Physical properties of nutritive shortenings produced from regioselective hardening of soybean oil with Pt containing zeolite

JAOCS, Journal of the American Oil Chemists' Society

Volumn 88, Issue 12, 2011, Pages 2023-2034

  Philippaerts, An ^a   Breesch, Annika ^a   De Cremer, Gert ^a   Kayaert, Pieterjan ^a   Hofkens, Johan ^a   Van Den Mooter, Guy ^a   Jacobs, Pierre ^a   Sels, Bert ^a  

^a UNIVERSITY OF LEUVEN   (Belgium)

Author keywords

Crystallization; Hardening; Hydrogenation; Melting behavior; Polymorphism; Pt ZSM 5 catalyst; Shortening; Solid fat content; Soybean oil

Indexed keywords

FLEXIBLE SOLIDS; HIGH PLASTICITY; HIGH THERMAL STABILITY; HIGH-CONTENT; MELTING AND CRYSTALLIZATION; MELTING BEHAVIOR; MELTING CHARACTERISTICS; MESOPOROUS ALUMINA; MICROPOROUS ZEOLITE; MOLECULAR PACKINGS; NETWORK FORMATION; PHYSICAL CHARACTERISTICS; PT/ALUMINA; REGIO-SELECTIVE; SELECTIVE HYDROGENATION; SHORTENING; SLIP MELTING POINT; SOLID FAT CONTENT; SOYBEAN OIL; TRANS FATTY ACID; TRIACYLGLYCEROLS; ZEOLITE ZSM-5;

ALUMINA; CATALYSTS; CRYSTALLIZATION; GLYCEROL; HARDENING; HYDROGENATION; OILS AND FATS; PALMITIC ACID; PHASE TRANSITIONS; PHYSICAL PROPERTIES; POLYMORPHISM;

PLATINUM;

GLYCINE MAX;

EID: 84855696711     PISSN: 0003021X     EISSN: None     Source Type: Journal    
DOI: 10.1007/s11746-011-1878-9     Document Type: Article

References (36)

1. Ghotra BS, Dyal SD, Narine SS (2002) Lipid shortenings: a review. Food Res Int 35:1015-1048 (Pubitemid 35404690)
2. Albright LF (1963) Mechanism of hydrogenation of triglycerides. J Am Oil Chem Soc 40:16
3. Clifton PM, Keogh JB, Noakes M (2004) Trans fatty acids in adipose tissue and the food supply are associated with myocardial infarction. J Nutr 134:1848
4. Mozaffarian D, Katan MB, Ascherio A, Stampfer MJ, Willett WC (2006) Medical progress - trans fatty acids and cardiovascular disease. New Engl J Med 354:1601-1613
5. US Department of Health and Human Services FaDA, 21 CFR Part 101 [Docket No. 94P-0036], Food labeling: trans fatty acids in nutrition labeling, nutrient content claims and health claims, Washington, 2003, p. 254
6. EFSA (2004) Opinion on the scientific panel on dietetic products, nutrition and allergies on the request from the commission related to the presence of trans fatty acids in foods and the effect on human health of the consumption of trans fatty acids (Request No. EFSA-Q-2003-022). EFSA J 81:1-49
7. Patterson HBW (1994) Hydrogenation of fats and oils: theory and practice. AOCS Press, Illinois
8. Cizmeci M, Musavi A, Kayahan M, Tekin A (2005) Monitoring of hydrogenation with various catalyst ratios. J Am Oil Chem Soc 82:925-929 (Pubitemid 46444819)
9. Berben PH, Borninkhof F, Reesink B, Kuijpers E (1994) Production of low trans-isomer-containing products by hydrogenation. Inform 5:516
10. Beers A, Mangnus G (2004) Hydrogenation of edible oils for reduced trans-fatty acid content. Inform 15:404-405
11. Smidovnik A, Kobe J, Leskovsek S, Koloini T (1994) Kinetics of catalytic transfer hydrogenation of soybean oil. J Am Oil Chem Soc 71:507-511
12. Ju JW, So WS, Kim JH, Bae BJ, Choi EN, Kwon YH, Chung IM, Yoon SH, Jung MY (2003) Effects of alcohol type and amounts on conjugated linoleic acid formation during catalytic transfer hydrogenation of soybean oil. J Food Sci 68:1915-1922 (Pubitemid 37024094)
13. Yusem GJ, Pintauro PN (1992) The electrocatalytic hydrogenation of soybean oil. J Am Oil Chem Soc 69:399-404
14. An WD, Hong JK, Pintauro PN, Warner K, Neff W (1998) The electrochemical hydrogenation of edible oils in a solid polymer electrolyte reactor. I. Reactor design and operation. J Am Oil Chem Soc 75:917-925 (Pubitemid 128559008)
15. Mondal K, Lalvani SB (2003) Mediator-assisted electrochemical hydrogenation of soybean oil. Chem Eng Sci 58:2643-2656 (Pubitemid 36775095)
16. King JW, Holliday RL, List GR, Snyder JM (2001) Hydrogenation of vegetable oils using mixtures of supercritical carbon dioxide and hydrogen. J Am Oil Chem Soc 78:107-113 (Pubitemid 32272250)
17. Ramirez E, Recasens F, Fernandez M, Larrayoz MA (2004) Sunflower oil hydrogenation on Pd/C in SC propane in a continuous recycle reactor. AIChe J 50:1545-1555 (Pubitemid 38856779)
18. Santana A, Larrayoz MA, Ramirez E, Nistal J, Recasens F (2007) Sunflower oil hydrogenation on Pd in supercritical solvents: Kinetics and selectivities. J Supercrit Fluids 41:391-403 (Pubitemid 46661148)
19. Piqueras CA, Tonetto G, Bottini S, Damiani DE (2008) Sunflower oil hydrogenation on Pt catalysts: comparison between conventional process and homogeneous phase operation using supercritical propane. Catal Today 133:836-841
20. Khatoon S, Reddy SRY (2005) Plastic fats with zero trans fatty acids by interesterification of mango, mahua and palm oils. Eur J Lipid Sci Technol 107:786-791 (Pubitemid 41736438)
21. Siew WL, Cheah KY, Tang WL (2007) Physical properties of lipase-catalyzed interesterification of palm stearin with canola oil blends. Eur J Lipid Sci Technol 109:97-106
22. Chu BS, Ghazali HM, Lai OM, Man YBC, Yusof S, Tee SB, Yusoff MSA (2001) Comparison of lipase-transesterified blend with some commercial solid frying shortenings in Malaysia. J Am Oil Chem Soc 78:1213-1219 (Pubitemid 34180235)
23. Lee JH, Akoh CC, Lee KT (2008) Physical properties of transfree bakery shortening produced by lipase-catalyzed interesterification. J Am Oil Chem Soc 85:1-11 (Pubitemid 50001072)
24. Katan MB, Zock PL, Mensink RP (1994) Effects of fats and fattyacids on blood-lipids in humans - an overview. Am J Clin Nutr 60:S1017-S1022
25. Philippaerts A, Paulussen S, Beersch A, Turner S, Lebedev OI, Van Tendeloo G, Sels B, Jacobs P (2011) Unprecedented shape selectivity in hydrogenation of triacylglycerol molecules with Pt/ ZSM-5 zeolite. Angew Chem Int Ed 50:3947-3949
26. Philippaerts A, Paulussen S, Turner S, Lebedev OI, Van Tendeloo G, Poelman H, Bulut M, De Clippel F, Smeets P, Sels B, Jacobs P (2010) Selectivity in sorption and hydrogenation of methyl oleate and elaidate on MFI zeolites. J Catal 270:172-184
27. Kris-Etherton PM, Pearson TA, Wan Y, Hargrove RL, Moriarty K, Fishell V, Etherton T (1999) High-monounsaturated fatty acid diets lower both plasma cholesterol and triacylglycerol concentrations. Am J Clin Nutr 70:1009-1015
28. Kelly FD, Sinclair AJ, Mann NJ, Turner AH, Abedin L, Li D (2001) A stearic acid-rich diet improves thrombogenic and atherogenic risk factor profiles in healthy males. Eur J Clin Nutr 55:88-96 (Pubitemid 32156888)
29. Luddy FE, Magidman P, Herb SF, Riemenschneider RW, Barford RA (1964) Pancreatic lipase hydrolysis of triglycerides by semimicro technique. J Am Oil Chem Soc 41:693
30. Hastert RC (1996) Hydrogenation. In: Hui YH (ed) Bailey's Industrial Oil & Fat Products. Wiley, New York, p 679
31. Chu YH, Lin LH (1991) An evaluation of commercial nickelcatalysts during hydrogenation of soybean oil. J Am Oil Chem Soc 68:680-683
32. Linderborg KM, Kallio HPT (2005) Triacylglycerol fatty acid positional distribution and postprandial lipid metabolism. Food Rev Int 21:331-355 (Pubitemid 41054329)
33. Hernqvist L (1984) Polymorphism of fats. Lund University, Lund
34. Dsouza V, Deman JM, Deman L (1990) Short spacings and polymorphic forms of natural and commercial solid fats - a review. J Am Oil Chem Soc 67:835-843
35. Watanabe A, Tashima I, Matsuzaki N, Kurashige J, Sato K (1992) On the formation of granular crystals in fat blends containing palm oil. J Am Oil Chem Soc 69:1077-1080
36. List GR, Jackson M, Eller F, Adlof RO (2007) Low trans spread and shortening oils via hydrogenation of soybean oil. J Am Oil Chem Soc 84:609-612 (Pubitemid 46906536)