First stereoselective total synthesis of naturally occurring (6 R)-6-(4-Oxopentyl)-5,6-dihydro-2 H -pyran-2-one and Its (6 S)-enantiomer

Synthesis

Volumn 44, Issue 3, 2012, Pages 469-473

  Shinde, Digambar Balaji ^a   Kanth, Boddu Shashi ^a   Srilatha, Malampati ^a   Das, Biswanath ^a  

^a INDIAN INSTITUTE OF CHEMICAL TECHNOLOGY   (India)

Author keywords

(6 R) 6 (4 oxopent 2 enyl) 5,6 dihydro 2 H pyran 2 one; (6 S) 6 (4 oxopent 2 enyl) 5,6 dihydro 2 H pyran 2 one; lactones; ring closing metathesis; stereoselective synthesis

Indexed keywords

(6 R)-6-(4-OXOPENT-2-ENYL)-5,6-DIHYDRO-2 H -PYRAN-2-ONE; (6 S)-6-(4-OXOPENT-2-ENYL)-5,6-DIHYDRO-2 H -PYRAN-2-ONE; LACTONES; RING CLOSING METATHESIS; STEREOSELECTIVE SYNTHESIS;

CHIRALITY; ENANTIOMERS; PARAFFINS; STEREOCHEMISTRY;

STEREOSELECTIVITY;

5 (BENYZYLOXY)PENTAN 1 OL; 5 (TERT BUTYLDIPHENYLSILOXY)HEXAN 1 OL; 5 (TERT BUTYLDIPHENYLSILOXY)HEXANAL; 6 (4 OXOPENTYL) 5,6 DIHYDRO 2H PYRAN 2 ONE; 6 (4 OXOPENTYL) 5,6 DIHYDROPYRAN 2 ONE; 6 (BENYZYLOXY)HEXAN 1 OL; 6 (OXOPENTYL) 5,6 DIHYDROPYRAN 2 ONE; 8 (TERT BUTYLDIPHENYLSILOXY)NON 1 EN 4 OL; 8 (TERT BUTYLDIPHENYLSILOXY)NON 1 EN 4 YL ACRYLATE; 8 HYDROXYNON 1 EN 4 YL ACRYLATE; 8 OXONON 1 EN 4 YL ACRYLATE; [6 (BENYZYLOXY)HEXAN 2 YLOXY]TERT BUTYLDIPHENYLSILANE; ANTIFUNGAL AGENT; ANTIINFECTIVE AGENT; CYTOTOXIC AGENT; LACTONE DERIVATIVE; UNCLASSIFIED DRUG;

ALLYLATION; ARTICLE; CHEMICAL PARAMETERS; DEPROTECTION REACTION; DRUG STRUCTURE; DRUG SYNTHESIS; ENANTIOMER; MARUOKA ASYMMETRIC ALLYLATION; RING CLOSING METATHESIS; STEREOCHEMISTRY;

EID: 84856214523     PISSN: 00397881     EISSN: 1437210X     Source Type: Journal    
DOI: 10.1055/s-0031-1289643     Document Type: Article

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