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See Supporting Information for full details.
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See Supporting Information for full details.
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13C chemical shift of Re-CHO. Solid-state structures appear to be intermediate between carbene and formyl.
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14) as an analytically pure white powder. See Supporting Information for full details.
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77958110807
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The reactivity in THF is consistent with the initially formed carbene undergoing fast disproportionation chemistry, just as the Re analogue.
-
The reactivity in THF is consistent with the initially formed carbene undergoing fast disproportionation chemistry, just as the Re analogue.
-
-
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69
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77958099957
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note
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3(CHO) with trialkylboranes, as the formyl shifts upfield with added borane.
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70
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77958112237
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The large size of Re and P in these rings is expected to favor smaller ring sizes than organic counterparts, which suggests that seven- and eight-membered rings are more destablized than organic systems.
-
The large size of Re and P in these rings is expected to favor smaller ring sizes than organic counterparts, which suggests that seven- and eight-membered rings are more destablized than organic systems.
-
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71
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77958108542
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One possibility for this kinetic discrepancy could be tighter ion pairing for the smaller anions, which may aid in the transfer of hydride between two cationic species.
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One possibility for this kinetic discrepancy could be tighter ion pairing for the smaller anions, which may aid in the transfer of hydride between two cationic species.
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3 generally resulted in much more hydride formation and were thus avoided. These reactions were sometimes accompanied by intense color changes consistent with reduction processes, which would labilize the CO ligands and lead to reactivity at Re itself.
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