Chemical understanding of carbide cluster metallofullerenes: A case study on Sc 2C 2@ C 2v(5)-C 80 with complete X-ray crystallographic characterizations

Journal of the American Chemical Society

Volumn 134, Issue 6, 2012, Pages 3139-3144

  Kurihara, Hiroki ^a   Lu, Xing ^a   Iiduka, Yuko ^a   Nikawa, Hidefumi ^a   Mizorogi, Naomi ^a   Slanina, Zdenek ^a   Tsuchiya, Takahiro ^a   Nagase, Shigeru ^b   Akasaka, Takeshi ^a  

^a UNIVERSITY OF TSUKUBA   (Japan)

^b INSTITUTE FOR MOLECULAR SCIENCE   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

CARBENES; CARBIDE CLUSTERS; CRYSTALLOGRAPHIC CHARACTERIZATION; EXPERIMENTAL TECHNIQUES; METALLOFULLERENES; SINGLE CRYSTAL X-RAY CRYSTALLOGRAPHY; THERMAL ISOMERIZATIONS;

CARBIDES; CHEMICAL PROPERTIES; FULLERENES; ISOMERS; PHOTOCHEMICAL REACTIONS; X RAY CRYSTALLOGRAPHY;

SCANDIUM;

CARBENE; CARBON; FULLERENE; METALLOFULLERENE; REAGENT; UNCLASSIFIED DRUG;

ARTICLE; CRYSTAL STRUCTURE; ELECTROCHEMICAL ANALYSIS; ISOMERIZATION; MATERIALS; STRUCTURE ANALYSIS; X RAY CRYSTALLOGRAPHY;

EID: 84856852491     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja210101f     Document Type: Article

References (55)

1. Geim, A. K.; Novoselov, K. S. Nat. Mater. 2007, 6, 183-191
2. Allen, M. J.; Tung, V. C.; Kaner, R. B. Chem. Rev. 2010, 110, 132-145
3. Vostrowsky, O.; Hirsch, A. Angew. Chem., Int. Ed. 2004, 43, 2326-2329
4. Fowler, P. W.; Manolopoulos, D. E. An Atlas of Fullerenes; Oxford Press: Clarendon, 1995.
5. Thilgen, C.; Diederich, F. Chem. Rev. 2006, 106, 5049-5135
6. Fullerenes: Recent Advances in the Chemistry and Physics of Fullerenes and Related Materials; Kadish, K. M.;; Ruoff, R. S., Eds.; The Electrochemical Society, Pennington, NJ, 1997.
7. Nakamura, E.; Isobe, H. Chem. Rec. 2010, 10, 260-270
8. Hirsch, A.; Brettreich, M. Fullerenes: Chemistry and Reactions; Wiley-VCH, 2005.
9. Giacalone, F.; Martin, N. Chem. Rev. 2006, 106, 5136-5190
10. Matsuo, Y.; Nakamura, E. Chem. Rev. 2008, 108, 3016-3028
11. Endofullerenes: A New Family of Carbon Clusters, Akasaka, T.; Nagase, S., Eds.; Kluwer: Dordrecht, The Netherlands, 2002.
12. Chemistry of Nanocarbons; Akasaka, T.; Wudl, F.; Nagase, S., Eds.; Wiley-Blackwell: London, 2010.
13. Lu, X.; Akasaka, T.; Nagase, S. Rare Earth Metals Trapped inside Fullerenes: Endohedral Metallofullerenes, in Rare Earth Coordination Chemistry: Fundamentals and Applications; Huang, C. H., Ed.; John Wiley & Sons: Singapore, 2010; pp 273-308.
14. Chaur, M. N.; Melin, F.; Ortiz, A. L.; Echegoyen, L. Angew. Chem., Int. Ed. 2009, 48, 7514-7538
15. Yamada, M.; Akasaka, T.; Nagase, S. Acc. Chem. Res. 2010, 43, 92-102
16. Dunsch, L.; Yang, S. Small 2007, 3, 1298-1320
17. Rodríguez-Fortea, A.; Balch, A. L.; Poblet, J. M. Chem. Soc. Rev. 2011, 40, 3551-3563
18. Lu, X.; Akasaka, T.; Nagase, S. Chem. Commun. 2011, 47, 5942-5957
19. Maeda, Y.; Tsuchiya, T.; Lu, X.; Takano, Y.; Akasaka, T.; Nagase, S. Nanoscale 2011, 3, 2421-2429
20. Osuna, S.; Swart, M.; Sola, M. Phys. Chem. Chem. Phys. 2011, 13, 3585-3603
21. Lu, X.; Nikawa, H.; Feng, L.; Tsuchiya, T.; Maeda, Y.; Akasaka, T.; Mizorogi, N.; Slanina, Z.; Nagase, S. J. Am. Chem. Soc. 2009, 131, 12066-12067
22. Lu, X.; Nikawa, H.; Tsuchiya, T.; Akasaka, T.; Toki, M.; Sawa, H.; Mizorogi, N.; Nagase, S. Angew. Chem., Int. Ed. 2010, 49, 594-597
23. Lukoyanova, O.; Cardona, C. M.; Rivera, J.; Lugo-Morales, L. Z.; Chancellor, C. J.; Olmstead, M. M.; Rodriguez-Fortea, A.; Poblet, J. M.; Balch, A. L.; Echegoyen, L. J. Am. Chem. Soc. 2007, 129, 10423-10430
24. Cardona, C. M.; Elliott, B.; Echegoyen, L. J. Am. Chem. Soc. 2006, 128, 6480-6485
25. Wang, C. R.; Kai, T.; Tomiyama, T.; Yoshida, T.; Kobayashi, Y.; Nishibori, E.; Takata, M.; Sakata, M.; Shinohara, H. Angew. Chem., Int. Ed. 2001, 40, 397-399
26. Iiduka, Y.; Wakahara, T.; Nakahodo, T.; Tsuchiya, T.; Sakuraba, A.; Maeda, Y.; Akasaka, T.; Yoza, K.; Horn, E.; Kato, T.; Liu, M. T. H.; Mizorogi, N.; Kobayashi, K.; Nagase, S. J. Am. Chem. Soc. 2005, 127, 12500-12501
27. Iiduka, Y.; Wakahara, T.; Nakajima, K.; Tsuchiya, T.; Nakahodo, T.; Maeda, Y.; Akasaka, T.; Mizorogi, N.; Nagase, S. Chem. Commun. 2006, 2057-2059
28. Iiduka, Y.; Wakahara, T.; Nakajima, K.; Nakahodo, T.; Tsuchiya, T.; Maeda, Y.; Akasaka, T.; Yoza, K.; Liu, M. T. H.; Mizorogi, N.; Nagase, S. Angew. Chem., Int. Ed. 2007, 46, 5562-5564
29. Yamazaki, Y.; Nakajima, K.; Wakahara, T.; Tsuchiya, T.; Ishitsuka, M. O.; Maeda, Y.; Akasaka, T.; Waelchli, M.; Mizorogi, N.; Nagase, S. Angew. Chem., Int. Ed. 2008, 47, 7905-7908
30. Wang, T. S.; Chen, N.; Xiang, J. F.; Li, B.; Wu, J. Y.; Xu, W.; Jiang, L.; Tan, K.; Shu, C. Y.; Lu, X.; Wang, C. R. J. Am. Chem. Soc. 2009, 131, 16646-16647
31. Wang, T. S.; Wu, J. Y.; Xu, W.; Xiang, J. F.; Lu, X.; Li, B.; Jiang, L.; Shu, C. Y.; Wang, C. R. Angew. Chem., Int. Ed. 2010, 49, 1786-1789
32. Kurihara, H.; Lu, X.; Iiduka, Y.; Mizorogi, N.; Slanina, Z.; Tsuchiya, T.; Akasaka, T.; Nagase, S. J. Am. Chem. Soc. 2011, 133, 2382-2385
33. Lu, X.; Nakajima, K.; Iiduka, Y.; Nikawa, H.; Mizorogi, N.; Slanina, Z.; Tsuchiya, T.; Nagase, S.; Akasaka, T. J. Am. Chem. Soc. 2011, 133, 19553-19558
34. Takata, M.; Nishibori, E.; Sakata, M.; Inakuma, M.; Yamamoto, E.; Shinohara, H. Phys. Rev. Lett. 1999, 83, 2214-2217
35. Takata, M.; Nishibori, E.; Umeda, B.; Sakata, M.; Yamamoto, E.; Shinohara, H. Phys. Rev. Lett. 1997, 78, 3330-3333
36. Inakuma, M.; Yamamoto, E.; Kai, T.; Wang, C. R.; Tomiyama, T.; Shinohara, H.; Dennis, T. J. S.; Hulman, M.; Krause, M.; Kuzmany, H. J. Phys. Chem. B 2000, 104, 5072-5077
37. Becke, A. D. Phys. Rev. A 1988, 38, 3098-3100
38. Becke, A. D. J. Chem. Phys. 1993, 98, 5648-5652
39. Lee, C.; Yang, W.; Parr, R. G. Phys. Rev. B 1988, 37, 785-789
40. Frisch, M. J. Gaussian 03, Revision C. 01; Gaussian Inc.: Wallingford, CT, 2004.
41. Hay, P. J.; Wadt, W. R. J. Chem. Phys. 1985, 82, 299-310
42. Francl, M. M.; Pietro, W. J.; Hehre, W. J.; Binkley, J. S.; Gordon, M. S.; DeFrees, D. J.; Pople, J. A. J. Chem. Phys. 1982, 77, 3654-3665
43. Antonio, R. F.; Campanera, M. J.; Cardona, C. M.; Echegoyen, L.; Polet, J. M. Angew. Chem., Int. Ed. 2006, 45, 8176
44. Sheldrick, G. M. Acta Crystallogr. 2008, A64, 112-122
45. Maeda, Y. J. Am. Chem. Soc. 2004, 126, 6858-6859
46. Akasaka, T. J. Am. Chem. Soc. 2008, 130, 12840-12841
47. Takano, Y.; Aoyagi, M.; Yamada, M.; Nikawa, H.; Slanina, Z.; Mizorogi, N.; Ishitsuka, M. O.; Tsuchiya, T.; Maeda, Y.; Akasaka, T.; Kato, T.; Nagase, S. J. Am. Chem. Soc. 2009, 131, 9340-9346
48. Lu, X.; Nikawa, H.; Nakahodo, T.; Tsuchiya, T.; Ishitsuka, M. O.; Maeda, Y.; Akasaka, T.; Toki, M.; Sawa, H.; Slanina, Z.; Mizorogi, N.; Nagase, S. J. Am. Chem. Soc. 2008, 130, 9129-9136
49. Lu, X.; Nikawa, H.; Tsuchiya, T.; Maeda, Y.; Ishitsuka, M. O.; Akasaka, T.; Toki, M.; Sawa, H.; Slanina, Z.; Mizorogi, N.; Nagase, S. Angew. Chem., Int. Ed. 2008, 47, 8642-8645
50. Zuo, T. M.; Beavers, C. M.; Duchamp, J. C.; Campbell, A.; Dorn, H. C.; Olmstead, M. M.; Balch, A. L. J. Am. Chem. Soc. 2007, 129, 2035-2043
51. Lu, X.; lian, Y.; Beavers, C. M.; Mizorogi, N.; Slanina, Z.; Nagase, S.; Akasaka, T. J. Am. Chem. Soc. 2011, 133, 10772-10775
52. Cai, T.; Slebodnick, C.; Xu, L.; Harich, K.; Glass, T. E.; Chancellor, C.; Fettinger, J. C.; Olmstead, M. M.; Balch, A. L.; Gibson, H. W.; Dorn, H. C. J. Am. Chem. Soc. 2006, 128, 6486-6492
53. Cardona, C. M.; Kitaygorodskiy, A.; Echegoyen, L. J. Am. Chem. Soc. 2005, 127, 10448-10453
54. Takano, Y.; Ishitsuka, M. O.; Tsuchiya, T.; Akasaka, T.; Kato, T.; Nagase, S. Chem. Commun. 2010, 46, 8035-8036
55. Lu, X.; Nikawa, H.; Kikuchi, T.; Mizorogi, N.; Slanina, Z.; Tsuchiya, T.; Nagase, S.; Akasaka, T. Angew. Chem., Int. Ed. 2011, 50, 6356-6359