BROMIDES; ULTRASONIC BATH; ULTRASONIC HORN;

AMMONIUM COMPOUNDS; BROMINE COMPOUNDS; COOLING SYSTEMS; EPOXIDATION; HYDROGEN PEROXIDE; IODINE; SONOCHEMISTRY; ULTRASONICS; VEGETABLE OILS;

OILSEEDS;

EID: 84858343506     PISSN: 02552701     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.cep.2012.01.006     Document Type: Article

References (33)

1. Mungroo R., Pradhan N.C., Goud V.V., Dalai A.K. Epoxidation of canola oil with hydrogen peroxide catalyzed by acidic ion exchange resin. J. Am. Oil Chem. Soc. 2008, 85:887-896.
2. Hessel V., Cortese B., de Croon M.H.J.M. Novel process windows-concept, proposition and evaluation methodology, and intensified superheated processing. Chem. Eng. Sci. 2011, 66:1426-1448.
3. Murphy D.J. Biotechnology and the improvement of oil crops-genes, dreams and realities. Phytochem. Rev. 2002, 1:67-77.
4. Piazza G.J., Foglia T.A. Preparation of fatty amide polyols via epoxidation of vegetable oil amides by oat seed peroxygenase. J. Am. Oil Chem. Soc. 2005, 82:481-485.
5. Gurbanov M.S., Chalabiev C.A., Mamedov B.A., Efendiev A.A. Epoxidation of soybean oil in the course of cooxidation with hydrogen peroxide in the presence of propanoic acid and chlorinated ku-2×8 cation exchanger. Russ. J. Appl. Chem. 2005, 78:1707-1711.
6. Meyer P., Techaphattana N., Manundawee S., Sangkeaw S., Junlakan W., Tongurai C. Epoxidation of soybean oil and jatropha oil. Thammasat Int. J. Sci. Technol. 2008, 13:1-5.
7. Yang L., Dai H., Yi A., Lin B., Li G. Structure and properties of partially epoxidized soybean oil. J. Therm. Anal. Calorim. 2008, 93:875-879.
8. Fariasa M., Martinelli M., Bottegab D.P. Epoxidation of soybean oil using a homogeneous catalytic system based on a molybdenum (VI) complex. Appl. Catal. A: Gen. 2010, 384:213-219.
9. Dinda S., Patwardhan A.V., Goud V.V., Pradhan N.C. Epoxidation of cottonseed oil by aqueous hydrogen peroxide catalysed by liquid inorganic acids. Bioresour. Technol. 2008, 99:3737-3744.
10. Zaher F.A., El-Mallah M.H., El-Hefnawy M.M. Kinetics of oxirane cleavages in epoxidised soybean oil. J. Am. Oil Chem. Soc. 1989, 66:698-700.
11. Carlson K.D., Chang S.P. Chemical epoxidation of natural unsaturated epoxy seed oil from Vernonia galamensis and a look at epoxy oil markets. J. Am. Oil Chem. Soc. 1985, 62:934-939.
12. Hang X., Yang H. Model for a cascade continuous epoxidation process. J. Am. Oil Chem. Soc. 1999, 76:89-92.
13. Guenter S., Reith R., Robottom K.T. Ullmann's Encyclopedia of Industrial Chemistry 2003, vol. 12. John Wiley & Sons, pp. 269-284. 6th ed.
14. Sheldon R.A., Dakka J. Heterogeneous catalytic oxidations in the manufacture of fine chemicals. Catal. Today 1994, 19:215-246.
15. Gogate P.R. Cavitational reactors for process intensification of chemical processing applications: a critical review. Chem. Eng. Process. 2008, 47:515-527.
16. Thompson L.H., Doraiswamy L.K. Sonochemistry: science and engineering. Ind. Eng. Chem. Res. 1999, 38:1215-1249.
17. Cravatto G., Cintas P. Power ultrasound in organic synthesis: moving cavitational chemistry from academia to innovative and large-scale applications. Chem. Soc. Rev. 2006, 35:180-196.
18. Mason T.J. Ultrasound in synthetic organic chemistry. Chem. Soc. Rev. 1997, 26:443-451.
19. Swern D. Organic peroxides. Chem. Rev. 1949, 45:1-521.
20. Paquot C. Standard Methods for the Analysis of Oils, Fats and Derivatives Part 1 1979, Pergamon, Oxford, United Kingdom, pp. 66-70. 6th ed.
21. May C.A. Epoxy Resins: Chemistry and Technology 1973, Marcel Dekker, New York, pp. 672-673.
22. Petrovic S., Zlatanic A., Lava C.C., Sinadinovic-Fiser S. Epoxidation of soybean oil in toluene with peroxyacetic and peroxyformic acids-kinetics and side reactions. Eur. J. Lipid Sci. Technol. 2002, 104:293-299.
23. Goud V.V., Patwardhan A.V., Dinda S., Pradhan N.C. Kinetics of epoxidation of jatropha oil with peroxyacetic and peroxyformic acid catalysed by acidic ion exchange resin. Chem. Eng. Sci. 2007, 62:4065-4076.
24. Sutkar V.S., Gogate P.R. Design aspects of sonochemical reactors: techniques for understanding cavitational activity distribution and effect of operating parameters. Chem. Eng. J. 2009, 155:26-36.
25. Ratoarinoro N., Wilhelm A.M., Berlan J., Delmas H. Effects of ultrasound emitter type and power on a heterogeneous reaction. Chem. Eng. J. 1992, 50:27-31.
26. Toukoniitty B., Mikkola J.P., Murzin D.Y., Salmi T. Utilization of electromagnetic and acoustic irradiation in enhancing heterogeneous catalytic reactions. Appl. Catal. A: Gen. 2005, 279:1-22.
27. Gogate P.R., Wilhelm A.M., Pandit A.B. Some aspects of the design of sonochemical reactors. Ultrason. Sonochem. 2003, 10:325-330.
28. Hingu S.M., Gogate P.R., Rathod V.K. Synthesis of biodiesel from waste cooking oil using sonochemical reactors. Ultrason. Sonochem. 2010, 17:827-832.
29. Rooze J., Rebrov E.V., Schouten J.C., Keurentjes J.T.F. Effect of resonance frequency, power input, and saturation gas type on the oxidation efficiency of an ultrasound horn. Ultrason. Sonochem. 2011, 18:209-215.
30. Yang H.M., Chiu C.C. Ultrasound-assisted phase-transfer catalysis: benzoylation of sodium 4-acetylphenoxide by dual-site phase-transfer catalyst in a tri-liquid system. Ultrason. Sonochem. 2011, 18:363-369.
31. Wang M.L., Rajendran V. Ultrasound assisted phase transfer catalytic epoxidation of 1,7-octadiene-a kinetic study. Ultrason. Sonochem. 2007, 14:46-54.
32. Goud V.V., Patwardhan A.V., Pradhan N.C. Studies on the epoxidation of mahua oil (Madhumica indica) by hydrogen peroxide. Bioresour. Technol. 2006, 97:1365-1371.
33. P. Tadkar, M. Chem. Eng. Thesis, Institute of Chemical Technology, Mumbai, 2011.