Molecular structure of a hydridoniobocene complex [Nb(η 5-C5H4SiMe3)2(H) 3] and its use as catalyst for the ring-opening polymerization of cyclic esters

European Journal of Inorganic Chemistry

Volumn , Issue 7, 2012, Pages 1139-1144

  Alonso Moreno, Carlos ^a   Antiñolo, Antonio ^a   García Martínez, Joaquín C ^a   García Yuste, Santiago ^a   Lõpez Solera, Isabel ^a   Otero, Antonio ^a   Pérez Flores, Juan C ^a   Tercero Morales, Maria T ^a  

^a UNIVERSITY OF CASTILLA LA MANCHA   (Spain)

Author keywords

Hydride ligands; Lactones; Metallocenes; Niobium; Ring opening polymerization

Indexed keywords

ESTERS; HYDRIDES; NIOBIUM COMPOUNDS; POLYDISPERSITY; RING OPENING POLYMERIZATION; TRANSITION METALS; X RAY DIFFRACTION;

CAPROLACTONE; CLASSIFIEDS; CYCLIC ESTERS; HYDRIDE LIGANDS; LACTONE; MOLECULAR WEIGHT POLYMERS; RING-OPENING POLYMERIZATION; SINGLE COMPONENTS; X- RAY DIFFRACTIONS; ]+ CATALYST;

ORGANOMETALLICS;

EID: 84857324633     PISSN: 14341948     EISSN: 10990682     Source Type: Journal    
DOI: 10.1002/ejic.201101263     Document Type: Article

References (43)

1. M. Peruzzini, R. Poli, Recent Advances in Hydride Chemistry, Elsevier, Amsterdam, 2001, p. 4.
2. A. Antiñolo, B. Chaudret, G. Commenges, M. Fajardo, F. Jalõn, R. H. Morris, A. Otero, C. T. Schweitzer, J. Chem. Soc., Chem. Commun. 1988, 1210-1212.
3. S. Camanyes, F. Maseras, M. Moreno, A. Lledõs, J. M. Lluch, J. Bertrán, J. Am. Chem. Soc. 1996, 118, 4617-4621.
4. A. Antiñolo, F. Carrillo-Hermosilla, M. Fajardo, J. Fernandez-Baeza, S. García-Yuste, A. Otero, S. Camanyes, F. Maseras, M. Moreno, A. Lledõs, J. M. Lluch, J. Am. Chem. Soc. 1997, 119, 6107-6114.
5. A. Antiñolo, F. Carrillo-Hermosilla, M. Fajardo, J. Fernandez-Baeza, S. García-Yuste, A. Otero, Coord. Chem. Rev. 1999, 193-195, 43-72.
6. A. Antiñolo, F. Carrillo, S. García-Yuste, A. Otero, Organometallics 1994, 13, 2761-2766.
7. A. Antiñolo, F. Carrillo-Hermosilla, B. Chaudret, M. Fajardo, J. Fernandez-Baeza, M. Lanfranchi, H. H. Limbach, M. Maurer, A. Otero, M. A. Pellinghelli, Inorg. Chem. 1996, 35, 7873-7881.
8. A. Antiñolo, F. Carrillo-Hermosilla, J. Fernandez-Baeza, S. García-Yuste, A. Otero, A. M. Rodriguez, J. Sánchez-Prada, E. Villaseñor, M. Moreno, J. M. Lluch, A. Lledõs, Organometallics 2000, 19, 3654-3663.
9. A. Antiñolo, A. Otero, A. Lara-Sanchez, Comprehensive Organometallic Chemistry III, Elsevier, Oxford, UK, 2007, vol. 5, p. 61.
10. T. Keii, Y. Doi, Shiyokubai Jpn. 1979, 21, 32.
11. S. W. Shalaby, K. J. L. Burg, Absorbable and Biodegradable Polymers (Advances in Polymeric Materials), CRC Press, Boca Raton, 2003.
12. A. J. Domb, D. M. Wiseman, Handbook of Biodegradable Polymers, CRC Press, Boca Raton, 1998.
13. L. S. Nair, C. T. Laurencin, Prog. Polym. Sci. 2007, 32, 762-798.
14. C. Jérôme, P. Lecomte, Adv. Drug Delivery Rev. 2008, 60, 1056-1076.
15. C. L. Wanamaker, M. J. Bluemle, L. M. Pitet, L. E. O'Leary, W. B. Tolman, M. A. Hillmyer, Biomacromolecules 2009, 10, 2904-2911.
16. D. Bourissou, S. Moebs-Sanchez, B. Martin-Vaca, C. R. Chim. 2007, 10, 775-794.
17. S. F. Williams, D. P. Martin, Biopolymers (Eds.:, A. Steinbüchel, Y. Doi), Wiley-VCH, Weinheim, 2002, vol. 4, pp. 91-127.
18. M. K. Kiesewetter, E. J. Shin, J. L. Hedrick, R. M. Waymouth, Macromolecules 2010, 43, 2093-2107.
19. C. M. Thomas, Chem. Soc. Rev. 2010, 39, 165-173.
20. P. Dubois, O. Coulembier, J.-M. Raquez, Handbook of Ring-Opening Polymerization, Wiley-VCH, Weinheim, 2009.
21. A. P. Dove, Chem. Commun. 2008, 6446-6470.
22. J. Wu, T.-L. Yu, C.-T. Chen, C.-C. Lin, Coord. Chem. Rev. 2006, 250, 602-626.
23. O. Dechy-Cabaret, B. Martin-Vaca, D. Bourissou, Chem. Rev. 2004, 104, 6147-6176.
24. C. A. Wheaton, P. G. Hayes, B. J. Ireland, Dalton Trans. 2009, 4832-4846.
25. R. D. Wilson, T. F. Koetzle, D. W. Hart, A. Kwick, D. L. Tipton, R. Bau, J. Am. Chem. Soc. 1977, 99, 1775-1781.
26. S. Camanyes, F. Maseras, M. Moreno, A. Lledõs, J. M. Lluch, J. Bertrán, Chem. Eur. J. 1999, 5, 1166-1171.
27. G. J. Kubas, Chem. Rev. 2007, 107, 4152-4205.
28. A. Otero, A. Lara-Sanchez, J. Fernandez-Baeza, C. Alonso-Moreno, M. I. Marquez-Segovia, J. A. Castro-Osma, L. F. Sanchez-Barba Merlo, A. M. Rodriguez, J. C. García-Martínez, Organometallics 2011, 30, 1507-1522.
29. A. Otero, J. Fernandez-Baeza, A. Lara-Sanchez, C. Alonso-Moreno, M. I. Marquez-Segovia, L. F. Sanchez-Barba Merlo, A. M. Rodriguez, Angew. Chem. 2009, 121, 2210-2213;
30. Angew. Chem. Int. Ed. 2009, 48, 2176-2179.
31. L. F Sanchez-Barba Merlo, A. Garces Osado, J. Fernandez-Baeza, A. Otero, C. Alonso-Moreno, A. Lara-Sanchez, A. M. Rodriguez, Organometallics 2011, 30, 2775-2789.
32. I. Barakat, P. Dubois, R. Jérôme, P. Teyssié, J. Polym. Sci., Part A: Polym. Sci. 1993, 31, 505-514.
33. B. Chamberlain, M. Cheng, D. Moore, T. Ovitt, E. Lobkovsky, G. W. Coates, J. Am. Chem. Soc. 2001, 123, 3229-3238.
34. C. Alonso-Moreno, A. Garces Osado, L. F. Sanchez-Barba Merlo, J. Fernandez-Baeza, A. Otero, A. Lara-Sanchez, A. Antiñolo, L. Broomfield, I. Lopez-Solera, Organometallics 2008, 27, 1310-1321.
35. T. R. Jensen, C. P. Schaller, M. A. Hillmyer, W. B. Tolman, J. Organomet. Chem. 2005, 690, 5881-5891.
36. M. H. Chisholm, J. C. Huffman, K. Phomphrai, J. Chem. Soc., Dalton Trans. 2001, 222-224.
37. M. Cheng, A. B. Attygalle, E. B. Lobkovsky, G. W. Coates, J. Am. Chem. Soc. 1999, 121, 11583-11584.
38. D. Garlotta, J. Polym. Environ. 2001, 9, 63-84.
39. A.-C. Albertsson, I. K. Varma, Biomacromolecules 2003, 4, 1466-1486.
40. N. Barros, P. Mountford, S. M. Guillaume, L. Maron, Chem. Eur. J. 2008, 14, 5507-5518.
41. N. K. Szymczak, D. R. Tyler, Coord. Chem. Rev. 2008, 252, 212-230.
42. G. M. Sheldrick, Acta Crystallogr., Sect. A 1990, 46, 467-473.
43. G. M. Sheldrick, SHELX93: Program for Determination of Crystal Structure, University of Göttingen, Germany, 1994.