Phosphinoborane-induced fragmentation of the unsaturated hydride H 2Re 2(CO) 8: X-ray structure of HRe(CO) 4(κ B,P-Ph 2PCH 2CH 2BR 2) (where BR 2 = 9-borabicyclo[3.3.1]nonanyl) and DFT Evaluation of hydride versus CO coordination by the ancillary borane

Journal of Organometallic Chemistry

Volumn 700, Issue , 2012, Pages 103-109

  Huang, Shih Huang ^a   Wang, Xiaoping ^b   Richmond, Michael G ^a  

^a UNIVERSITY OF NORTH TEXAS   (United States)

^b OAK RIDGE NATIONAL LABORATORY   (United States)

Author keywords

Ambiphilic ligand; Crystallography; DFT; Phosphinoborane; Rhenium

Indexed keywords

CO-GROUP; DFT; HIGH YIELD; HYDRIDE ABSTRACTION; IR AND NMR SPECTROSCOPY; LEWIS ACID; PHOSPHINOBORANE; ROOM TEMPERATURE; SOLID-STATE STRUCTURES; X-RAY STRUCTURE;

CRYSTALLOGRAPHY; DIMERS; LIGANDS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; PHOSPHORUS COMPOUNDS; RHENIUM; X RAY CRYSTALLOGRAPHY; X RAY DIFFRACTION ANALYSIS;

HYDRIDES;

EID: 84856219448     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jorganchem.2011.11.020     Document Type: Article

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