Epoxidation of cottonseed oil by aqueous hydrogen peroxide catalysed by liquid inorganic acids

Bioresource Technology

Volumn 99, Issue 9, 2008, Pages 3737-3744

  Dinda, Srikanta ^a   Patwardhan, Anand V ^a   Goud, Vaibhav V ^a   Pradhan, Narayan C ^a  

^a INDIAN INSTITUTE OF TECHNOLOGY   (India)

Author keywords

Cottonseed oil; Hydrogen peroxide; In situ epoxidation; Kinetics; Liquid inorganic acids

Indexed keywords

ACETIC ACID; COTTONSEED OIL; EPOXIDATION; RATE CONSTANTS; REACTION KINETICS;

IN SITU EPOXIDATION; LIQUID INORGANIC ACIDS;

HYDROGEN PEROXIDE;

ACETIC ACID; COTTON SEED OIL; ETHYLENE OXIDE; FORMIC ACID; HYDROCHLORIC ACID; HYDROGEN PEROXIDE; INORGANIC ACID; NITRIC ACID; PERACETIC ACID; PHOSPHORIC ACID; SULFURIC ACID; EPOXIDE; ETHYLENE; ETHYLENE DERIVATIVE; FORMIC ACID DERIVATIVE; GLYCOL; OXYGEN;

ACETIC ACID; COTTONSEED OIL; EPOXIDATION; HYDROGEN PEROXIDE; RATE CONSTANTS; REACTION KINETICS;

ACETIC ACID; ACTIVATION ENERGY; CATALYSIS; COTTON; ENTHALPY; ENTROPY; HYDROGEN PEROXIDE; REACTION KINETICS; SULFURIC ACID; THERMODYNAMICS; VEGETABLE OIL;

AQUEOUS SOLUTION; ARTICLE; CATALYSIS; ENERGY; ENTHALPY; ENTROPY; EPOXIDATION; LIQUID; OXIDATION KINETICS; PRIORITY JOURNAL; CHEMISTRY; DRUG EFFECT; KINETICS; TEMPERATURE; THERMODYNAMICS; TIME;

MICROPUS;

ACETIC ACID; ACIDS, NONCARBOXYLIC; CATALYSIS; COTTONSEED OIL; EPOXY COMPOUNDS; ETHYLENE OXIDE; ETHYLENES; FORMIC ACIDS; GLYCOLS; HYDROGEN PEROXIDE; KINETICS; OXYGEN; SULFURIC ACIDS; TEMPERATURE; THERMODYNAMICS; TIME FACTORS;

EID: 43849092155     PISSN: 09608524     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.biortech.2007.07.015     Document Type: Article

References (22)

1. Biermann U., Friedt W., Lang S., Luhs W., Machmuller G., Metzger J.O., Klaas M.R., Schafer H.J., and Schneider M.P. New syntheses with oils and fats as renewable raw materials for the chemical industry. Angew. Chem. Int. Ed. 39 (2000) 2206-2224
2. Chakrabarty M.M. Chemistry and Technology of Oils and Fats (2003), Allied Publishers, New Delhi pp. 151-152
3. Gan L.H., and Ng S.C. Kinetic studies of the performic acid epoxidation of natural rubber latex stabilized by cationic surfactant. Eur. Polym. J. 22 (1986) 573-576
4. Gan L.H., Goh S.H., and Ooi K.S. Kinetic studies of epoxidation and oxirane cleavage of palm olein methyl esters. J. Am. Oil Chem. Soc. 69 (1992) 347-351
5. Gan L.H., Ooi K.S., Gan L.M., and Goh S.H. Effect of epoxidation on the thermal oxidative stabilities of esters of fatty acids derived from palm olein. J. Am. Oil Chem. Soc. 72 (1995) 439-442
6. Goud V.V., Patwardhan A.V., and Pradhan N.C. Studies on the epoxidation of mahua oil (Madhumica Indica) by hydrogen peroxide. Bioresour. Technol. 97 (2006) 1365-1371
7. 2. J. Am. Oil Chem. Soc. 83 (2006) 635-640
8. Guenter S., Rieth R., and Rowbottom K.T. Ullmann's Encyclopedia of Industrial Chemistry. 6th ed. vol. 12 (2003), John Wiley and Sons pp. 269-284
9. Janković M., and Fišer S.S. Prediction of the chemical equilibrium constant for peracetic acid formation by hydrogen peroxide. J. Am. Oil Chem. Soc. 82 (2005) 301-303
10. Kapoor K.L. A Textbook of Physical Chemistry vol. 4 (1985), Macmillan India Limited, New Delhi Chapter 6
11. Klaas M.R., and Warwel S. Complete and partial epoxidation of plant oils by lipase-catalysed perhydrolysis. Ind. Crops Prod. 9 (1999) 125-132
12. May C.A. Epoxy Resins: Chemistry and Technology (1973), Marcel Dekker, New York pp. 672-673
13. Okieimen F.E., Bakare O.I., and Okieimen C.O. Studies on the epoxidation of rubber seed oil. Ind. Crops Prod. 15 (2002) 139-144
14. Pahari S. Physical Chemistry. first ed. (1990), New Central Book Agency, Kolkata p. 569
15. Paquot C. Standard Methods for the Analysis of Oils, Fats and Derivatives Part-1. fifth ed. (1979), Pergamon Press, Germany pp. 52-93
16. Rios L.A., Weckes P., Schuster H., and Hoelderich W.F. Mesoporous and amorphous Ti-silicas on the epoxidation of vegetables oils. J. Catal. 232 (2005) 19-26
17. Sharpless K.B., Woodard S.S., and Finn M.G. On the mechanism of titanium tartrate catalyzed asymmetric epoxidation. Pure Appl. Chem. 55 (1983) 1823-1836
18. Sheldon R.A., and Dakka J. Heterogeneous catalytic oxidations in the manufacture of fine chemicals. Catal. Today 19 (1994) 215-246
19. Siggia S., and Hanna J.G. Quantitative Organic Analysis via Functional Groups (1979), Wiley Interscience, New York pp. 394-398
20. Srivastava A., and Prasad R. Triglycerides-based diesel fuels. Renew. Sustain. Energy Rev. 4 (2000) 111-133
21. Wallace J.C. Encyclopedia of Chemical Technology. third ed. vol. 9 (1978), John Wiley and Sons, New York
22. Weiss F.T. Determination of Organic Compounds: Methods and Procedures (1970), Wiley Interscience, New York pp. 34-44